Exxon Donor Solvent Process

Exxon donor solvent process
Process type Chemical
Industrial sector(s) Chemical industry
Oil industry
Feedstock Coal
Product(s) Synthetic fuel
Leading companies Carter Oil
Year of invention 1966
Developer(s) Exxon Research and Engineering Company

Exxon Donor Solvent Process was a coal liquefaction process developed by Exxon Research and Engineering Company. The process converts solid coal directly to liquid synthetic fuels which could be used as a substitute for petroleum products. The process does not involve an intermediate step of coal gasification.

History

Exxon started to develop this process in 1966 and the development process continued until 1976.[1] By 1975, the process was used in 1/2-tons per day pilot plant.[2] In 1977, preparations to build the demonstration-scale 250-tons per day plant in Baytown, Texas. The plant was opened in April 1980.[2] The plant was built by Carter Oil, an affiliate of Exxon Corporation later renamed Exxon Coal, U.S.A.[3] The plant was financed by the United States Department of Energy and by the private investors Carter Oil, Electric Power Research Institute, Japan Coal Liquefaction Development Company, Phillips Coal Company, ARCO Coal Company, Ruhrkohle and Agip.[4] The plant was closed and dismantled in 1982.[2][5] Originally Exxon planned to open its first commercial scale plant in 1997;[1] however, this plan was abandoned.

Process

In the EDS process is a non-catalytic processing of solvent-slurried coal in the high-pressure liquefaction reactor. Coal is cleaned, crushed and fed to the slurry drier. After drying the crushed coal is slurried with the hydrogen donor recycle solvent. After that, the coal slurry is treated with hydrogen and heated in the liquefaction slurry furnace. The next step is the liquefaction at the temperature of 840 °F (449 °C) and the pressure of 2,000 pounds per square inch (14,000 kPa). The process produces product gas and liquids. After separation of gas from liquids and remaining solids, the gas is cooled to separate vaporized naptha, scrubbed to remove ammonia, hydrogen gas, and carbon monoxide. The remaining gas is treated with hydrogen, and reused in the liquefaction reactor. Liquids, remaining solids and condensate from the process gas are treated in fractionators for separating naptha, a spent solvent, and vacuum gas oil. Naptha is processed into different hydrocarbon products while spent solvent hydrogenated before reusing in the slurry drier.[1] By this process from one short ton (0.907 t) of dry, high volatile coal could be produced more than 2.6 barrels (0.41 m3) of a synthetic fuel.[6]

Initially, the process was focused to be used for bituminous coals but it was tested also for lower grade coals, such as lignite.[7] Pilot testings show that lignite was harder to process than bituminous coals and it resulted a lower oil yield.[8]

References

  1. 1 2 3 McGuckin, John (February 1982). "Technical Report. Exxon Donor Solvent Coal Liquefaction Process" (PDF). United States Environmental Protection Agency. Retrieved 2016-04-11.
  2. 1 2 3 Kent, James A. (2013). Riegel's Handbook of Industrial Chemistry (9 ed.). Springer Science & Business Media. p. 574. ISBN 9781475764314.
  3. ↑ Probstein, Ronald F.; Hicks, R. Edwin (2013). Synthetic Fuels. Dover Books on Aeronautical Engineering. Courier Corporation. p. 301. ISBN 9780486319339.
  4. ↑ Maa, Peter S.; Trachte, Ken L.; Williams, Richard D. (2013). "Solvent Effects in Exxon Donor-Solvent Coal Liquefaction". In Schlosberg, Richard H. Chemistry of Coal Conversion. Springer Science & Business Media. p. 317. ISBN 9781489936325.
  5. ↑ Lee, Sunggyu; Speight, James G.; Loyalka, Sudarshan K. (2014). Handbook of Alternative Fuel Technologies. Green Chemistry and Chemical Engineering (2 ed.). CRC Press. pp. 100–101. ISBN 9781466594562.
  6. ↑ Neavel, R. C.; Knights, C. F.; Schulz, H. (1981-03-20). "Exxon Donor Solvent Liquefaction Process". Philosophical Transactions of the Royal Society A: Mathematical, Physical & Engineering Sciences (Royal Society) 300 (1453). doi:10.1098/rsta.1981.0055. ISSN 1471-2962.
  7. ↑ Mitchell, Willard N.; Trachte, Kenneth L.; Zaczepinski, Sam (1979). "Performance of Low Rank Coals in the Exxon Donor Solvent Process". Industrial & Engineering Chemistry Product Research and Development (ACS Publications) 18 (4): 311–314. doi:10.1021/i360072a016.
  8. ↑ Schobert, Harold H. (1995). Lignites of North America. Coal Science and Technology 23. Elsevier. p. 641. ISBN 9780080544625.
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