| Secretary | Position | Year Appointed | Administration |
| Government |
| Corazon Aquino | President of the Philippines | 1986 | Herself |
| Gloria Macapagal-Arroyo | President of the Philippines | 2001 | Herself |
| Gloria Macapagal-Arroyo | Vice President of the Philippines | 1998 | Joseph Estrada |
| Secretary of Budget and Management |
| Emilia T. Boncodin | Secretary of Budget and Management | 1998 | Fidel Ramos |
| Emilia T. Boncodin | Secretary of Budget and Management | 2001 | Gloria Macapagal-Arroyo |
| Secretary of Education |
| Lourdes Sevilla Quisumbung | Secretary of Education, Culture and Sports | 1998 | Corazon Aquino |
| Erlinda C. Perifanco | Secretary of Education, Culture and Sports | 1986 | Fidel Ramos |
| Secretary of Environment and Natural Resources |
| Elisea G. Gozun | Secretary of Environment and Natural Resources | 2002 | Gloria Macapagal-Arroyo |
| Secretary of Finance |
| Juanita Dy Amatong | Secretary of Finance | 2003 | Gloria Macapagal-Arroyo |
| Secretary of Foreign Affairs |
| Gloria Macapagal-Arroyo | Secretary of Foreign Affairs | 2002 | Herself |
| Gloria Macapagal-Arroyo | Secretary of Foreign Affairs | 2003 | Herself |
| Delia Domingo Albert | Secretary of Foreign Affairs | 2003 | Gloria Macapagal-Arroyo |
| Secretary of Health |
| Carmencita Reodica | Secretary of Health | 1996 | Fidel Ramos |
| Carmencita Reodica | Secretary of Health | 1998 | Joseph Estrada |
| Dr. Esperanza Cabral | Secretary of Health | 2010 | Gloria Macapagal-Arroyo |
| Dr. Janette Garin | Secretary of Health | 2014 | Benigno Aquino III |
| Secretary of Justice |
| Leila de Lima | Secretary of Justice | 2010 | Benigno Aquino III |
| Secretary of Labour and Employment |
|
| Marie Nieves E. Confessor | Secretary of Labour | 1992 | Corazon Aquino |
| Patricia Sto. Tomas | Secretary of Labour and Employment | 2001 | Gloria Macapagal-Arroyo |
| Rosalinda Baldoz | Secretary of Labour and Employment | 2010 | Benigno Aquino III |
| Secretary of National Defense |
| Gloria Macapagal-Arroyo | Secretary of National Defense | 2003 | Herself |
| Gloria Macapagal-Arroyo | Secretary of National Defense | 2006 | Herself |
| Secretary of Science and Technology |
| Estrella F. Alabastro | Secretary of Science and Technology | 2001 | Gloria Macapagal-Arroyo |
| Estrella F. Alabastro | Secretary of Science and Technology | 2010 | Gloria Macapagal-Arroyo |
| Secretary of Social Welfare and Development |
| Estefania Aldaba-Lim | Secretary of Social Welfare | 1972 | Ferdinand Marcos |
| Imelda Romualdez Marcos | Minister of Human Settlements | 1978 | Ferdinand Marcos |
| Sylvia P. Montes | Minister of Social Services and Development | 1978 | Ferdinand Marcos |
| Dr. Mita Pardo de Tavera | Minister/Secretary of Social Welfare and Development | 1986 | Corazon Aquino |
| Corazon Alma C. de Leon | Secretary of Social Welfare and Development | 1992 | Fidel Ramos |
| Lilian Laigo | Secretary of Social Welfare and Development | 1995 | Fidel Ramos |
| Gloria Macapagal-Arroyo | Secretary of Social Welfare and Development | 1998 | Joseph Estrada |
| Dulce Saguisag | Secretary of Social Welfare and Development | 2000 | Joseph Estrada |
| Corazon Julian N. Soliman | Secretary of Social Welfare and Development | 2001 | Gloria Macapagal-Arroyo |
| Dr. Esperanza Cabral | Secretary of Social Welfare and Development | 2006 | Gloria Macapagal-Arroyo |
| Corazon Julian N. Soliman | Secretary of Social Welfare and Development | 2010 | Gloria Macapagal-Arroyo |
| Secretary of Tourism |
| Narzalina Lim | Secretary of Tourism | 1987 | Corazon Aquino |
| Mina Gabor | Secretary of Tourism | 1996 | Fidel Ramos |
| Gemma Teresa Guerrero Cruz Araneta | Secretary of Tourism | 1998 | Joseph Estrada |
| Presidential Spokesperson |
| Anabella T. Abaya | Presidential Spokesperson | 1992 | Fidel Ramos |
| Executive Secretary |
| Luz Cleta Reyes-Bakunawa | Executive Secretary | 1987 | Corazon Aquino |
| Chairman of the Commission on Higher Education |
| Patricia Licuanan | Chairman of the Commission on Higher Education | 2010 | Benigno Aquino III |
| Presidential Management Staff |
| Ma. Leonora Vasquez-de Jesus, Ph.D. | Chief of the Presidential Management Staff | 1992 | Fidel Ramos |
| Ma. Leonora Vasquez-de Jesus, Ph.D. | Chief of the Presidential Management Staff | 1998 | Joseph Estrada |
| Julia Abad | Chief of the Presidential Management Staff | 2010 | Benigno Aquino III |
| Cabinet Secretary |
| Ma. Leonora Vasquez-de Jesus, Ph.D. | Cabinet Secretary | 1992 | Fidel Ramos |
| Ma. Leonora Vasquez-de Jesus, Ph.D. | Cabinet Secretary | 1998 | Joseph Estrada |
| Housing and Urban Development Coordinating Council |
| Ma. Leonora Vasquez-de Jesus, Ph.D. | Chairman of the Housing and Urban Development Coordinating Council | 2000 | Joseph Estrada |
| Secretary of Socio-economic Planning/Director General of National Economic and Development Authority |
| Solita Collas-Monsod | Director General of National Economic and Development Authority and
Minister/Secretary of Economic Planning | 1986 | Corazon Aquino |