Niobium triselenide
| Names | |
|---|---|
| IUPAC name
Niobium Triselenide | |
| Identifiers | |
| 12034-78-5 | |
| Properties | |
| NbSe3 | |
| Molar mass | 1292.425 g/mol |
| Appearance | black crystal |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Niobium triselenide is an inorganic compound belonging to the class of transition metal trichalcogenides. It has the formula NbSe3. It was the first reported example of one-dimensional compound to exhibit the phenomenon of sliding charge density waves.[1] Due to its many studies and exhibited phenomena in quantum mechanics, niobium triselenide has become the model system for quasi-1-D charge density waves.
Structure
Although oxidation states are somewhat artificial for semiconductors, they provide a useful way to classify compounds. NbSe3 is viewed as Nb4+(Se2−)(Se22−), i.e., it contains both selenide and diselenide subunits.
The Nb center is bound within a trigonal prismatic Se6 coordination sphere descr The Se---Se bond lengths are 2.37, 2.48, 2.91 Angstroms. The NbSe6 subunits form infinite chains lined up in parallel. Although the prisms share the same coordination, the cell consists of three chain types repeated twice, where each chain is defined by its Se-Se bond length. The high anisotropy of this structure results in the anisotropic crystallization of NbSe3, forming a ribbon-like fibre.[2]
Synthesis
The compound is prepared by Meerschaut and Rouxel via traditional solid state reaction by heating niobium and selenium at 600 to 700 °C:
- Nb + 3 Se → NbSe3
The resulting black crystals can contain NbSe2 impurities which can be purified by chemical vapor transport (CVT) between 650 and 700 °C. The lower limit of CVT was determined by the temperature at which NbSe2 is no longer stable.[3]
Properties
NbSe3 had a significant role in providing evidence for charge density wave (CDW) transport, CDW pinning, magnestism, Shubnikov-de Hass oscillations, and the Aharonov–Bohm effect.
The electrical resitivity of most metallic compounds decrease as temperature decreases. For the most part NbSe3 follows this trend except two anomalities exist where electrical resistivity reaches two local maxima at 145 K (−128 °C) and 59 K (−214 °C). The maxima result in a sharp decrease in electrical conductivity. This observation is explained by the charge density wave formations that open the gaps in the Fermi surface. The opening causes the 1-D linear system to behave more like a semiconductor and less like a metal, a transition commonly known as Peierls transition. NbSe3 continues to be metallic despite the Peierls transition because the charge density wave formation does not completely remove the Fermi surface, a phenomenon known as imperfect Fermi surface nesting.[4]
In the form of nanofibers, NbSe3 exhibits superconductivity below 2 K (−271 °C).
Niobium triselenide has been considered as a cathode material for rechargeable lithium batteries due to its fibrous structure, high electrical conductivity, and high gravimetric and volumetric energy densities at room temperature.[5]
References
- ↑ Monçeau, P.; Ong, N.; Portis, A.; Meerschaut, A.; Rouxel, J. (1976). "Electric Field Breakdown of Charge-Density-Wave—Induced Anomalies in NbSe_{3}". Physical Review Letters 37 (10): 602. doi:10.1103/PhysRevLett.37.602.
- ↑ Gor'kov, L. P.; Grüner, G., eds. (1985). "Transition Metal Trichalcogenides". Modern Problems in Condensed Matter Science [Charge Density Waves in Solids] 25. North-Holland: Elsevier Science Publishers B.V. ISBN 0 444 87370 8.
- ↑ Tang, H.; Li, C.; Yang, X.; Mo, C.; Cao, K.; Yan, F. (2011). "Synthesis and tribological properties of NbSe3 nanofibers and NbSe2 microsheets". Crystal Research and Technology 46 (4): 400. doi:10.1002/crat.201100030.
- ↑ Hodeau, J. L.; Marezio, M.; Roucau, C.; Ayroles, R.; Meerschaut, A.; Rouxel, J.; Monceau, P. (1978). "Charge-density waves in NbSe3 at 145K: Crystal structures, X-ray and electron diffraction studies". Journal of Physics C: Solid State Physics 11 (20): 4117. doi:10.1088/0022-3719/11/20/009.
- ↑ Ratnakumar, B. V.; Stefano, S.; Bankston, C. P. (1989). "A.c. Impedance of niobium triselenide cathode in secondary lithium cells". Journal of Applied Electrochemistry 19 (6): 813. doi:10.1007/BF01007927.