Chlorophyll b

Chlorophyll b

Names
IUPAC name Chlorophyll b
Systematic IUPAC name Magnesium [methyl (3S,4S,21R)-14-ethyl-13-formyl-4,8,18-trimethyl-20-oxo-3-(3-oxo-3-{[(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecen-1-yl]oxy}propyl)-9-vinyl-21-phorbinecarboxylatato(2-)-κ^2N,N']
Other names β-Chlorophyll
Identifiers
CAS Number	519-62-0
ChemSpider	16739843
EC Number	208-272-4
Jmol interactive 3D	Image
PubChem	6450186 11593175 (from spinach)
UNII	5712ZB110R
InChI InChI=1S/C55H71N4O6.Mg/c1-12-38-35(8)42-27-43-36(9)40(23-24-48(61)65-26-25-34(7)22-16-21-33(6)20-15-19-32(5)18-14-17-31(3)4)52(58-43)50-51(55(63)64-11)54(62)49-37(10)44(59-53(49)50)28-46-39(13-2)41(30-60)47(57-46)29-45(38)56-42;/h12,25,27-33,36,40,51H,1,13-24,26H2,2-11H3,(H-,56,57,58,59,60,62);/q-1;+2/p-1/b34-25+;/t32-,33-,36+,40+,51-;/m1./s1 Key: NSMUHPMZFPKNMZ-VBYMZDBQSA-M InChI=1S/C55H72N4O6.Mg/c1-12-38-35(8)42-27-43-36(9)40(23-24-48(61)65-26-25-34(7)22-16-21-33(6)20-15-19-32(5)18-14-17-31(3)4)52(58-43)50-51(55(63)64-11)54(62)49-37(10)44(59-53(49)50)28-46-39(13-2)41(30-60)47(57-46)29-45(38)56-42;/h12,25,27-33,36,40,51H,1,13-24,26H2,2-11H3,(H2,56,57,58,59,60,62);/q;+2/p-2/b34-25+;/t32-,33-,36+,40+,51-;/m1./s1 Key: MSLKMRUEVOYOOZ-VBYMZDBQSA-L
SMILES CCC\1=C(c2/cc\3/c(c(c4/n3[Mg]n5c(/cc1\n2)c(c6c5/c(c/7\nc(\c4)[C@H]([C@@H]7CCC(=O)OC/C=C(\C)/CCC[C@H](C)CCC[C@H](C)CCCC(C)C)C)/[C@H](C6=O)C(=O)OC)C)C)C=C)C=O
Properties
Chemical formula	C55H70MgN4O6
Molar mass	907.49 g·mol^−1
Appearance	Green
Odor	Odorless
Melting point	~ 125 °C (257 °F; 398 K)[1]
Solubility in water	Insoluble[1]
Solubility	Very soluble in EtOH, ether, C5H5N Soluble in MeOH[1]
Absorbance	See text
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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The absorption spectrum of both the chlorophyll a and the chlorophyll b pigments. The use of both together enhances the size of the absorption of light for producing energy.

Chlorophyll b is a form of chlorophyll. Chlorophyll b helps in photosynthesis by absorbing light energy. It is more soluble than chlorophyll a in polar solvents because of its carbonyl group. Its color is yellow, and it primarily absorbs blue light.^[2]

In land plants, the light-harvesting antennae around photosystem II contain the majority of chlorophyll b. Hence, in shade-adapted chloroplasts, which have an increased ratio of photosystem II to photosystem I, there is a higher ratio of chlorophyll b to chlorophyll a.^[3] This is adaptive, as increasing chlorophyll b increases the range of wavelengths absorbed by the shade chloroplasts.

Structure of chlorophyll b molecule showing the long hydrocarbon tail

References

1. Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
2. photosynthesis pigments
3. Kitajima and Hogan 2003