1-Bromohexane
Names | |
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IUPAC name
1-Bromohexane[1] | |
Other names
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Identifiers | |
111-25-1 | |
1731290 | |
ChemSpider | 7810 |
EC Number | 203-850-2 |
Jmol interactive 3D | Image |
MeSH | 1-bromohexane |
PubChem | 8101 |
RTECS number | MO0925000 |
UN number | 1993 |
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Properties | |
C6H13Br | |
Molar mass | 165.07 g·mol−1 |
Appearance | Colorless liquid |
Density | 1.176 g/mL |
Melting point | −84.70 °C; −120.46 °F; 188.45 K |
Boiling point | 154 to 158 °C; 309 to 316 °F; 427 to 431 K |
Insoluble | |
Solubility | Alcohol, ether |
Refractive index (nD) |
1.448 |
Thermochemistry | |
219.7 J K−1 mol−1 | |
Std molar entropy (S |
452.92 J K−1 mol−1 |
Std enthalpy of formation (ΔfH |
−196.1–−192.9 kJ mol−1 |
Std enthalpy of combustion (ΔcH |
−4026.2–−4023.0 kJ mol−1 |
Hazards | |
GHS pictograms | |
GHS signal word | WARNING |
H226, H315, H319, H335 | |
P261, P305+351+338 | |
EU classification (DSD) |
Xi |
R-phrases | R36/37/38 |
S-phrases | S26, S36 |
NFPA 704 | |
Flash point | 57 °C (135 °F; 330 K) |
Lethal dose or concentration (LD, LC): | |
LD50 (Median dose) |
1.226 g/kg (IP, mouse) |
Related compounds | |
Related alkanes |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
1-Bromohexane is a liquid organohalide with structural formula Br-CH2-CH2-CH2-CH2-CH2-CH3. Its refractive index is 1.4478 (20 °C, D).
Applications
It is used to manufacture pharmaceuticals and organic chemicals. 1-Bromohexane is also a solvent that is frequently used in grignard reactions, that are involved with creating bromo-cyclic compounds. [2]
See also
References
- ↑ "1-bromohexane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 26 March 2005. Identification. Retrieved 17 June 2012.
- ↑ Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113(14), 5392-5397.
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