Edenite
| Edenite | |
|---|---|
|
Edenite crystal from Bancroft District, Ontario | |
| General | |
| Category | Inosilicate, amphibole |
| Formula (repeating unit) | NaCa2Mg5(Si7Al)O22(OH)2 |
| Crystal symmetry |
Monoclinic prismatic H-M symbol: (2/m) Space group: C 2/m |
| Unit cell | a = 9.83 Å, b = 17.95 Å, c = 5.3 Å, β = 105.18°; Z=2 |
| Identification | |
| Formula mass | 834.25 g |
| Color | White to gray, pale to dark green, also brown and pale pinkish-brown |
| Crystal habit | Prismatic crystals, fibrous, as reaction rims on pyroxenes |
| Crystal system | Monoclinic |
| Twinning | Simple or multiple parallel to {010} |
| Cleavage | Good on (110) |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 5–6 |
| Luster | Vitreous |
| Streak | White |
| Diaphaneity | Semitransparent |
| Specific gravity | 3.05 - 3.37 |
| Optical properties | Biaxial (+) |
| Refractive index | nα = 1.606 - 1.649, nβ = 1.617 - 1.660, nγ = 1.631 - 1.672 |
| Birefringence | δ = 0.025 |
| Pleochroism | Distinct, greens, blue-greens, and yellow-browns |
| 2V angle | 50–82° |
| References | [1][2][3][4] |
Edenite is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described.[3]
Occurrence
Edenite has been found primarily in metamorphic rocks, occurring in pods of other magnesium rich minerals within a marble formation or with garnet rich lherzolites from deep within the Earth's crust.[5][6] Thus, finding edenite in the field can indicate high temperature regional metamorphism of the surrounding rocks.
Uses and importance
While edenite is not important for commercial or industrial applications, it is often studied because of its unique chemical substitution properties. Results from research performed on amphiboles have shown that edenite is particularly suited for fitting chlorine anions into its chemical framework.[7] This makes edenite a good candidate for use in chlorine isotope fractionation in amphibole-bearing rocks. Many synthetic variations of edenite are also used in geochemical research to produce a boron analogue of fluroedenite.[8]
Crystal habit
Edenite is a member of the monoclinic crystal system and is in the crystal class 2/m (space group C2/m).[5] This means crystalline edenite is symmetrical around a two-fold rotation axis that is then reflected across a mirror plane perpendicular to the long axis of the mineral.[9]
Optical properties
Edenite is a biaxial positive mineral. When viewed in thin section with a petrographic microscope, it is white-gray with pale green pleochorism in plane-polarized light. Under crossed polars, its interference colors range from first order gray to first order blue.[2]
References
- ↑ Edenite Handbook of Mineralogy
- 1 2 Edenite on Mindat.org
- 1 2 Edenite on Webmineral
- ↑ IMA Master List
- 1 2 Oberti, R., Cámara, F., Della Ventura, G., Iezzi, G., and Benimoff, A.I. (2006). "Parvo-mangano-edenite, parvo-manganotremolite, and the solid solution between Ca and Mn2+ at the M4 site in amphiboles" (PDF). American Mineralogist 91 (4): 526–532. doi:10.2138/am.2006.1905.
- ↑ Yang, J. (2003). "Relict edenite in a garnet lherzolite from the Chinese Su-Lu UHP metamorphic terrane: Implications for metamorphic history" (PDF). American Mineralogist 88: 180–188.
- ↑ Oberti, R., Hawthorne, F.C., Cannillo, E., and Cámara, F. (2007). "Long-Range Order in Amphiboles". Reviews in Mineralogy and Geochemistry 67: 125–171. doi:10.2138/rmg.2007.67.4.
- ↑ Oberti, R., Della Ventura, G., and Cámara, F. (2007). "New Amphibole Compositions: Natural and Synthetic". Reviews in Mineralogy and Geochemistry 67: 89–124. doi:10.2138/rmg.2007.67.3.
- ↑ Klein, C., and Dutrow, B. (2007) The 23rd Edition of the Manual of Mineral Science, John Wiley and Sons, Inc. Hoboken, New Jersey, U.S..