Helional
"Helional" is also a brand of the pharmaceutical drug phenobarbital.
Names | |
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IUPAC name
3-(1,3-Benzodioxol-5-yl)-2-methylpropanal | |
Other names
2-Methyl-3-(3,4-methylenedioxyphenyl)propanal; 2-piperonylpropanal Helional Ocean propanal | |
Identifiers | |
1205-17-0 | |
ChemSpider | 58337 |
Jmol 3D model | Interactive image |
PubChem | 64805 |
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Properties | |
C11H12O3 | |
Molar mass | 192.21 g·mol−1 |
Appearance | clear colorless liquid |
Odor | floral, herbaceous |
Density | 1.162 g/ml |
Boiling point | 282°C |
Hazards | |
Safety data sheet | [1] |
GHS pictograms | |
GHS signal word | Warning |
H315, H319, H335 | |
P261, P305+351+338 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Helional (from heliotropin, from which is it commonly derived) is a chemical compound used as a perfume in soap and laundry detergent. Chemically it is an aldehyde with a dihydrocinnamaldehyde motif; a structural element which is present in a number of other important commercial fragrances.
Synthesis
Several synthetic routes exist but the most common is a crossed-aldol condensation between piperonal (heliotropin) and propanal followed by selective hydrogenation of the intermediate alkene. This produces a racemic product.
See Also
References
- ↑ Sigma-Aldrich Co., 2-methyl-3-(3,4-methylenedioxyphenyl)propanal. Retrieved on 2016-03-02.
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