Dithionous acid

Dithionous acid

Names
IUPAC name Dithionous acid
Other names Hydrosulfurous acid; Hyposulfurous acid
Identifiers
CAS Number	15959-26-9
ChEBI	CHEBI:29253
ChemSpider	22898
Jmol interactive 3D	Image
PubChem	24490
InChI InChI=1S/H2O4S2/c1-5(2)6(3)4/h(H,1,2)(H,3,4) Key: GRWZHXKQBITJKP-UHFFFAOYSA-N InChI=1/H2O4S2/c1-5(2)6(3)4/h(H,1,2)(H,3,4) Key: GRWZHXKQBITJKP-UHFFFAOYAX
SMILES O=S(O)S(=O)O
Properties
Chemical formula	H2S2O4
Molar mass	130.144 g/mol
Acidity (pKa)	0.35, 2.45 [1]
Related compounds
Related compounds	Oxalic acid Sodium dithionite Potassium dithionite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Dithionous acid is a sulfur oxoacid with the chemical formula H₂S₂O₄. It is unstable in pure form,^[2] but its salts, known as dithionites, are stable.

It was initially assumed that the C₂ symmetric structure HOS(=O)-S(=O)OH is the most stable among molecules with the formula H
2S
2O
4 using ab initio calculations.^[3] The reason for this is the existence of intermolecular hydrogen bonds. It is now known that dithionous acid spontaneously decomposes to SO₂ and S(OH)₂.

Sodium dithionite is a white powder used as a reductant and a bleaching agent. It is also used to reduce the nitro group to an amino group in organic reactions.

See also

• Potassium dithionite
• Sodium dithionite

References

1. Catherine E. Housecroft; Alan G. Sharpe (2008). "Chapter 16: The group 16 elements". Inorganic Chemistry, 3rd Edition. Pearson. p. 520. ISBN 978-0-13-175553-6.
2. Drozdova, Yana; Steudel, Ralf; Hertwig, Roland H.; Koch, Wolfram; Steiger, Thomas (1998). "Structures and Energies of Various Isomers of Dithionous Acid, H2S2O4, and of Its Anion HS2O4- 1". The Journal of Physical Chemistry A 102 (6): 990. doi:10.1021/jp972658d.
3. Drozdova, Y.; Steudel, R.; Hertwig, R. H.; Koch, W.; Steiger, T. J. Phys. Chem. A 1998, 102, 990-996. DOI: 10.1021/jp972658d