Acetic formic anhydride

Acetic formic anhydride
Skeletal formula of acetic formic anhydride
Ball-and-stick model of the acetic formic anhydride molecule
Names
IUPAC name
Acetyloxymethanone
Systematic IUPAC name
Formyl acetate[1]
Other names
Formic acetic anhydride
Identifiers
2258-42-6 N
ChemSpider 67812 YesY
Jmol interactive 3D Image
PubChem 75269
Properties
C3H4O3
Molar mass 88.06 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Acetic formic anhydride, or ethanoic methanoic anhydride is an organic compound with the chemical formula C
3
H
4
O
3
and a structural formula of H
3
C
-(C=O)-O-(C=O)H. It can be viewed as the mixed anhydride of acetic acid and formic acid.

Preparation

Acetic formic anhydride can be produced by reacting sodium formate with acetyl chloride in anhydrous diethyl ether between 23–27 °C.[2]

Applications

Acetic formic anhydride is a formylation agent for amines, amino acids, and alcohols. It is also a starting material for other compounds such as formyl fluoride.[2]

See also

References

  1. "Formyl acetate - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information.
  2. 1 2 Krimen, Lewis I. (1970). "Acetic Formic Anhydride". Organic Syntheses 50: 1. doi:10.15227/orgsyn.050.0001.
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