Mercuric amidochloride
 | |
| Names | |
|---|---|
| IUPAC name
mercuric azanide chloride | |
| Other names
mercuric amidochloride mercury(II) amide chloride mercury(II) amidochloride ammoniated mercury | |
| Identifiers | |
10124-48-8  | |
| ChemSpider | 21106343 |
| Jmol interactive 3D | Image |
| PubChem | 3032553 |
| UNII | JD546Z56F0  |
| |
| |
| Properties | |
| ClH2HgN | |
| Molar mass | 252.065 g/mol |
| Density | 5.56 g/cm3 |
| Pharmacology | |
| ATC code | D08 |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| verify (what is ?) | |
| Infobox references | |
Mercuric amidochloride is an inorganic compound with the formula HgNH2Cl. It consists of a zig-zag 1-dimensional polymer (HgNH2)n with chloride counterions.[1][2] It arises from the reaction of ammonia and mercuric chloride. Addition of base converts it into "Millon's base," which has the formula [Hg2N]OH(H2O)x. A variety of related amido and nitrido materials with chloride, bromide, and hydroxide are known.[3]
Before the toxicity of mercury was appreciated, mercuric amidochloride, known as "ammoniated mercury", was used as a topical antiseptic and disinfectant.[4][5]
Eli Lilly & Company - Ointment No. 8 - Ammoniated Mercury 10%
See also
- Merbromin, also known as "Mercurochrome", another antiseptic mercury compound
- Thiomersal, another antiseptic mercury compound
References
- ↑ Wells, A.F. (1984). Structural Inorganic Chemistry. Oxford: Clarendon Press. ISBN 0-19-855370-6.
- ↑ Lipscomb, W. N. (1951). "The structure of mercuric amidochloride, HgNH2Cl". Acta Crystallographica 4 (3): 266–8. doi:10.1107/S0365110X51000866.
- ↑ Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.
- ↑ Aberer W, Gerstner G, Pehamberger H (September 1990). "Ammoniated mercury ointment: outdated but still in use". Contact Dermatitis 23 (3): 168–71. doi:10.1111/j.1600-0536.1990.tb04778.x. PMID 2149317.
- ↑ http://www.huidziekten.nl/allergie/stoffen/mercury-ammonium-chloride.htm[]
| ||||||||||||||||||||||||
This article is issued from Wikipedia - version of the Monday, November 30, 2015. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.