Helium trimer

The helium trimer is a weakly bound molecule consisting of three helium atoms. Van der Waals forces link the atoms together. The combination of three atoms is much more stable than the two atom helium dimer. The three atom combination of helium-4 atoms is an Efimov state.[1][2] Helium-3 is predicted to form a trimer, although ground state dimers containing helium-3 are completely unstable.[3]

Helium trimer molecules have been produced by expanding cold helium gas from a nozzle into a vacuum chamber. Such a set up also produces the helium dimer and other helium atom clusters. The existence of the molecule was proven by matter wave diffraction on a diffraction grating.[4] The kind of grating used needs to have empty space between the bars, so that molecules can pass through, glass would stop helium. Properties of the molecules can be discovered by Coulomb explosion imaging[4] in which a laser ionizes all three atoms simultaneously, and then three ions fly apart and are then detected.

The helium trimer is large, being more than 100 Å, which is even larger than the helium dimer. The atoms are not arranged in a equilateral triangle as might be expected, but form random shaped triangles.[5]

Interatomic Coulombic decay can occur when one atom is ionised and excited. It can transfer energy to another atom in the trimer, even though they are separated. However this is much more likely to occur when the atoms are close together, and so the interatomic distances measured by this vary with half full height from 3.3 to 12 Å. The predicted mean distance for Interatomic Coulombic decay in 4He3 is 10.4 Å. For 3He4He2 this distance is even larger at 20.5 Å.[6]

References

  1. ↑ Kolganova, Elena A. (26 Nov 2010). "Helium Trimer in the Framework of Faddeev Approach" (PDF). Physics of Particles and Nuclei. pp. 1108–1110. doi:10.1134/S1063779610070282. Retrieved 28 February 2015.
  2. ↑ Kolganova, E. A.; Motovilov, A. K.; Sandhas, W. (4 May 2011). "The 4He Trimer as an Efimov System". Few-Body Systems 51 (2–4): 249–257. arXiv:1104.1989. Bibcode:2011FBS....51..249K. doi:10.1007/s00601-011-0233-x.
  3. ↑ Al Taisan, Nada Ahmed (May 2013). Spectroscopic Detection of the Lithium Helium (LiHe) van der Waals Molecule (PDF) (Thesis).
  4. 1 2 Kunitski, M.; Zeller, S.; Voigtsberger, J.; Kalinin, A.; Schmidt, L. P. H.; Schoffler, M.; Czasch, A.; Schollkopf, W.; Grisenti, R. E.; Jahnke, T.; Blume, D.; Dorner, R. (30 April 2015). "Observation of the Efimov state of the helium trimer". Science 348 (6234): 551–555. doi:10.1126/science.aaa5601.
  5. ↑ Goethe University Frankfurt (30 April 2015). "Efimov state in the helium trimer observed". Retrieved 2 May 2015.
  6. ↑ Kolorenč, Přemysl; Sisourat, Nicolas (14 December 2015). "Interatomic Coulombic decay widths of helium trimer: Ab initio calculations". The Journal of Chemical Physics 143 (22): 224310. doi:10.1063/1.4936897.

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