Isopropyl iodide
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| Names | |
|---|---|
| IUPAC name
2-Iodopropane[1] | |
| Identifiers | |
75-30-9  | |
| 1098244 | |
| ChemSpider | 6122  |
| EC Number | 200-859-3 |
| Jmol interactive 3D | Image |
| MeSH | isopropyl+iodide |
| PubChem | 6362 |
| RTECS number | TZ4200000 |
| UN number | 2392 |
| |
| |
| Properties | |
| C3H7I | |
| Molar mass | 169.99 g·mol−1 |
| Appearance | Colourless liquid |
| Density | 1.703 g mL−1 |
| Melting point | −90.00 °C; −130.00 °F; 183.15 K |
| Boiling point | 88.8 to 89.8 °C; 191.7 to 193.5 °F; 361.9 to 362.9 K |
| 1.4 g L−1 (at 12.5 °C) | |
| Solubility in chloroform | Miscible |
| Solubility in ethanol | Miscible |
| Solubility in diethyl ether | Miscible |
| Solubility in benzene | Miscible |
| Henry's law constant (kH) |
890 nmol Pa−1 kg−1 |
| Refractive index (nD) |
1.4997 |
| Viscosity | 6.971 mPa (at 20 °C) |
| Thermochemistry | |
| 137.3 J K−1 mol−1 | |
| Std enthalpy of formation (ΔfH |
−77.2–−72.6 kJ mol−1 |
| Hazards | |
| GHS pictograms |   |
| GHS signal word | WARNING |
| H226, H302 | |
| EU classification (DSD) |
 Xn |
| R-phrases | R10, R22 |
| S-phrases | S36/37 |
| Flash point | 42 °C (108 °F; 315 K) |
| Related compounds | |
| Related alkanes |
|
| Related compounds |
Diiodohydroxypropane |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| verify (what is ?) | |
| Infobox references | |
Isopropyl iodide is the organoiodine compound with the formula (CH3)2CHI. It is colorless, flammable, and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of iodine.
Preparation
Isopropyl iodide is prepared by iodination of isopropyl alcohol using hydrogen iodide or, equivalently, with a mixture of glycerol, iodine, and phosphorus.[2] An alternative preparation involves the reaction of 2-propyl bromide with an acetone solution of potassium iodide (KI):[3]
- (CH3)2CHBr + KI → (CH3)2CHI + KBr
References
- ↑ "isopropyl iodide - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 27 March 2005. Identification and Related Records. Retrieved 3 March 2012.
- ↑ Merck Index of Chemicals and Drugs, 9th ed., monograph 5074
- ↑ Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989
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