δ18O

In geochemistry, paleoclimatology and paleoceanography δ¹⁸O or delta-O-18 is a measure of the ratio of stable isotopes oxygen-18 (¹⁸O) and oxygen-16 (¹⁶O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis. In paleosciences, ¹⁸O:¹⁶O data from corals, foraminifera and ice cores are used as a proxy for temperature.

The definition is, in "per mil" (‰, parts per thousand):

$\delta ^{18}O = \Biggl( \frac{\bigl( \frac{^{18}O}{^{16}O} \bigr)_{sample}}{\bigl( \frac{^{18}O}{^{16}O} \bigr)_{standard}} -1 \Biggr) * 1000\ ^{o}\!/\!_{oo}$

where the standard has a known isotopic composition, such as Vienna Standard Mean Ocean Water (VSMOW).^[1] The fractionation can arise from kinetic, equilibrium, or mass-independent fractionation.

Mechanism

Foraminifera samples.

Foraminifera shells are composed of calcium carbonate (CaCO₃) and are found in many common geological environments. The ratio of ¹⁸O to ¹⁶O in the shell is used to indirectly determine the temperature of the surrounding water at the time the shell was formed. The ratio varies slightly depending on the temperature of the surrounding water, as well as other factors such as the water's salinity, and the volume of water locked up in ice sheets.

δ¹⁸O also reflects local evaporation and freshwater input, as rainwater is ¹⁶O enriched—a result of the preferential evaporation of the lighter ¹⁶O from seawater. Consequently, the surface ocean contains greater amounts of ¹⁸O around the subtropics and tropics where there is more evaporation, and lesser amounts of ¹⁸O in the mid-latitudes where it rains more.

Similarly, when water vapor condenses, heavier water molecules holding ¹⁸O atoms tend to condense and precipitate first. The water vapor gradient heading from the tropics to the poles gradually becomes more and more depleted of ¹⁸O. Snow falling in Canada has much less H₂¹⁸O than rain in Florida; similarly, snow falling in the center of ice sheets has a lighter δ¹⁸O signature than that at its margins, since heavier ¹⁸O precipitates first.

Changes in climate that alter global patterns of evaporation and precipitation therefore change the background δ¹⁸O ratio.

Extrapolation of temperature

Based on the simplifying assumption that the signal can be attributed to temperature change alone, with the effects of salinity and ice volume change ignored, Epstein et al. (1953) estimated that a δ¹⁸O increase of 0.22‰ is equivalent to a cooling of 1 K (i.e. one degree on the °C scale, or 1.8 degrees on the °F scale).^[2] More precisely, Epstein et al. (1953) give a quadratic extrapolation for the temperature, as

$t = 16.5 - 4.3\mathrm{\delta} + 0.14 \mathrm{\delta^2}$

where t is the temperature in °C (based on a least-squares fit for a range of temperature values between 9°C and 29°C, with a standard deviation of ±0.6°C, and δ is δ¹⁸O for a calcium carbonate sample).

Paleoclimatology

Climate record as reconstructed by Lisiecki and Raymo (2005)

Lisiecki and Raymo (2005) used measurements of δ¹⁸O in benthic foraminifera from 57 globally distributed deep sea sediment cores, taken as a proxy for the total global mass of glacial ice sheets, to reconstruct the climate for the past five million years.^[3]

The stacked record of the 57 cores was orbitally tuned to an orbitally driven ice model, the Milankovitch cycles of 41 ky (obliquity), 26 ky (precession) and 100 ky (eccentricity), which are all assumed to cause orbital forcing of global ice volume. Over the past million years, there have been a number of very strong strong glacial maxima and minima, spaced by roughly 100 ky. As the observed isotopoe variatons are similar in shape to the temperature variations recorded for the past 420 ky at Vostok Station, the figure shown on the right aligns the values of δ¹⁸O (right scale) with the reported temperature variations from the Vostok ice core (left scale), following Petit et al. (1999).

See also

• δ¹³C
• δ¹⁵N
• Isotopic signature
• Isotope analysis
• Isotope geochemistry

References

1. "USGS -- Isotope Tracers -- Resources -- Isotope Geochemistry". Retrieved 2009-01-18.
2. Epstein, S., Buchsbaum, R., Lowenstam, H. & Urey, H. "Revised carbonate-water isotopic temperature scale", Geol. Soc. Am. Bull. 64 (1953), 1315–1325.
3. Lisiecki, L. E.; Raymo, M. E. (January 2005). "A Pliocene-Pleistocene stack of 57 globally distributed benthic δ¹⁸O records" (PDF). Paleoceanography 20: PA1003. Bibcode:2005PalOc..20.1003L. doi:10.1029/2004PA001071.
   Lisiecki, L. E.; Raymo, M. E. (May 2005). "Correction to "A Pliocene-Pleistocene stack of 57 globally distributed benthic δ¹⁸O records"". Paleoceanography 20 (2): PA2007. Bibcode:2005PalOc..20.2007L. doi:10.1029/2005PA001164.
   data: doi:10.1594/PANGAEA.704257.

• Clark, I.D. and Fritz, P (1997). Environmental Isotopes in Hydrogeology. CRC Press. ISBN 1-56670-249-6.
• Schmidt, G.A. (1999). "Forward Modeling of Carbonate Proxy Data from Planktonic Foraminifera Using Oxygen Isotope Tracers in a Global Ocean Model". Paleoceanography 14 (4): 482–497. Bibcode:1999PalOc..14..482S. doi:10.1029/1999PA900025.