| Picture |
Viceroy |
From |
Until |
Monarch |
|
 | Don Antonio de Mendoza,
Marquis of Mondéjar, Count of Tendilla | 14 November 1535 | 25 November 1550 | 
Charles I |
 | Don Luís de Velasco,
| 25 November 1550 | 31 July 1564 |
 | Francisco Ceinos,
Dean of the Audiencia | 1 August 1564 | 19 October 1566 | 
Philip II |
 | Don Gastón Carrillo de Peralta y Bosquete,
Third Marquis of Falces | 19 October 1566 | 11 November 1567 |
| Licenciado Alonso de Muñoz and
Licenciado Luís Carrillo | 11 November 1567 | April 1568 |
| Licenciado Alonso de Muñoz | April 1568 | 14 April 1568 |
| Francisco Ceinos,
Dean of the Audiencia | 14 April 1568 | 4 November 1568 |
 | Don Martín Enríquez de Almanza | 5 November 1568 | 4 October 1580 |
 | Don Lorenzo Suárez de Mendoza,
Fourth Count of La Coruña | 4 October 1580 | 19 June 1583 |
| | Luís de Villanueva y Zapata,
Dean of the Audiencia | 19 June 1583 | 24 September 1584 |
 | Pedro de Moya y Contrerás
(Archbishop of Mexico) | 25 September 1584 | 17 October 1585 |
 | Don Álvaro Manrique de Zúñiga
First Marquis of Villamanrique | 17 October 1585 | 27 January 1590 |
 | Don Luís de Velasco
Marquis of Salinas | 27 January 1590 | 5 November 1595 |
 | Don Gaspar de Zúñiga Acevedo y Fonseca,
Fifth Count of Monterrey | 5 November 1595 | 27 October 1603 |
 | Don Juan de Mendoza y Luna,
Marquis of Montesclaros | 27 October 1603 | 2 July 1607 | 
Philip III |
| | Don Luís de Velasco,
Marquis of Salinas | 2 July 1607 | 19 June 1611 |
 | García Guerra, O.P.
(Archbishop of Mexico) | 19 June 1611 | 22 February 1612 |
| | Pedro Otárola,
Dean of the Audiencia | 22 February 1612 | 18 October 1612 |
 | Don Diego Fernández de Córdoba,
Marquis of Guadalcázar and Count of Posadas | 18 October 1612 | 14 March 1621 |
| Paz de Valecillo,
Dean of the Audiencia | 14 March 1621 | 11 September 1621 |
 | Don Diego Carrillo de Mendoza y Pimentel,
First Marquis of Gélves | 12 September 1621 | 1 November 1624 | 
Philip IV |
Vacant
Due to the discrepancy on the arrival of successor Viceroy
from 1 November to 3 November 1624. |
 | Don Rodrigo Pacheco y Osorio de Toledo,
Third Marquis of Cerralvo | 3 November 1624 | 16 September 1635 |
 | Don Lope Díez de Aux de Armendáriz,
Marquis of Cadereyta | 16 September 1635 | 28 August 1640 |
 | Don Diego Roque López Pacheco Cabrera y Bobadilla,
Seventh Duke of Escalona, Seventh Marquis of Villena and Seventh Count of Xiquena | 28 August 1640 | 10 June 1642 |
 | DonJuan de Palafox y Mendoza
(Bishop of Puebla) | 10 June 1642 | 23 November 1642 |
 | Don García Sarmiento de Sotomayor,
Second Count of Salvatierra and Marquis of Sobroso | 23 November 1642 | 14 May 1648 |
 | Marcos de Torres y Rueda
(Bishop of Yucatan) | 15 May 1648 | 22 April 1649 |
| | Matías de Peralta,
Dean of the Audiencia | 22 April 1649 | 28 June 1650 |
 | Don Luis Enríquez de Guzmán,
Ninth Count of Alba de Liste and Marquis of Villaflor | 28 June 1650 | 15 August 1653 |
 | Don Francisco Fernández de la Cueva,
Eighth Duke of Alburquerque, Marquis of Cuéllar, Count of Ledesma and of Huelma | 15 August 1653 | 16 September 1660 |
 | Don Juan de Leyva de la Cerda,
Count of Baños and Marquis of Leyva and of Ladrada | 16 September 1660 | 29 June 1664 |
 | Diego Osorio de Escobar y Llamas
(Bishop of Puebla) | 29 June 1664 | 15 October 1664 |
 | Don Antonio Sebastián de Toledo Molina y Salazar,
Second Marquis of Mancera | 16 October 1664 | 20 November 1673 |
 | Don Pedro Nuño Colón de Portugal y Castro,
Sixth Duke of Veragua, Sixth Marquis of Jamaica and Sixth Count of Gelves | 20 November 1673 | 13 December 1673 | 
Charles II |
 | Payo Enríquez de Rivera Manrique, O.S.A.
(Bishop of Guatemala and Archbishop of Mexico) | 13 December 1673 | 7 November 1680 |
 | Don Tomás Antonio Manuel Lorenzo de la Cerda y Aragón
Third Marquis of La Laguna de Camero Viejo | 7 November 1680 | 16 June 1686 |
 | Don Melchor Portocarrero y Lasso de la Vega,
Third Count of Monclova | 16 June 1686 | 20 November 1688 |
 | Don Gaspar Melchor Baltasar de la Cerda Silva Sandoval y Mendoza,
Eighth Count of Galve, Lord of Salcedón and Tortola | 20 November 1688 | 27 February 1696 |
 | Juan de Ortega Cano Montañez y Patiño
(Bishop of Durango, Guatemala, Michoacán and Archbishop of Mexico) | 27 February 1696 | 18 December 1696 |
 | Don José Sarmiento y Valladares,
Count of Moctezuma and of Tula | 18 December 1696 | 4 November 1701 |
| | Juan de Ortega Cano Montañez y Patiño
(Archbishop of Mexico) | 4 November 1701 | 27 November 1702 | 
Philip V |
 | Don Francisco V Fernández de la Cueva Enríquez y Fernández de la Cueva,
Tenth Duke of Alburquerque and Marquis of Cuéllar | 27 November 1702 | 13 November 1710 |
 | Don Fernando de Alencastre Noroña y Silva,
First Duke of Linares and Marquis of Valdefuentes | 13 November 1710 | 16 July 1716 |
 | Don Baltasar de Zúñiga Guzmán Sotomayor y Mendoza,
Duke of Arión and Marquis of Valero | 16 July 1716 | 15 October 1722 |
 | Don Juan de Acuña y Bejarano,
Second Marquis of Casa Fuerte | 15 October 1722 | 17 March 1734 | 
Louis I
From 1700–1724, Philip V of Spain was the king; then from 1724–1746. Louis I only reigned in 1724. |
 | Juan Antonio de Vizarrón y Eguiarreta
(Archbishop of Mexico) | 17 March 1734 | 17 August 1740 |
Philip V |
 | Don Pedro de Castro Figueroa y Salazar,
First Duke of La Conquista and First Marquis of Gracia Real | 17 August 1740 | 22 August 1741 |
_Version_with_Golden_Fleece_and_Holy_Spirit_Collars.svg.png) | Pedro Malo de Villavicencio,
President of the Audiencia | 23 August 1741 | 2 November 1742 |
 | Don Pedro Cebrián y Agustín,
Fifth Count of Fuenclara | 3 November 1742 | 9 July 1746 |
 | Don Juan Francisco de Güemes y Horcasitas,
First Count of Revillagigedo | 9 July 1746 | 9 November 1755 | 
Ferdinand VI |
 | Don Agustín de Ahumada y Villalón,
Marquis of Amarillas | 10 November 1755 | 5 February 1760 |
| | Francisco Antonio de Echávarri,
Dean of the Audiencia | 5 February 1760 | 28 April 1760 |
 | Francisco Cajigal de la Vega | 28 April 1760 | 5 October 1760 | 
Charles III |
 | Don Joaquín de Montserrat,
Marquis of Cruillas | 5 October 1760 | 24 August 1766 |
 | Don Carlos Francisco de Croix,
Marquis of Croix | 24 August 1766 | 22 September 1771 |
 | Don Antonio María de Bucareli y Ursúa,
Marquis of Valleheroso and Count of Jerena | 22 September 1771 | 9 April 1779 |
| | Francisco Romá y Rosell,
Regent of the Audiencia | 10 April 1779 | 22 August 1779 |
 | Martín de Mayorga Ferrer,
Captain General of Guatemala | 23 August 1779 | 28 April 1783 |
 | Matías de Gálvez y Gallardo,
Captain General of Guatemala | 28 April 1783 | 20 October 1784 |
| | Vicente de Herrera y Rivero,
Regent of the Audiencia | 20 October 1784 | 17 June 1785 |
 | Don Bernardo de Gálvez y Madrid,
Viscount of Galveston and Count of Gálvez | 17 June 1785 | 30 November 1786 |
| | Eusebio Sánchez Pareja y Beleño
Regent of the Audiencia | 30 November 1786 | 8 May 1787 |
 | Alonso Núñez de Haro y Peralta
(Archbishop of Mexico) | 8 May 1787 | 16 August 1787 |
 | Manuel Antonio Flores Maldonado Martínez Ángulo y Bodquín | 16 August 1787 | 16 October 1789 |
 | Don Juan Vicente de Güemes Pacheco de Padilla y Horcasitas,
Second Count of Revillagigedo | 17 October 1789 | 11 July 1794 | 
Charles IV |
 | Don Miguel de la Grúa Talamanca de Carini y Branciforte,
First Marquis of Branciforte | 12 July 1794 | 31 May 1798 |
 | Don Miguel José de Azanza,
Duke of Santa Fe | 31 May 1798 | 30 April 1800 |
 | Félix Berenguer de Marquina | 30 April 1800 | 4 January 1803 |
 | José de Iturrigaray | 4 January 1803 | 16 September 1808 |
 | Pedro de Garibay | 16 September 1808 | 19 July 1809 | 
Joseph Bonaparte |
 | Francisco Javier de Lizana y Beaumont
(Archbishop of Mexico) | 19 July 1809 | 8 May 1810 | _by_Goya.jpg)
Ferdinand VII |
_Version_with_Golden_Fleece_and_Order_of_Charles_III_Collars.svg.png) | Pedro Catani | 8 May 1810 | 14 September 1810 |
 | Don Francisco Javier Venegas,
Marquess of Reunión and of New Spain | 14 September 1810 | 4 March 1813 |
 | Don Félix María Calleja del Rey,
First Count of Calderón | 4 March 1813 | 20 September 1816 |
 | Don Juan Ruiz de Apodaca,
First Count of Venadito | 20 September 1816 | 5 July 1821 |
 | Francisco Novella Azabal Pérez y Sicardo | 15 July 1821 | 21 July 1821 |
 | Juan O'Donojú | 21 July 1821 | 28 September 1821 |