Rheopecty

Rheopecty or rheopexy is the rare property of some non-Newtonian fluids to show a time-dependent increase in viscosity (Time Dependent Viscosity); the longer the fluid undergoes shearing force, the higher its viscosity.^[1] Rheopectic fluids, such as some lubricants, thicken or solidify when shaken. The opposite type of behaviour, in which fluids become less viscous the longer they undergo shear, is called thixotropy and is much more common.

Examples of rheopectic fluids include gypsum pastes and printer inks. In the body synovial fluid exhibits the extraordinary property of inverse thixotropy or rheopexy.^[2]

There is ongoing research into new ways to make and use rheopectic materials. There is great interest in possible military uses of this technology. Moreover, the high end of the sports market has also begun to respond to it. Body armor and combat vehicle armor are key areas where efforts are being made to use rheopectic materials. Work is also being done to use these materials in other kinds of protective equipment, which is seen as potentially useful to reduce apparent impact stress in athletics, motor sports, transportation accidents, and all forms of parachuting. In particular, footwear with rheopectic shock absorption is being pursued as a dual-use technology that can provide better support to those who must frequently run, leap, climb, or descend.

Confusion between rheopectic and dilatant fluids

An incorrect example often used to demonstrate rheopecty is cornstarch mixed with water, which resembles a very viscous, white fluid. It is a cheap and simple demonstrator, which can be picked up by hand as a near-solid, but flows easily when not under pressure. However, cornstarch in water is actually a dilatant fluid, since it does not show the time-dependent, shear-induced change required in order to be labeled rheopectic. These terms are often and easily confused since the terms are rarely used; a true rheopectic fluid would when shaken be liquid at first, becoming thicker as shaking continued.

Just as the opposite behaviour of becoming thinner with time is thixotropism (time dependent pseudoplastic behaviour), rheopectic behaviour may be described as time-dependent dilatant behaviour.^[3]

References

1. http://www.bbc.co.uk/science/0/22880407
2. O'Neill, p.l (1996). "The Inverse Thixotropic Behaviour of Synovial Fluid".
3. Sato, Tatsuo (August 1995). "Rheology of suspensions". The Journal of Coatings Technology: 69. Retrieved March 12, 2016.