3-Carboxy-cis,cis-muconic acid

3-Carboxy-cis,cis-muconic acid
Names
Systematic IUPAC name
(1E,3Z)-Buta-1,3-diene-1,2,4-tricarboxylic acid[1]
Identifiers
1116-26-3 N
3DMet B00251
ChEBI CHEBI:15749 YesY
ChemSpider 4444085 YesY
Jmol interactive 3D Image
KEGG C01163 YesY
PubChem 5280404
Properties
C7H6O6
Molar mass 186.12 g·mol−1
Density 1.25 g cm−3
0.40 D
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

3-Carboxy-cis,cis-muconic acid is a metabolite of the catechin degradation by Bradyrhizobium japonicum.[2]

The enzyme 3-carboxy-cis,cis-muconate cycloisomerase uses 2-carboxy-2,5-dihydro-5-oxofuran-2-acetate to produce 3-carboxy-cis,cis-muconate.

The enzyme carboxy-cis,cis-muconate cyclase uses 3-carboxy-2,5-dihydro-5-oxofuran-2-acetate to produce 3-carboxy-cis,cis-muconate.

The enzyme protocatechuate 3,4-dioxygenase uses 3,4-dihydroxybenzoate and O2 to produce 3-carboxy-cis,cis-muconate.

References

  1. "(1E,3Z)-buta-1,3-diene-1,2,4-tricarboxylic acid - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 13 October 2011.
  2. Waheeta Hopper and A. Mahadevan (1997). "Degradation of catechin by Bradyrhizobium japonicum". Biodegradation 8 (3): 159–165. doi:10.1023/A:1008254812074.


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