Allylmagnesium bromide

Allylmagnesium bromide

Identifiers
CAS Number	1730-25-2
ChemSpider	10796765
Jmol interactive 3D	Image
PubChem	74413
InChI InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1 Key: FEMBXICCJNZMMC-UHFFFAOYSA-M InChI=1/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.BrH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1 Key: FEMBXICCJNZMMC-NCRCPWRRAY
SMILES [Br-].[Mg+]CC=C
Properties
Chemical formula	C3H5BrMg
Molar mass	145.28 g·mol^−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Allylmagnesium bromide is an Grignard reagent used for introducing the allyl group. It is commonly available as a solution in diethyl ether. If desired, it may be synthesized in the normal method from magnesium and allyl bromide.^[1]

References

1. Benson, R. E.; McKusick, B. C. (1958). "1,4-Pentadiene". Org. Synth. 38: 78.; Coll. Vol. 4, p. 746

Further reading

• Chabot, P. (1996). "7. Infrared and Raman Spectroscopy". In Rakita, P. E.; Silverman, G. Handbook of Grignard Reagents. New York, N.Y.: Marcel Dekker. pp. 93–102. ISBN 0-8247-9545-8.