Micellar solutions

A micellar solution consists of a dispersion of micelles in a solvent (most usually water). Micelles consist of aggregated amphiphiles, and in a micellar solution these are in equilibrium with free, unaggregated amphiphiles. Micellar solutions form when the concentration of amphiphile exceeds the critical micellar concentration (CMC) or critical aggregation concentration - CAC, and persist until the amphiphile concentration becomes sufficiently high to form a lyotropic liquid crystal phase.

Although micelles are often depicted as being spherical, they can be cylindrical or oblate depending on the chemical structure of the amphiphile. Micellar solutions are isotropic phases.

Schematic of a micellar solution showing spherical micelles distributed in water (solvent) and having no long-range positional order.