Copper(I) chloride

Copper(I) chloride
Names
IUPAC name
Copper(I) chloride
Other names
Cuprous chloride
Identifiers
7758-89-6 YesY
ChEBI CHEBI:53472 YesY
ChemSpider 56403 YesY
EC Number 231-842-9
Jmol 3D model Interactive image
PubChem 62652
RTECS number GL6990000
Properties
CuCl
Molar mass 98.999 g/mol
Appearance white powder, slightly green from oxidized impurities
Density 4.145 g/cm3
Melting point 426 °C (799 °F; 699 K)
Boiling point 1,490 °C (2,710 °F; 1,760 K) (decomposes)
0.0062 g/100 mL (20 °C)
1.72 x 10−7
Solubility insoluble in ethanol
acetone; soluble in concentrated HCl, NH4OH
1.930[1]
Structure
Zinc blende structure
Hazards
Safety data sheet JT Baker
Harmful (Xn)
Dangerous for the environment (N)
R-phrases R22, R50/53
S-phrases (S2), S22, S60, S61
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
0
3
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
140 mg/kg
US health exposure limits (NIOSH):
PEL (Permissible)
 TWA 1 mg/m3 (as Cu)[2]
REL (Recommended)
 TWA 1 mg/m3 (as Cu)[2]
IDLH (Immediate danger)
 TWA 100 mg/m3 (as Cu)[2]
Related compounds
Other anions
 Copper(I) bromide
Copper(I) iodide
Other cations
 Copper(II) chloride
Silver(I) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY verify (what is YesYN ?)
Infobox references
IR spectrum of Copper(I) chloride

Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper(II) chloride.[3]

History

Copper(I) chloride was first prepared by Robert Boyle in the mid-seventeenth century[4] from mercury(II) chloride ("Venetian sublimate") and copper metal:

HgCl2 + 2 Cu → 2 CuCl + Hg

In 1799, J.L. Proust characterized the two different chlorides of copper. He prepared CuCl by heating CuCl2 at red heat in the absence of air, causing it to lose half of its combined chlorine followed by removing residual CuCl2 by washing with water.[5]

An acidic solution of CuCl was formerly used for analysis of carbon monoxide content in gases, for example in Hempel's gas apparatus.[6] This application was significant[7] during the time that coal gas was widely used for heating and lighting, during the nineteenth and early twentieth centuries.


Synthesis

Copper(I) chloride is synthesed by reducing copper(II) chloride, e.g. with sulfur dioxide:

2 CuCl2 + SO2 + 2 H2O → 2 CuCl + H2SO4 + 2 HCl

Many other reducing agents can be used.[8]

Chemical properties

Copper(I) chloride is a Lewis acid, which is classified as soft according to the Hard-Soft Acid-Base concept. Thus, it tends to form stable complexes with soft Lewis bases such as triphenylphosphine:

CuCl + P(C6H5)3 → [CuCl(P(C6H5)3)]4

Although CuCl is insoluble in water, it dissolves in aqueous solutions containing suitable donor molecules. It forms complexes with halide ions, for example forming H3O+ CuCl2− with concentrated hydrochloric acid. It is attacked by CN−, S2O32−, and NH3 to give the corresponding complexes.

Solutions of CuCl in HCl or NH3 absorb carbon monoxide to form colourless complexes such as the chloride-bridged dimer [CuCl(CO)]2. The same hydrochloric acid solutions also react with acetylene gas to form [CuCl(C2H2)]. Ammoniacal solutions of CuCl react with acetylenes to form the explosive copper(I) acetylide, Cu2C2. Complexes of CuCl with alkenes can be prepared by reduction of CuCl2 by sulfur dioxide in the presence of the alkene in alcohol solution. Complexes with dienes such as 1,5-cyclooctadiene are particularly stable:[9]

In absence of other ligands, its aqueous solutions are unstable with respect to disproportionation into Cu and CuCl2.[10] In part for this reason samples in air assume a green coloration (see photograph in upper right).

Uses

The main use of copper(I) chloride is as a precursor to the fungicide copper oxychloride. For this purpose aqueous copper(I) chloride is generated by comproportionation and then air-oxidized:

Cu + CuCl2 → 2 CuCl
6 CuCl + 3/2 O2 + 3 H2O → 2 Cu3Cl2(OH)4 + CuCl2

Copper(I) chloride catalyzes a variety of organic reactions, as discussed above. Its affinity for carbon monoxide in the presence of aluminium chloride is exploited in the COPureSM process.

In organic synthesis

CuCl is used with carbon monoxide, aluminium chloride, and hydrogen chloride in the Gatterman-Koch reaction to form benzaldehydes.

In the Sandmeyer reaction.[11] Treatment of an arenediazonium salt with CuCl leads to an aryl chloride, for example:

The reaction has wide scope and usually gives good yields.

Early investigators observed that copper(I) halides catalyse 1,4-addition of Grignard reagents to alpha,beta-unsaturated ketones[12] led to the development of organocuprate reagents that are widely used today in organic synthesis:[13]

This finding led to the development of organocopper chemistry. For example, CuCl reacts with methyllithium (CH3Li) to form "Gilman reagents" such as (CH3)2CuLi, which find extensive use in organic synthesis. Grignard reagents form similar organocopper compounds. Although other copper(I) compounds such as copper(I) iodide are now more often used for these types of reactions, copper(I) chloride is still recommended in some cases:[14]

Here, Bu indicates an n-butyl group. Without CuCl, the Grignard reagent alone gives a mixture of 1,2- and 1,4-addition products (i.e., the butyl adds at the C closer to the C=O).

Copper(I) chloride is also an intermediate formed from copper(II) chloride in the Wacker process.

In polymer chemistry

CuCl is used as a catalyst in Atom Transfer Radical Polymerization (ATRP).

References

  1. ↑ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  2. 1 2 3 "NIOSH Pocket Guide to Chemical Hazards #0150". National Institute for Occupational Safety and Health (NIOSH).
  3. ↑ United States Patent US4582579 "method of preparing cupric ion free cuprous chloride" Section 2, lines 4-41 , via www.freepatentsonline.com
  4. ↑ Boyle, Robert (1666). Considerations and experiments about the origin of forms and qualities. Oxford. As reported in Mellor.
  5. ↑ Proust, J. L. (1799). Ann. Chim. Phys. (1) 32: 26. Missing or empty |title= (help)
  6. ↑ Martin, Geoffrey (1917). Industrial and Manufacturing Chemistry (Part 1, Organic ed.). London: Crosby Lockwood. pp. 330–31.
  7. ↑ Lewes, Vivian H. (1891). "Journal of the Society of Chemical Industry". Journal of the Society of Chemical Industry 10: 407–413.
  8. ↑ O. Glemser and H. SauerR "Copper(I) Chloride" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1005.
  9. ↑ Nicholls, D. Complexes and First-Row Transition Elements, Macmillan Press, London, 1973.
  10. ↑ Greenwood, N.N.; Earnshaw, A. Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.
  11. ↑ (a) Wade, L. G. Organic Chemistry, 5th ed., p. 871, Prentice Hall, Upper Saddle RIver, New Jersey, 2003. (b) March, J. Advanced Organic Chemistry, 4th ed., p. 723, Wiley, New York, 1992.
  12. ↑ Kharasch, M. S; Tawney, P. O (1941). "Factors Determining the Course and Mechanisms of Grignard Reactions. II. The Effect of Metallic Compounds on the Reaction between Isophorone and Methylmagnesium Bromide". J. Am. Chem. Soc. 63 (9): 2308. doi:10.1021/ja01854a005.
  13. ↑ Jasrzebski, J. T. B. H.; van Koten, G. in Modern Organocopper Chemistry, (N. Krause, ed.), p. 1, Wiley-VCH, Weinheim, Germany, 2002.
  14. ↑ (a) Bertz, S. H.; Fairchild, E. H. in Handbook of Reagents for Organic Synthesis, Volume 1: Reagents, Auxiliaries and Catalysts for C-C Bond Formation, (R. M. Coates, S. E. Denmark, eds.), pp. 220-3, Wiley, New York, 1999. (b) Munch-Petersen, J., et al., Acta Chimica Scand., 15, 277 (1961).

Further reading

  1. Mellor, J. W., A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Volume III, pp157–168. Longmans, Green & Co., London, 1967 (new impression).

External links

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