Oxetene
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| Names | |
|---|---|
| IUPAC name
2H-Oxete | |
| Identifiers | |
| 287-25-2 | |
| 4652799 | |
| ChEBI | CHEBI:51195  |
| ChemSpider | 10143952 |
| Jmol interactive 3D | Image |
| PubChem | 11970569 |
| |
| |
| Properties | |
| C3H4O | |
| Molar mass | 56.06326 |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
Oxetene is an unsaturated heterocycle. The compound is unstable and has been synthesized.[1] Compared to oxetane, the saturated compound, oxetene is destabilized because the double bond increases the ring strain. Synthesis of some substituted derivatives has been reported.[2][3]
References
- ↑ Friedrich, Louis;Lam, Yuk-Sun (1981). "Syntheses and reactions of 3-phenyloxete and the parent unsubstituted oxete". The Journal of Organic Chemistry 46 (2): 306–311. doi:10.1021/jo00315a016.
- ↑ Longchar, M.; Bora, U.; Boruah, R. C.; Sandhu, J. S. (2002). "A Convenient Synthesis of Oxetene Via [2+2]Cycloaddition Reaction Under Microwave Irradiation". Synthetic Communications 32 (23): 3611. doi:10.1081/SCC-120014973.
- ↑ Martino, Philip C.; Shevlin, Philip B. (1980). "Oxetene: Synthesis and energetics of electrocyclic ring opening". Journal of the American Chemical Society 102 (16): 5429. doi:10.1021/ja00536a069.
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