Nitroapocynin

Nitroapocynin
Names
IUPAC name
4-Hydroxy-3-methoxy-5-nitroacetophenone
Other names
Nitroapocynin, 5-nitroapocynin, 1-(4-hydroxy-3-methoxy-5-nitrophenyl)ethanone
Identifiers
20716-41-0
Jmol interactive 3D Image
PubChem 294764
Properties
C9H9NO5
Molar mass 211.17 g·mol−1
Appearance Yellow powder
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Nitroapocynin is a mono-nitrated form of apocynin.

Synthesis

Apocynin can be nitrated with sodium nitrate and acidic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate in acetonitrile solvent.[1][2]

References

  1. Tajik, H.; Niknam, K.; Parsa, F. (2009). "Using acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate in selective nitration of phenols under mild conditions". Journal of the Iranian Chemical Society 6: 159. doi:10.1007/BF03246515.
  2. Babu, Sainath; Raghavamenon, Achuthan C.; Fronczek, Frank R.; Uppu, Rao M. (2009). "4-Hydroxy-3-methoxy-5-nitroacetophenone (5-nitroapocynin)". Acta Crystallographica Section E Structure Reports Online 65 (9): o2292. doi:10.1107/S160053680903390X.
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