Collinsite

Collinsite

Crystals of collinsite from the Rapid Creek area of northern Yukon, Canada
General
Category Phosphate mineral
Formula
(repeating unit)		 Ca2(Mg,Fe2+)(PO4)2·2H2O
Strunz classification 08.CG.05
Dana classification 40.2.2.3
Crystal system Triclinic
Unit cell a = 5.734(1) Å
b = 6.780(1) Å
c = 5.441(1) Å
α = 97.29°
β = 108.56°
γ = 107.28°
Z = 1[1]
Identification
Crystal symmetry Pinacoidal
H-M group: 1
Space group: P1
Cleavage Fair on {001} and {010}
Tenacity Brittle[1]
Mohs scale hardness 3 to 3.5
Luster Subvitreous, silky if fibrous[1]
Streak White[1]
Diaphaneity Translucent
Specific gravity 2.99
Optical properties Biaxial (+)
Refractive index nα = 1.632
nβ = 1.642
nγ = 1.657
Birefringence δ = 0.025
2V angle 80° (measured)
Dispersion r < v strong
Ultraviolet fluorescence Non-fluorescent[2]
Solubility Readily soluble in acids
References [3]

Collinsite is a mineral with formula Ca2(Mg,Fe2+)(PO4)2·2H2O. It was discovered in British Columbia, Canada, and formally described in 1927. It was named in honor of William Henry Collins (1878–1937), director of the Geological Survey of Canada. There are three varieties of the mineral: magnesian collinsite, zincian collinsite, and strontian collinsite. The crystal structure consists of polyhedral chains linked by weak hydrogen bonds.

Description

Brown-colored collinsite from François Lake

Collinsite is translucent and brown, chocolate-black, light brown, yellowish white, white, or colorless.[1] It is colorless in thin section[1] and light yellow-brown to colorless in transmitted light.[3] The zincian variety of collinsite is pale blue.[1] The mineral can occur with fibrous habit, as globular aggregates of crystals, as concentrically layered botryoidal masses, or as bladed or prismatic crystals up to 2 cm (0.79 in).[1]

Collinsite is a member of the fairfieldite group.[1] Hillite is the zinc analogue of collinsite[4] and collinsite is the magnesium analogue of messelite.[5]

Varieties

There are three varieties of collinsite:

Magnesian collinsite was described from South Dakota in 1972,[6] zincian collinsite was described from South Australia in 1973,[8] and strontian collinsite was described from Russia as early as 1965.[9] The replacement of calcium by strontium that occurs in strontian collinsite is atypical of collinsite.[10]

Structure

The crystal structure of collinsite was determined using essentially pure magnesian collinsite, Ca2Mg(PO4)2·2H2O, and published in 1974.[11] It consists of chains of corner-sharing (MgΦ6) octahedra and (PO4) tetrahedra. Four of the Mg ligands link to (PO4) groups and the other two to water molecules. Two of the ligands in the (PO4) group link to (MgΦ6) octahedra and the other two link to calcium atoms and act as hydrogen bond acceptors. Weak hydrogen bonds link chains together and force separation between them.[12] The separation gives room for interstitial, eight-coordinated calcium between chains.[12][13]

History

Diagram of the phosphorite nodules from François Lake; collinsite is the lightly colored layer

Collinsite was discovered prior to 1927 near François Lake, British Columbia.[14] In a 4-to-12-inch-wide vein (10 to 30 cm), phosphorite nodules were discovered that consisted of a fragment of andesite enclosed by concentric layers of phosphate minerals coated in wurtzilite.[14] The phosphate layers were composed of a mineral named quercyite (since determined to be improperly classified)[15] and the new mineral collinsite.[16] The François Lake collinsite was light-brown and consisted of sub-centimeter blades.[16]

Collinsite was named in honor of William Henry Collins (1878–1937) who, at the time, was director of the Geological Survey of Canada.[3][16] The mineral was described by Eugene Poitevin in 1927 in a publication of the Geological Survey.[17] With the analysis performed by E. A. Thompson, Poitevin identified the formula as Ca2(Mg,Fe2+)(PO4)2·2½H2O.[18] Since no crystals of collinsite were found, the only crystallographic information determined was the angle between cleavages.[19]

In 1940, C. W. Wolfe reexamined the mineral species.[19] With analysis performed by F. A. Gonyer, Wolfe identified the formula of collinsite was Ca2(Mg,Fe2+)(PO4)2·2H2O, containing less water than Poitevin indicated.[18] Wolfe also questioned the four cleavages found by Poitevin, since he could identify only two fair cleavages from six fibrous crystals.[19]

When the IMA was founded, messelite was grandfathered as a valid mineral species.[3]

Occurrence

Collinsite has been found in Australia, Austria, Bahamas, Brazil, Canada, Germany, Namibia, Norway, Romania, Russia, South Africa, Spain, and the United States.[3] The mineral formed as an incrustation of other minerals by weathering. It occurs in association with bitumen, bobierrite, carbonate rich fluoroapatite, cryptomelane, dolomite, Fe–Mn oxides, kovdorskite, parahopeite, and scholzite.[1]

References

  1. 1 2 3 4 5 6 7 8 9 10 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Collinsite" (PDF). Handbook of Mineralogy. Chantilly, VA: Mineralogical Society of America.
  2. ↑ "Collinsite". Webmineral. Retrieved August 9, 2012.
  3. 1 2 3 4 5 "Collinsite". Mindat. Retrieved August 8, 2012.
  4. ↑ Yakubovich et al. 2003, p. 981
  5. ↑ Foshag 1928, p. 202
  6. 1 2 Bridge & Pryce 1974, p. 579
  7. 1 2 Yakubovich et al. 2003, p. 227
  8. ↑ Bridge & Pryce 1974, p. 577
  9. ↑ Liferovich et al. 2001, p. 1082
  10. ↑ Yakubovich et al. 2003, p. 226
  11. ↑ Brotherton et al. 1974, p. 653
  12. 1 2 Hawthorne 1998, p. 162
  13. ↑ Brotherton et al. 1974, p. 655
  14. 1 2 Poitevin 1927, pp. 2–4
  15. ↑ "Quercyite". Mindat. Retrieved August 9, 2012.
  16. 1 2 3 Poitevin 1927, p. 5
  17. ↑ Poitevin 1927, p. 2
  18. 1 2 Wolfe 1940, p. 747
  19. 1 2 3 Wolfe 1940, p. 746
Bibliography

Further reading

External links

Media related to collinsite at Wikimedia Commons

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