Mercury regulation in the United States

Mercury regulation in the United States is a set of laws and regulations limiting the maximum concentrations of mercury (Hg) that is permitted in air, water, soil, food and drugs. These laws and regulations are promulgated by U.S. Federal Agencies such as the Environmental Protection Agency, (EPA) Food and Drug Administration (FDA) as well as a variety of State and local authorities.

What is mercury

Forms of mercury

Mercury occurs naturally in the environment and exists in a large number of forms. In pure form, it is known alternatively as “elemental” or “metallic” mercury. Elemental mercury is a shiny, silver-white metal that is liquid at room temperature. It is not found in this form in nature, however, but in compounds and inorganic salts. If not sealed off, mercury slowly evaporates into the air, forming a vapor. The quantity of vapor formed increases as temperatures rise. Elemental mercury is traditionally used in thermometers and some electrical switches.

Inorganic mercury compounds or mercury salts, more commonly found in nature, include mercuric sulphide (HgS), mercuric oxide (HgO) and mercuric chloride (HgCl2). Most of these are white powders or crystals, except for mercuric sulphide which is red and turns black after exposure to light.

Organic mercury is formed when mercury combines with carbon and other elements. Examples of organic mercury compounds are dimethylmercury, phenylmercuric acetate, and methylmercuric chloride. The form most commonly found in the environment is methylmercury.

How mercury exists in the environment

Elemental mercury in the atmosphere can undergo transformation into inorganic mercury forms, providing a significant pathway for deposition of emitted elemental mercury.

Some micro-organisms can produce organic mercury, particularly methylmercury, from other mercury forms. Methylmercury can accumulate in living organisms and reach high levels in fish and marine mammals via a process called biomagnification (i.e. concentrations increase in the food chain).

Being an element, mercury cannot be broken down or degraded into harmless substances. Mercury may change between different states and species in its cycle, but its simplest form is elemental mercury, which itself is harmful to humans and the environment. Once mercury has been liberated from either ores or from fossil fuel and mineral deposits hidden in the earth’s crust and released into the biosphere, it can be highly mobile, cycling between the earth’s surface and the atmosphere. The earth’s surface soils, water bodies and bottom sediments are thought to be the primary biospheric sinks for mercury.

Mercury speciation

The different forms mercury exists in (such as elemental mercury vapour, methylmercury, or mercuric chloride) are commonly designated “species”. As mentioned above, the main groups of mercury species are elemental mercury, inorganic and organic mercury forms. Speciation is the term commonly used to represent the distribution of a quantity of mercury among various species.

Speciation influences the transport of mercury within and between environmental compartments including the atmosphere and oceans, among others. For example, the speciation is a determining factor for how far from the source mercury emitted to air is transported. Mercury adsorbed on particles and ionic (e.g., divalent) mercury compounds will fall on land and water mainly in the vicinity of the sources (local to regional distances), while elemental mercury vapour is transported on a hemispherical/global scale making mercury emissions a global concern. Another example is the so-called "polar sunrise mercury depletion incidence", where the transformation of elemental mercury to divalent mercury is influenced by increased solar activity and the presence of ice crystals, resulting in a substantial increase in mercury deposition during a three-month period (approximately March to June).

Moreover, speciation determines how to control mercury emissions to air. For example, emissions of inorganic mercuric compounds (such as mercuric chloride) are captured reasonably well by some control devices (such as wet-scrubbers), while capture of elemental mercury tends to be low for most emission control devices.

Sources of mercury

The releases of mercury to the biosphere can be grouped in four categories:[1]

The majority of atmospheric anthropogenic emissions are released as gaseous elemental mercury. The atmospheric residence time of elemental mercury is in the range of months to roughly one year. This makes transport on a hemispherical scale possible and emissions in any continent can thus contribute to the deposition in other continents. Current estimates are that less than half of all mercury deposition within the U.S. comes from U.S. sources.[2][3]

Anthropogenic sources

The largest emissions of mercury to the global atmosphere occur from combustion of fossil fuels; mainly coal in utility, industrial, and residential boilers. As much as two thirds of the total emission of ca. 2269 tonnes of mercury emitted from all anthropogenic sources worldwide in 2000 came from combustion of fossil fuels.[4] Other anthropogenic sources of mercury include: cement production (mercury in lime), mining (iron/steel, zinc, gold), use of fluorescent lamps, various instruments and dental amalgam fillings, manufacturing of products containing mercury (thermometers, manometers and other instruments, electrical and electronic switches) and waste disposal.[5]

Exposure to mercury

Mercury in the air eventually settles into water or onto land where it can be washed into water. Once deposited, certain microorganisms can change it into methylmercury, a highly toxic form that builds up in fish, shellfish and animals that eat fish. The general population is primarily exposed to methylmercury through the diet (especially fish) and to elemental mercury vapors due to dental amalgams. Depending on local mercury pollution load, substantial additional contributions to the intake of total mercury can occur through air and water.

Health effects

Almost all people have at least trace amounts of methylmercury in their tissues, reflecting methylmercury’s widespread presence in the environment and people’s exposure through the consumption of fish and shellfish. Although the presence of Mercury is quite common, most people remain below the levels that can lead to contamination or poisoning.[6]

For fetuses, infants, and children, the primary health effect of methylmercury is impaired neurological development. Methylmercury exposure in the womb, which can result from a mother's consumption of fish and shellfish that contain methylmercury, can adversely affect a baby's growing brain and nervous system (see: Minamata disease). Impacts on cognitive thinking, memory, attention, language, and fine motor and visual spatial skills have been seen in children exposed to methylmercury in the womb.[7][8]

Elemental (metallic) mercury primarily causes health effects when it is breathed as a vapor where it can be absorbed through the lungs. These exposures can occur when elemental mercury is spilled or products that contain elemental mercury break and expose mercury to the air, particularly in warm or poorly ventilated indoor spaces.[9][10] emotional changes (e.g., mood swings, irritability, nervousness, excessive shyness); insomnia; neuromuscular changes (such as weakness, muscle atrophy, twitching); headaches; disturbances in sensations; changes in nerve responses; performance deficits on tests of cognitive function.[11][12] At higher exposures there may be kidney effects, respiratory failure and death.

For methylmercury, the US Environmental Protection Agency (US EPA) has estimated a safe daily intake level of 0.1 µg/kg body weight per day.[13]

The National Institute for Occupational Safety and Health (NIOSH)recommends that exposures to mercury metal be limited to an average of 0.05 mg/m3 over a 10-hour workday in addition to a ceiling limit of 0.1 mg/m3. The American Concerence of Governmental Industrial Hygienists (ACGIH) recommends that metallic mercury exposures be limited to an average of 0.025 mg/m3 over an 8-hour workday[14]

Environmental effects

A very important factor in the impacts of mercury to the environment is its ability to build up in organisms and up along the food chain. All forms of mercury can accumulate in organisms. However, methylmercury is taken up at a faster rate than other forms and bioaccumulates to a greater extent. The biomagnification of methylmercury has a most significant influence on the impact on animals and humans. Fish appear to bind methylmercury strongly, nearly 100 percent of mercury that bioaccumulates in predator fish is methylmercury.[15] Consequently, the elimination of methylmercury from fish is very slow. Given steady environmental concentrations, mercury concentrations in individuals of a given fish species tend to increase with age as a result of the slow elimination of methylmercury and increased intake due to changes in trophic position that often occur as fish grow to larger sizes.[16]

While much is generally known about mercury bioaccumulation and biomagnification, the process is extremely complex and involves complicated biogeochemical cycling and ecological interactions. As a result, although accumulation/magnification can be observed, the extent of mercury biomagnification in fish is not easily predicted across different sites.[17]

Several exposure pathways are possible for both plants and animals in terrestrial systems. The two main pathways by which terrestrial plants can be exposed to mercury are uptake from soils into the roots and absorption directly from the air. Potential exposure routes for terrestrial animals include the following: (1) ingestion of mercury-contaminated food; (2) direct contact with contaminated soil; (3) ingestion of mercury-contaminated drinking water; and (4) inhalation.[18]

U.S. regulations to prevent mercury contamination

Regulations governing use of mercury

Regulations associated with mercury use in commerce impose costs, conditions, and/or restrictions associated with obtaining, selling, using, or transporting mercury. The following categories describe mercury use regulations: (1) commerce-related regulations such as taxes and transportation requirements; (2) product-related restrictions; and (3) reporting requirements.

Mercury use regulations affect only those facilities that use mercury as an input. They do not affect those sources that release mercury incidentally as a by-product.

Commerce-related regulations

Commerce Type Regulation[19] Law or Example Mercury Information Regulatory Mechanism
Obtaining Mercury Excise Tax Internal Revenue Code of 1986 (26 USCA §4661) The Internal Revenue Code imposes taxes on 40 chemicals, including mercury, that are sold by the manufacturer, producer, or importer . The tax rate for mercury is $4.45/ton, the second highest tax rate listed (10 substances have the highest tax rate of $4.87/ton). Input/sales tax
Import Tax Harmonized Tariff Schedule of the United States Mercury and several mercury compounds are subject to import taxes under the Harmonized Tariff Schedule of the United States, which identifies import taxes on all goods imported into the United States from most-favored-nation (MFN) countries, as well as from special treaty nations and non-most-favored-nation (non-MFN) countries. For 1994, the tax rate for mercury imports from MFN countries is 16.5 ¢/kg, compared to a 55.1 ¢/kg tax on imports from non-MFN countries (item 2805.40). Due to special treaty agreements, no duty is imposed on mercury imports from Canada, Israel, Bolivia, Colombia, Ecuador, and Caribbean Basin countries. Tax
Government Mercury Stockpile Sales Strategic and Critical Materials Stockpile Act (50 USCA §98) The Strategic and Critical Materials Stockpile Act regulates mercury that the Defense Logistics Agency (DLA) sells from the National Defense Stockpile. The amount of mercury sold from the stockpile has the potential to affect the mercury market, although DLA considers its impact on the market when requesting Congressional authorization for sales. DLA accepts daily bids for mercury. Over the last year, the price of DLA mercury has ranged from $57 – 82 per flask. Command & Control
Transporting Mercury Transportation The Hazardous Materials Transportation Act The Department of Transportation regulates hazardous materials transport under the Hazardous Materials Transportation Act (HMTA). Mercury and mercury compounds are hazardous substances subject to packaging, shipping and transportation rules for hazardous materials. RCRA regulations for hazardous waste transporters incorporate HMTA rules Operating requirements, Labeling
Using Mercury Use restrictions Currently, only Minnesota has a use-restriction law providing that mercury sold in the state will be used only for medical, dental, instructional, research, or manufacturing purposes. Sellers must provide buyers with a material safety data sheet and have the buyer sign a statement of proper use and disposal.

Product-related restrictions

Federal Insecticide, Fungicide and Rodenticide Act (FIFRA)
FIFRA covers the sale and use of pesticides, including registration of chemicals that meet health and safety tests.[19] Until recently, several mercury compounds were registered as pesticides, bactericides, and fungicides. By 1991, however, all registrations for mercury compounds in paints had been canceled by EPA or voluntarily withdrawn by the manufacturer. Registrations for calo-chlor and calo-gran, the last mercury-based pesticides registered for use in the United States (to control pink and grey snow mold) were voluntarily canceled by the manufacturer in November 1993. Existing stocks may be sold until depleted.
Federal Food, Drug, and Cosmetic Act (FFDCA)
The Food and Drug Administration is responsible for mercury in food, drugs, and cosmetics. Mercury use as a preservative or antimicrobial is limited to eye-area cosmetics or ointments in concentrations below 60ppm. Yellow mercuric oxide is not recognized as a safe and effective ophthalmic anti-infective ingredient. The FDA also regulates dental amalgam under FFDCA. Dental mercury is classified as a Class I medical device, with extensive safety regulations on its use. Dental amalgam alloy is classified as a Class II device, subject to additional special controls.
Mercury-Containing and Rechargeable Battery Management Act of 1996
The Mercury-Containing and Rechargeable Battery Management Act of 1996 (Battery Act) phases out the use of mercury in batteries, and provides for the efficient and cost-effective disposal of used nickel cadmium (Ni-Cd) batteries, used small sealed lead-acid (SSLA) batteries, and certain other regulated batteries. The statute applies to battery and product manufacturers, battery waste handlers, and certain battery and product importers and retailers.

Reporting requirements

At a federal level, only facilities that exceed threshold planning quantities for mercury under SARA Title III regulations must report that quantity to their local emergency planning commission. EPA is currently considering a chemical use inventory, which would track the quantities of chemicals used at individual facilities.[19]

Currently, only Michigan has regulations that specifically require facilities to report the quantities of chemicals used. Under the Part 9 rules of Act 245, Michigan's water pollution control act, businesses that use any substance listed on the "Critical Materials Registry" must report the quantities of each substance used and released. Mercury is included the Critical Materials Registry. The state uses this information to assist in permit development and compliance in its water program.

Regulations governing releases of mercury

Regulations associated with releases or mercury into the environment impose costs, conditions, and/or restrictions on activities that incidentally discharge mercury into the environment. The following categories describe mercury release regulations: (1) airborne releases; (2) effluent discharges into waters; (3) hazardous waste disposal; and (4) reporting requirements.

Airborne releases

The primary piece of federal legislation governing the airborne release of mercury in the United States is the Clean Air Act.[20] Unlike the criteria air pollutants, mercury is classified under the Act as a hazardous air pollutant and is thus subject to control under the National Emissions Standards for Hazardous Air Pollutants (NESHAP's) rather than the National Ambient Air Quality Standards (NAAQS). The key distinction is that the former is controlled by establishing performance standards under a program known as maximum achievable control technology standards (MACT), designed to reduce hazardous air pollutant emissions to a maximum achievable degree, by setting a standard at least as stringent as the emission reductions achieved by the average of the top 12% best controlled in the same pollution sources.[21] However, as of early 2011, no federal limits of mercury from coal and oil-fired electric utility steam generating units (EGU's) were on the books. The development of a regulatory policy framework to guide the emissions of mercury from power plants is on-going, the major developments of which have occurred largely within the last decade.

The movement toward the regulation of mercury from EGU's began in December 2000, when the Environmental Protection Agency determined the regulation of coal and oil-fired EGU's to be "appropriate and necessary" under the Clean Air Act, Section 112(c) standards for mercury emissions, adding these units to the list of sources that must be regulated.[22] This push gained further impetus in 2005, when the EPA released a report titled The Nata Inventory Modified for the Toxics Rule 2005 Base Year,[23] which linked 2/3's of the total amount of mercury released in 1990 to three source categories: stationary power plants, municipal waste combustors, and medical waste incinerators.

Additionally, according to the report the two latter categories saw 96% and 98% reductions of total mercury release, respectively, between the 15-year period between 1990 and 2005 while power plant emissions fell by only 10%. By 2005, coal-fired power plants made up the largest single source of airborne mercury emissions.[23]

Given these findings, the EPA reversed its earlier decision by offering a final revision of the 'appropriate and necessary finding' for coal and oil-fired EGUs by ultimately deciding to exclude these units from the 112 list. In its place, the EPA issued a rule to permanently cap and reduce mercury emissions from stationary power facilities.[24] The Clean Air Mercury Rule (CAMR) was designed to reduce emissions of mercury from stationary power plants through a cap-and-trade system of regulations, with the goal of a 70% reduction, from 48 to 15 tons annually. The proposed cap was set to be phased in two distinct phases, the first set at 38 tons annually while the second phase, set to commence 2018, required a cap of 15 tons annually.[25]

In December 2008, the D.C. Court of Appeals vacated the CAMR on the grounds that it illegally exempts utilities from the list of regulated source categories under the MACT standards.[24] On March 16, 2011 EPA proposes Mercury and Air Toxic Standards, the first nationwide limits on coal-fired power plant emissions of mercury. Specifically, the proposal aims to reduce emissions from new and existing coal and oil-fired EGUs by 91% from current levels through national quantity-based, numerical emission limits on mercury releases.[26] As part of this new rule, the EPA is also offering a proposal to "monitor" changes to industrial and commercial steam generating units New Source Performance Standard, but does not propose to change those emission standards.[27] According to the EPA, the Power Plant Mercury and Air Toxics Standards are expected to have broad health benefits (due to reductions in several pollutants, not just mercury), including the prevention in the year 2016 of between 6,800 and 17,000 premature deaths and 11,000 non-fatal heart attacks.[26] The EPA has also announced public hearings throughout the month of May.[28]

Under the Title V Operating Permits program, states may impose emissions fees up to $25/ton of emissions for all chemicals. Facilities releasing mercury are subject to this fee for their mercury emissions. Without a differential fee structure, the fee alone is not likely to be high enough to spur reductions in mercury emissions. For instance, Wisconsin's largest source of mercury air emissions, an electric utility, would only pay $15.90 for its mercury releases (.63 ton @$25/ton).[29]

Many states have operated independently from the federal EPA in setting their own emission reduction targets. In 2007, 18 states proposed more stringent abatement levels than what was proposed at the federal level at the time.[30]

Effluent releases

Clean Water Act regulations specify technology-based effluent limits for classes and categories of industries, and describes the circumstances in which states may require effluent limits or monitoring requirements more stringent than technology-based standards. The Clean Water Act relies on a permit system, known as the National Pollutant Discharge Elimination System (NPDES) to regulate water discharges. Facilities may be assigned a specific mercury discharge limit, or may only be required to monitor their discharge for mercury. Facilities report actual discharge levels in Discharge Monitoring Reports (DMRs), which serve as the basis for determining compliance. .[29] Pretreatment standards regulate industries that discharge into a publicly owned treatment plant (POTW) instead of discharging directly into a receiving water body. Regulations list industrial categories subject to national categorical pretreatment standards for new and existing facilities that discharge into treatment plants. POTWs with approved pretreatment programs may set permit limits and conduct inspections of industrial users. Facilities that do not have specific pretreatment standards for mercury (or other hazardous substances), are supposed to notify the POTW of any hazardous waste discharge that exceeds 100 kg per month. Wastestreams from certain manufacturing processes that may involve mercury, such as fluorescent lamps and switchgear, are excluded from categorical pretreatment standards because they are considered dilute.[29]

Mercury is included in the list of chemicals eligible for removal credits at a POTW. A POTW may allow a facility to discharge a higher quantity of mercury provided that the POTW meets the applicable mercury standard in its sludge without additional costs.[29] Under the Great Lakes Enforcement Strategy, EPA will target violations of daily maximum permit limits. This screening criteria is more stringent than the national definition of significant noncompliance, which targets violations of monthly average limits.[29]

The Clean Water Act stipulates that states should adopt specific water quality standards for their navigable waterways (streams, rivers, wetlands and lakes) and issue permits for discharge under the National Pollution Discharge Elimination System(NPDES).[31] The standards for mercury and other pollutants are set at a level that is reasonably expected not to adversely impact the health of humans or wildlife. Legal entitlements for discharge are granted in the form of permits, but the overall allowable level of discharge is controlled by the EPA.[32] The states may issue permits, but the allowable pollution levels must not exceed the federal standards.[31] Additionally, both the federal EPA and the corresponding environmental regulatory offices at the state level make pertinent information publicly available, which includes the harmful effects of mercury exposure[33] and the times of the year in which it is deemed dangerous to consume biotic organisms (e.g. consumption advisories for fish).[34]

Hazardous Waste

Resource Conservation and Recovery Act (RCRA) regulations outline specific classification and disposal requirements for products and wastes that contain mercury. In general, RCRA regulations are waste-specific, not source-specific, and thus may apply to any facility that generates mercury-containing wastes. RCRA regulations assign specific waste codes to five types of wastes that are either "characteristic" wastes or "listed" wastes. Mercury is both a characteristic and a listed waste under RCRA. [29] RCRA regulations describe specific disposal requirements for individual waste codes. All mercury-bearing wastes (wastewaters and nonwastewaters) are subject to land disposal restrictions. RCRA regulations also influence product disposal and recycling options for mercury containing products [29] On February 23, 2011, following ten years of litigation, the EPA released scaled-back air emission rules for industrial boilers and solid waste incinerators. The recently released final rules address hazardous air pollutant (“HAP”) emission standards for industrial, commercial and institutional boilers and process heaters (the Boiler Maximum Achievable Control Techcnology or "Boiler MACT" rule) and commercial and industrial solid waste incineration units (the “CISWI” rule).[35] Industrial boilers and process heaters burn fuels such as natural gas, biomass, coal and oil to produce heat or electricity; CISWIs burn solid waste. The Boiler MACT rules create emission limits for mercury, particulate matter and carbon monoxide for all new coal-fired boilers with heat input greater than 10 million Btu per hour and particulate matter emission limits for new biomass and oil-fired boilers.[36]

Reporting requirements

Emergency Planning and Community Right-to-Know Act establishes emergency release, inventory, and release reporting requirements. The requirement includes the Toxics Release Inventory (TRI), which requires facilities in the manufacturing sector (SIC codes 20-39) to report releases to air, water, and land for all listed chemicals, including mercury. Other sections require facilities to report spills of listed substances above a threshold reporting quantity (reportable quantities), and the quantities of chemicals stored above a specified threshold planning quantity.[29]

U.S. environmental standards

Media Mercury Standard[19] Explanation
Ambient Water Recommendations for Aquatic Life
  • 1.4 μg/L for freshwater maximum acute concentrations (CMC)
  • 0.77 μg/L for freshwater continuous concentrations (CCC)
  • 1.8 μg/L for saltwater maximum acute concentrations (CMC)
  • 0.94 μg/L for saltwater continuous concentrations (CCC)
  • These recommendations are for methylmercury (MeHg) concentrations; CMC ≡ Criterion Maximum Concentration (acute); CCC ≡ Criterion Continuous Concentration (chronic)[37]
Drinking Water
  • Maximum contaminant level = 0.002 mg/L (40 CFR 141.62)
  • Maximum contaminant level for mercury established under the Safe Drinking Water Act
Groundwater
  • 2 μg/L
Bottled Water
  • 0.002 mg/L (21 CFR 103.35)
Water-level of detect
  • 0.2 μg/L (200 ng/L) = recommended method
  • EPA-approved method to detect Hg in water. Lower detection methods are available, but not yet approved by EPA
Air
  • No ambient standard
Sewage Sludge
  • 17 mg/kg (dry wt) and 17 kg/hectare cumulative loading for sludge applied on agricultural, forest and publicly accessible lands (40 CFR 503, Table 2 of §503.13)
  • 17 mg/kg (dry wt) and .85 kg/hectare annual loading rate for sludge sold or distributed for application to a lawn or home garden (40 CFR 503, Table 3 of §503.13)
  • 57 mg/kg (dry wt) for sludge sold or distributed for other types of land disposal (40 CFR 503, Table 1 of §503.13)
Compost
  • No federal standards
  • Minnesota sets mercury concentration limits incompost
Fish
  • 1 mg/kg
  • 0.3 mg/kg
  • FDA action level for methylmercury
  • EPA maximum recommended fish tissue methylmercury residue based on a total fish consumption rate of 0.0175 kg/day[38]
Hazardous Waste
  • TCLP leachate ≥ 0.2 mg/L (40 CFR 261.24, 264)
  • Land disposal (Subtitle D, nonhazardous landfills) prohibited unless leachate contains less than 0.2 mg/L

Global regulations

Global convention

Convention on Long-range Transboundary Air Pollution and The 1998 Aarhus Protocol on Heavy Metals

Since 1979 the Convention on Long-range Transboundary Air Pollution has addressed some of the major environmental problems of the UNECE region through scientific collaboration and policy negotiation. The Convention has been extended by eight protocols that identify specific measures to be taken by Parties to cut their emissions of air pollutants.[39] The Executive Body adopted the Protocol on Heavy Metals on 24 June 1998 in Aarhus (Denmark). It targets three particularly harmful metals: cadmium, lead and mercury. According to one of the basic obligations, Parties will have to reduce their emissions for these three metals below their levels in 1990 (or an alternative year between 1985 and 1995). The Protocol aims to cut emissions from industrial sources (iron and steel industry, non-ferrous metal industry), combustion processes (power generation, road transport) and waste incineration. It lays down stringent limit values for emissions from stationary sources and suggests best available techniques (BAT) for these sources, such as special filters or scrubbers for combustion sources or mercury-free processes. The Protocol requires Parties to phase out leaded petrol. It also introduces measures to lower heavy metal emissions from other products, such as mercury in batteries, and proposes the introduction of management measures for other mercury-containing products, such as electrical components (thermostats, switches), measuring devices (thermometers, manometers, barometers), fluorescent lamps, dental amalgam, pesticides and paint.[40]

The Basel Convention

The Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal was brought into force in 1992 in order to prevent the transportation of hazardous wastes to developing countries. Over 170 countries have now joined the convention, including Australia who became a member of the Basel Convention on 5 February 1992.[41]

The Rotterdam PIC Convention

The Rotterdam PIC Convention is a means for formally obtaining and disseminating information so that decisions can be made by importing countries as to whether they wish to receive future shipments of certain chemicals and for ensuring compliance with these decisions by exporting countries. The Convention promotes shared responsibility between exporting and importing countries in protecting human health and the environment from the harmful effects of such chemicals and provides for the exchange of information about potentially hazardous chemicals that may be exported and imported. A key goal of the Rotterdam PIC Convention is to provide technical assistance for developing countries and countries with economies in transition to develop the infrastructure and capacity necessary to implement the provisions of the Convention. Substances covered under the Convention: Mercury compounds including inorganic and organometallic mercury compounds.[42]

UNEP Global Mercury Negotiation and Partnership

Global Legally Binding Instrument on Mercury

In February 2009, the Governing Council of UNEP agreed on the need to develop a global legally binding instrument on mercury. Participation in the intergovernmental negotiating committee (INC) is open to all Governments. Following the conclusion of the negotiations, the text will be open for signature at a diplomatic conference (Conference of Plenipotentiaries), which will be held in 2013 in Japan.[43]

UNEP Global Mercury Partnership Action Priorities

Most of the priorities for action to reduce risk from mercury have been defined within partnerships:

Artisanal and small-scale gold mining (ASGM) is a complex global development issue. Reaching out to individual miners is challenging, with an estimated 10-15 million artisanal and small-scale gold miners globally in approximately 70 countries. ASGM is the largest demand sector for mercury globally (estimated at 650-1000 tonnes in 2005). Low mercury and mercury free solutions are available.[44]

Burning of coal is the largest single anthropogenic source of mercury air emissions. Coal burning for power generation is increasing. Although coal contains only small concentrations of mercury, it is burnt in very large volumes. Household burning of coal is also a significant source of mercury emissions and a health hazard. The objective of this partnership area is continued minimization and elimination of mercury releases from coal combustion where possible.[45]

Mercury cell chlor-alkali production is a significant user of mercury and a source of mercury releases to the environment. The mercury used in this process acts as a catalyst in the chlorine production process. Best practices, such as proper waste management, can minimize the release of mercury. Mercury-free technologies are also available in chlor-alkali production.[46]

Transition success has been demonstrated in thermometers, switches and relays, batteries other than button cells, thermostats, HID auto discharge lamps, and sphygmomanometers. Reducing mercury in products may be the most effective means to control mercury in waste. Sound management should consider all stages of the product’s life-cycle. Clear regulation can prompt manufacturers to produce mercury-free products.[47]

Fate and transport research is important in setting and implementing national, regional and global priorities. It also helps establish baselines to monitor and assess progress on mercury reductions.[48]

The management of mercury and mercury-containing waste is the last step in the product life-cycle. The elimination of mercury in products and processes may be the most efficient way to avoid the presence of any form of mercury in waste.[49]

Mercury is an element and cannot be destroyed. Policies designed to decrease the production, use and trade of mercury must be accompanied by access to viable, safe and secure long term storage. Investing in supply, trade, and storage issue is more efficient than trying to control mercury release.[50]

Toolkit for Identification and Quantification of Mercury Releases

The "Toolkit for identification and quantification of mercury releases", the "Mercury Toolkit", is intended to assist countries to develop a mercury releases inventory. It provides a standardized methodology and accompanying database enabling the development of consistent national and regional mercury inventories. National inventories will assist countries to identify and address mercury releases.[51]

See also

References

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  2. ↑ Seigneur C, Vijayaraghavan K, Lohman K, Karamchandani P, Scott C (January 2004). "Global source attribution for mercury deposition in the United States" (PDF). Environ. Sci. Technol. 38 (2): 555–69. doi:10.1021/es034109t. PMID 14750733.
  3. ↑ Travnikov O, Ryaboshapko A. "Modelling of Mercury Hemispheric Transport and Depositions". MSC-E Technical Report 6/2002. Meteorological Synthesizing Centre - East. Retrieved 2011-04-08.
  4. ↑ Pacyna EG, Pacyna JM (July 2006). "Global anthropogenic mercury emission inventory for 2000". Atmospheric Environment 40 (22): 4048–4063. doi:10.1016/j.atmosenv.2006.03.041.
  5. ↑ Pacyna JM, EG Pacyna (2005). "Anthropogenic sources and global inventory of mercury emissions". In Percival JB, Parsons MD. Mercury: sources, measurements, cycles and effects. Ottawa, Ont: Mineralogical Association of Canada. ISBN 0-921294-34-4.
  6. ↑ "Mercury Fact Sheet" (PDF). United States Centers for Disease Control and Prevention (CDC). 2009-11-01. Retrieved 2011-04-09.
  7. ↑ Toxicological effects of methylmercury. Washington, D.C: National Academy Press. 2000. ISBN 0-309-07140-2.
  8. ↑ Steuerwald U, Weihe P, Jørgensen PJ, Bjerve K, Brock J, Heinzow B, Budtz-Jørgensen E, Grandjean P (May 2000). "Maternal seafood diet, methylmercury exposure, and neonatal neurologic function". J. Pediatr. 136 (5): 599–605. doi:10.1067/mpd.2000.102774. PMID 10802490.
  9. ↑ Smith RG, Vorwald AJ, Patil LS, Mooney TF (1970). "Effects of exposure to mercury in the manufacture of chlorine". Am Ind Hyg Assoc J 31 (6): 687–700. doi:10.1080/0002889708506315. PMID 5275968.
  10. ↑ Albers JW, Kallenbach LR, Fine LJ, Langolf GD, Wolfe RA, Donofrio PD, Alessi AG, Stolp-Smith KA, Bromberg MB (November 1988). "Neurological abnormalities associated with remote occupational elemental mercury exposure". Ann. Neurol. 24 (5): 651–9. doi:10.1002/ana.410240510. PMID 2849369.
  11. ↑ Levine SP, Cavender GD, Langolf GD, Albers JW (May 1982). "Elemental mercury exposure: peripheral neurotoxicity". Br J Ind Med 39 (2): 136–9. PMC 1008958. PMID 6279139.
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  14. ↑ https://www.osha.gov/Publications/mercuryexposure_fluorescentbulbs_factsheet.pdf
  15. ↑ Bloom NS, Watras CJ, Hurley JP (1991). "Impact of acidification on the methylmercury cycle of remote seepage lakes". Water, Air, & Soil Pollution 56 (1): 477–491. doi:10.1007/BF00342293.
  16. ↑ "Fate and Transport of Mercury in the Environment" (PDF). Mercury Study Report to Congress, EPA-452/R-97-005. United States Environmental Protection Agency (EPA) Office of Air Quality Planning and Standards and Office of Research and Development. 1997-12-01. Retrieved 2011-04-09.
  17. ↑ United Nations Environment Programme. (2008) Global Mercury Assessment: Summary of the report. Retrieved 4/5/11
  18. ↑ EPA (U.S. Environmental Protection Agency). (1997). Mercury Study Report to Congress. Volume VI: An Ecological Assessment for Anthropogenic Mercury Emissions in the United States. EPA-452/R-97-008. U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards and Office of Research and Development.
  19. 1 2 3 4 "Great Lakes Binational Toxics Strategy". Great Lakes Pollution Prevention and Toxics Reduction. United States Environmental Protection Agency. 2008-09-05. Retrieved 2011-04-07.
  20. ↑ "Mercury Quick Finder". United States Environmental Protection Agency. 2011-05-06. Retrieved 2011-05-08.
  21. ↑ "NESHAPS Maximum Achievable Control Technology (MACT)". United States Environmental Protection Agency. 2008-09-05. Retrieved 2011-05-08.
  22. ↑ "Controlling Power Plant Emissions: Chronology". United States Environmental Protection Agency. 2010-10-01. Retrieved 2011-05-08.
  23. 1 2 "Technology Transfer Network Air Toxics 2005 National-Scale Air Toxics Assessment". United States Environmental Protection Agency. 2011-02-24. Retrieved 2011-05-08.
  24. 1 2 http://www.epa.gov/hg/control_emissions/decision.htm
  25. ↑ http://www.epa.gov/CAMR/
  26. 1 2 http://www.epa.gov/airquality/powerplanttoxics/pdfs/proposalfactsheet.pdf
  27. ↑ http://www.epa.gov/airquality/powerplanttoxics/pdfs/proposal.pdf
  28. ↑ http://www.epa.gov/airquality/powerplanttoxics/actions.html
  29. 1 2 3 4 5 6 7 8 http://www.epa.gov/glnpo/bnsdocs/mercsrce/mercreg.html
  30. ↑ http://ncseonline.org/NLE/CRSreports/07March/RL33535.pdf
  31. 1 2 http://cfpub.epa.gov/npdes/
  32. ↑ http://cfpub.epa.gov/npdes/regs.cfm?program_id=45
  33. ↑ http://www.epa.gov/hg/exposure.htm
  34. ↑ http://water.epa.gov/scitech/swguidance/fishshellfish/fishadvisories/advisories_index.cfm
  35. ↑ Michael Best & Friedrich, LLP (25 February 2011). "EPA Issues Final Boiler MACT Rules". The National Law Review. Retrieved 2011-08-15.
  36. ↑ Hair, Corbin (18 December 2011). "Mercury Falling: Groundbreaking Power Plant Emissions Rule Imminent". The National Law Review. Retrieved 2011-12-21.
  37. ↑ U.S. Environmental Protection Agency National Recommended Water Quality Criteria - Aquatic Life Criteria Table (1995). Retrieved on 2015-12-30.
  38. ↑ U.S. Environmental Protection Agency. National Recommended Water Quality Criteria - Human Health Criteria Table. Retrieved on 2015-12-29.
  39. ↑ United Nations Economic Commission for Europe. Convention on Long-range Transboundary Air Pollution. Retrieved 2011-04-07
  40. ↑ United Nations Economic Commission for Europe. The 1998 Aarhus Protocol on Heavy Metals. Retrieved 2011-04-07
  41. ↑ EWaste. (2010). The Basel Convention – Combating the illegal trafficking of hazardous waste. Retrieved on 2011-04-07
  42. ↑ IISD.org. Introduction to the Rotterdam PIC Convention. Retrieved on 2011-04-07
  43. ↑ United Nations Environment Programme. The Negotiating Process. Retrieved on 2011-04-07
  44. ↑ United Nations Environment Programme. Reducing Mercury in Artisanal and Small-Scale Gold Mining. Retrieved on 2011-04-07.
  45. ↑ United Nations Environment Programme. Mercury Control from Coal Combustion. Retrieved on 2011-04-07.
  46. ↑ United Nations Environment Programme. Mercury Reduction in the Chlor-alkali Sector. Retrieved on 2011-04-07.
  47. ↑ United Nations Environment Programme. Mercury in Products. Retrieved on 2011-04-07.
  48. ↑ United Nations Environment Programme. Mercury Air Transport and Fate Research. Retrieved on 2011-04-07.
  49. ↑ United Nations Environment Programme. Waste management. Retrieved on 2011-04-07.
  50. ↑ United Nations Environment Programme. Supply and Storage. Retrieved on 2011-04-07.
  51. ↑ United Nations Environment Programme. Toolkit for Identification and Quantification of Mercury Releases. Retrieved on 2011-04-07.

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