James Napier
James Napier may refer to:
- James Napier (chemist) (1810–1884), Scottish chemist and antiquarian
- James Napier (actor) (born 1982), New Zealand actor
- James Robert Napier (1821–1879), Scottish engineer, inventor of Napier's diagram
- Jim Napier (born 1938), baseball catcher and manager
- James "Jimmy Napes" Napier, British songwriter, producer and musician
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