(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
The correct title of this article is [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride. The substitution or omission of any < > [ ] { } is because of technical restrictions.
ferrocene_palladium(II)_dichloride.svg.png) | |
| Identifiers | |
|---|---|
72287-26-4  95464-05-4 complex with DCM | |
| ChemSpider | 24602493 |
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| Properties | |
| C34H28Cl2FeP2Pd | |
| Molar mass | 731.71 g·mol−1 |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is an palladium complex containing the iron-containing dppf ligand. Commercially available, this compound is popularly used for palladium-catalyzed coupling reactions.
Commercially available, this compound may be prepared from dppf and nitrile complexes of palladium dichloride:[1]
- dppf + PdCl2(RCN)2 → (dppf)PdCl2 + 2 RCN (RCN = acetonitrile or benzonitrile)
References
- ↑ Nataro, Chip; Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1’-Bis(diphenylphosphino)ferrocene". J. Chem. Ed. 86: 1412. doi:10.1021/ed086p1412.
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