Trinitrotoluene

"TNT" redirects here. For other uses, see TNT (disambiguation).
Trinitrotoluene
solid trinitrotoluene
Names
IUPAC name
2-Methyl-1,3,5-trinitrobenzene
Other names
2,4,6-Trinitrotoluene,
TNT, Trilite, Tolite, Trinol, Trotyl, Tritolo, Tritolol, Triton, Tritone, Trotol, Trinitrotoluol,
2,4,6-Trinitromethylbenzene
Identifiers
118-96-7 YesY
Abbreviations TNT
ChEMBL ChEMBL1236345 N
ChemSpider 8073 N
DrugBank DB01676 YesY
EC Number 204-289-6
Jmol 3D model Interactive image
KEGG C16391 N
PubChem 11763
RTECS number XU0175000
UNII H43RF5TRM5 YesY
UN number 0209 – Dry or wetted with < 30% water
0388, 0389 – Mixtures with trinitrobenzene, hexanitrostilbene
Properties
C7H5N3O6
Molar mass 227.13 g·mol−1
Appearance Pale yellow solid. Loose "needles", flakes or prills before melt-casting. A solid block after being poured into a casing.
Density 1.654 g/cm3
Melting point 80.35 °C (176.63 °F; 353.50 K)
Boiling point 240.0 °C (464.0 °F; 513.1 K) (decomposes)[1]
0.13 g/L (20 °C)
Solubility in ether, acetone, benzene, pyridine soluble
Vapor pressure 0.0002 mmHg (20°C)[2]
Explosive data
Shock sensitivity Insensitive
Friction sensitivity Insensitive to 353 N
Detonation velocity 6900 m/s
RE factor 1.00
Hazards
Safety data sheet ICSC 0967
E Explosive

T Toxic

N Dangerous for the environment

R-phrases R2, R23/24/25, R33, R51/53
S-phrases (S1/2), S35, S45, S61
NFPA 704
Flammability code 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g., propane Health code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g., chloroform Reactivity code 4: Readily capable of detonation or explosive decomposition at normal temperatures and pressures. E.g., nitroglycerin Special hazards (white): no codeNFPA 704 four-colored diamond
4
2
4
Flash point 167 °C (333 °F; 440 K)
Lethal dose or concentration (LD, LC):
795 mg/kg (rat, oral)
660 (mouse, oral)[3]
500 mg/kg (rabbit, oral)
1850 mg/kg (cat, oral)[3]
US health exposure limits (NIOSH):
PEL (Permissible)
 TWA 1.5 mg/m3 [skin][2]
REL (Recommended)
 TWA 0.5 mg/m3 [skin][2]
IDLH (Immediate danger)
 500 mg/m3[2]
Related compounds
Related compounds
 picric acid
hexanitrobenzene
2,4-Dinitrotoluene
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Trinitrotoluene (/ˌtraɪˌnaɪtroʊˈtɒljuːˌiːn, -ljəˌwiːn/;[4][5] TNT), or more specifically 2,4,6-trinitrotoluene, is a chemical compound with the formula C6H2(NO2)3CH3. This yellow-colored solid is sometimes used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard measure of bombs and other explosives. In chemistry, TNT is used to generate charge transfer salts.

While the two words are sometimes used interchangeably in common conversation, TNT is not the same as dynamite, a special formatting of nitroglycerin for use as an industrial explosive.

History

Trinitrotoluene melting at 81 °C
M107 artillery shells. All are labelled to indicate a filling of "Comp B" (mixture of TNT and RDX) and have fuzes fitted
Analysis of TNT production by branch of the German army between 1941 and the first quarter of 1944 shown in thousands of tons per month
Detonation of the 500-ton TNT explosive charge as part of Operation Sailor Hat in 1965. The white blast-wave is visible on the water surface and a shock condensation cloud is visible overhead.
World War I-era HE artillery shell for a 9.2 inch howitzer. The red band indicates it is filled and the green band (marked "Trotyl") indicates that the filling is TNT

TNT was first prepared in 1863 by German chemist Julius Wilbrand[6] and originally used as a yellow dye. Its potential as an explosive was not appreciated for several years, mainly because it was so difficult to detonate and because it was less powerful than alternatives. Its explosive properties were first discovered by another German chemist, Carl Haeussermann, in 1891.[7] TNT can be safely poured when liquid into shell cases, and is so insensitive that in 1910, it was exempted from the UK's Explosives Act 1875 and was not considered an explosive for the purposes of manufacture and storage.[8]

The German armed forces adopted it as a filling for artillery shells in 1902. TNT-filled armour-piercing shells would explode after they had penetrated the armour of British capital ships, whereas the British lyddite-filled shells tended to explode upon striking armour, thus expending much of their energy outside the ship.[8] The British started replacing lyddite with TNT in 1907.

The United States Navy continued filling armor-piercing shells with explosive D after some other nations had switched to TNT; but began filling naval mines, bombs, depth charges, and torpedo warheads with burster charges of crude grade B TNT with the color of brown sugar and requiring an explosive booster charge of granular crystallized grade A TNT for detonation. High-explosive shells were filled with grade A TNT, which became preferred for this other use as industrial chemical capacity became available for removing xylene and similar hydrocarbons from the toluene feedstock and other nitrotoluene isomer byproducts from the nitrating reactions.[9]

TNT is still widely used by the United States military, as well as construction companies around the world. The majority of TNT currently used by the US military is manufactured by Radford Army Ammunition Plant near Radford, Virginia.

Preparation

In industry, TNT is produced in a three-step process. First, toluene is nitrated with a mixture of sulfuric and nitric acid to produce mononitrotoluene (MNT). The MNT is separated and then renitrated to dinitrotoluene (DNT). In the final step, the DNT is nitrated to trinitrotoluene (TNT) using an anhydrous mixture of nitric acid and oleum. Nitric acid is consumed by the manufacturing process, but the diluted sulfuric acid can be reconcentrated and reused. After nitration, TNT is stabilized by a process called sulfitation, where the crude TNT is treated with aqueous sodium sulfite solution to remove less stable isomers of TNT and other undesired reaction products. The rinse water from sulphitation is known as red water and is a significant pollutant and waste product of TNT manufacture.[10]

Control of nitrogen oxides in feed nitric acid is very important because free nitrogen dioxide can result in oxidation of the methyl group of toluene. This reaction is highly exothermic and carries with it the risk of a runaway reaction leading to an explosion.

In the laboratory, 2,4,6-trinitrotoluene is produced by a two-step process. A nitrating mixture of concentrated nitric and sulfuric acids is used to nitrate toluene to a mixture of mono- and di-nitrotoluene isomers, with careful cooling to maintain temperature. The nitrated toluenes are then separated, washed with dilute sodium bicarbonate to remove oxides of nitrogen, and then carefully nitrated with a mixture of fuming nitric acid and sulfuric acid. Towards the end of the nitration, the mixture is heated on a steam bath. The trinitrotoluene is separated, washed with a dilute solution of sodium sulfite and then recrystallized from alcohol.

Applications

TNT is one of the most commonly used explosives for military, industrial, and mining applications. TNT has been used in conjunction with hydraulic fracturing, a process used to recover oil and gas from shale formations. The technique involves displacing and detonating nitroglycerin in hydraulically induced fractures followed by wellbore shots using pelletized TNT.[11]

TNT is valued partly because of its insensitivity to shock and friction, with reduced risk of accidental detonation compared to more sensitive explosives such as nitroglycerin. TNT melts at 80 °C (176 °F), far below the temperature at which it will spontaneously detonate, allowing it to be poured or safely combined with other explosives. TNT neither absorbs nor dissolves in water, which allows it to be used effectively in wet environments. To detonate, TNT must be triggered by a pressure wave from a starter explosive, called an explosive booster.

Although blocks of TNT are available in various sizes (e.g. 250 g, 500 g, 1,000 g), it is more commonly encountered in synergistic explosive blends comprising a variable percentage of TNT plus other ingredients. Examples of explosive blends containing TNT include:

Explosive character

Upon detonation, TNT decomposes as follows:

2 C7H5N3O6 → 3 N2 + 5 H2O + 7 CO + 7 C
2 C7H5N3O6 → 3 N2 + 5 H2 + 12 CO + 2 C

The reaction is exothermic but has a high activation energy in the gas phase (~62 kcal/mol). The condensed phases (solid or liquid) show markedly lower activation energies of roughly 35 kcal/mol due to unique bimolecular decomposition routes at elevated densities.[20] Because of the production of carbon, TNT explosions have a sooty appearance. Because TNT has an excess of carbon, explosive mixtures with oxygen-rich compounds can yield more energy per kilogram than TNT alone. During the 20th century, amatol, a mixture of TNT with ammonium nitrate was a widely used military explosive.

TNT can be detonated with a high velocity initiator or by efficient concussion.[21]

For many years, TNT used to be the reference point for the Figure of Insensitivity. TNT had a rating of exactly 100 on the "F of I" scale. The reference has since been changed to a more sensitive explosive called RDX, which has an F of I rating of 80.

Energy content

See also: TNT equivalent
Cross-sectional view of Oerlikon 20 mm cannon shells (dating from circa 1945) showing color codes for TNT and pentolite fillings

The heat of detonation utilized by NIST is 4184 J/g (4.184 MJ/kg).[22] The energy density of TNT is used as a reference-point for many other explosives, including nuclear weapons, the energy content of which is measured in equivalent kilotons (~4.184 terajoules) or megatons (~4.184 petajoules) of TNT. The heat of combustion is 14.5 megajoules per kilogram, which requires that some of the carbon in TNT react with atmospheric oxygen, which does not occur in the initial event.[23]

For comparison, gunpowder contains 3 megajoules per kilogram, dynamite contains 7.5 megajoules per kilogram, and gasoline contains 47.2 megajoules per kilogram (though gasoline requires an oxidant, so an optimized gasoline and O2 mixture contains 10.4 megajoules per kilogram).

Detection

Various methods can be used to detect TNT including optical and electrochemical sensors and explosive-sniffing dogs.

In 2013, researchers from the Indian Institutes of Technology using noble-metal quantum clusters could detect TNT at the sub-zeptomolar (10−18 mol/m3) level.[24]

Safety and toxicity

TNT is poisonous, and skin contact can cause skin irritation, causing the skin to turn a bright yellow-orange color. During the First World War, munition workers who handled the chemical found that their skin turned bright yellow, which resulted in their acquiring the nickname "canary girls" or simply "canaries."

People exposed to TNT over a prolonged period tend to experience anemia and abnormal liver functions. Blood and liver effects, spleen enlargement and other harmful effects on the immune system have also been found in animals that ingested or breathed trinitrotoluene. There is evidence that TNT adversely affects male fertility.[25] TNT is listed as a possible human carcinogen, with carcinogenic effects demonstrated in animal experiments (rat), although effects upon humans so far amount to none [according to IRIS of March 15, 2000].[26] Consumption of TNT produces red urine through the presence of breakdown products and not blood as sometimes believed.[27]

Some military testing grounds are contaminated with TNT. Wastewater from munitions programs including contamination of surface and subsurface waters may be colored pink because of the presence of TNT. Such contamination, called "pink water", may be difficult and expensive to remedy.

TNT is prone to exudation of dinitrotoluenes and other isomers of trinitrotoluene. Even small quantities of such impurities can cause such effect. The effect shows especially in projectiles containing TNT and stored at higher temperatures, e.g. during summer. Exudation of impurities leads to formation of pores and cracks (which in turn cause increased shock sensitivity). Migration of the exudated liquid into the fuze screw thread can form fire channels, increasing the risk of accidental detonations; fuze malfunction can result from the liquids migrating into its mechanism.[28] Calcium silicate is mixed with TNT to mitigate the tendency towards exudation.[29]

Ecological impact

Because of its use in construction and demolition, TNT has become the most widely used explosive, and thus its toxicity is the most characterized and reported. Residual TNT from manufacture, storage, and use can pollute water, soil, atmosphere, and biosphere.

The concentration of TNT in contaminated soil can reach 50 g/kg of soil, where the highest concentrations can be found on or near the surface. In the last decade, the United States Environmental Protection Agency (USEPA) has declared TNT a pollutant whose removal is priority.[30] The USEPA maintains that TNT levels in soil should not exceed 17.2 gram per kilogram of soil and 0.01 milligrams per liter of water.[31]

Aqueous solubility

Dissolution is a measure of the rate that solid TNT in contact with water is dissolved. The relatively low aqueous solubility of TNT causes the dissolution of solid particles to be continuously released to the environment over extended periods of time.[32] Studies have shown that the TNT dissolved slower in saline water than in freshwater. However, when salinity was altered, TNT dissolved at the same speed (Figure 2).[33] Because TNT is moderately soluble in water, it can migrate through subsurface soil, and cause groundwater contamination.[34]

Soil adsorption

Adsorption is a measure of the distribution between soluble and sediment adsorbed contaminants following attainment of equilibrium. TNT and its transformation products are known to adsorb to surface soils and sediments, where they undergo reactive transformation or remained stored.[35] The movement or organic contaminants through soils is a function of their ability to associate with the mobile phase (water) and a stationary phase (soil). Materials that associate strongly with soils move slowly through soil. Materials that associate strongly with water move through water with rates approaching that of ground water movement.

The association constant for TNT with a soil is 2.7 to 11 liters per kilogram of soil.[36] This means that TNT has a one- to tenfold tendency to adhere to soil particulates than not when introduced into the soil.[32] Hydrogen bonding and ion exchange are two suggested mechanisms of adsorption between the nitro functional groups and soil colloids.

The number of functional groups on TNT influences the ability to adsorb into soil. Adsorption coefficient values have been shown to increase with an increase in the number of amino groups. Thus, adsorption of the TNT decomposition product 2,4-diamino-6-nitrotoluene (2,4-DANT) was greater than that for 4-amino-2,6-dinitrotoluene (4-ADNT), which was greater than that for TNT.[32] Lower adsorption coefficients for 2,6-DNT compared to 2,4-DNT can be attributed to the steric hindrance of the NO3 group in the ortho position.

Research has shown that in freshwater environments, with a high abundances of Ca2+, the adsorption of TNT and its transformation products to soils and sediments may be lower than observed in a saline environment, dominated by K+ and Na+. Therefore, when considering the adsorption of TNT, the type of soil or sediment and the ionic composition and strength of the ground water are important factors.[37]

The association constants for TNT and its degradation products with clays have been determined. Clay minerals have a significant effect on the adsorption of energetic compounds. It should be noted that soil properties, such as organic carbon content and cation exchange capacity had significant impacts of the adsorption coefficients reported in the table below.

Additional studies have shown that the mobility of TNT degradation products is likely to be lower “than TNT in subsurface environments where specific adsorption to clay minerals dominates the sorption process.”[37] Thus, the mobility of TNT and its transformation products are dependent on the characteristics of the sorbent.[37] The mobility of TNT in groundwater and soil has been extrapolated from “sorption and desorption isotherm models determined with humic acids, in aquifer sediments, and soils”.[37] From these models, it is predicted that TNT has a low retention and transports readily in the environment.[30]

Compared to other explosives, TNT has a higher association constant with soil, meaning it adheres more with soil than with water. Conversely, other explosives, such as RDX and HMX with low association constants (ranging from 0.06 to 7.3 L/kg and 0 to 1.6 L/kg respectively) can move more rapidly in water.[32]

Chemical breakdown

TNT is a reactive molecule and is particularly prone to react with reduced components of sediments or photodegradation in the presence of sunlight. TNT is thermodynamically and kinetically capable of reacting with a wide number of components of many environmental systems. This includes wholly abiotic reactants, like photons, hydrogen sulfide, Fe2+, or microbial communities, both oxic and anoxic.

Soils with high clay contents or small particle sizes and high total organic carbon content have been shown to promote TNT transformation. Possible TNT transformations include reduction of one, two, or three nitro-moieties to amines and coupling of amino transformation products to form dimers. Formation of the two monoamino transformation products, 2-ADNT and 4-ADNT are energetically favored, and therefore are observed in contaminated soils and ground water. The diamino products are energetically less favorable, and even less likely are the triamino products.

The transformation of TNT is significantly enhanced under anaerobic conditions as well as under highly reducing conditions. TNT transformations in soils can occur both biologically and abiotically.[37]

Photolysis is a major process that impacts the transformation of energetic compounds. The alteration of a molecule in photolysis occurs in the presence of direct absorption of light energy by the transfer of energy from a photosensitized compound. Phototransformation of TNT “results in the formation of nitrobenzenes, benzaldehydes, azodicarboxylic acids, and nitrophenols, as a result of the oxidation of methyl groups, reduction of nitro groups, and dimer formation.”[32]

Evidence of the photolysis of TNT has been seen due to the color change to pink of the wastewaters when exposed to sunlight. Photolysis was more rapid in river water than in distilled water. Ultimately, photolysis affects the fate of TNT primarily in the aquatic environment but could also affect the reaction when exposed to sunlight on the soil surface.[37]

Biodegradation

The ligninolytic physiological phase and manganese peroxidase system of fungi can cause a very limited amount of mineralization of TNT in a liquid culture; though not in soil. An organism capable of the remediation of large amounts of TNT in soil has yet to be discovered.[38] Both wild and transgenic plants can phytoremediate explosives from soil and water.[39]

See also

References

  1. ↑ 2,4,6-Trinitrotoluene. inchem.org
  2. 1 2 3 4 "NIOSH Pocket Guide to Chemical Hazards #0641". National Institute for Occupational Safety and Health (NIOSH).
  3. 1 2 "2,4,6-Trinitrotoluene". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).
  4. ↑ "Trinitrotoluene". Merriam-Webster Dictionary.
  5. ↑ "Trinitrotoluene". Dictionary.com Unabridged. Random House.
  6. ↑ Wilbrand, J. (1863). "Notiz über Trinitrotoluol". Annalen der Chemie und Pharmacie 128 (2): 178–179. doi:10.1002/jlac.18631280206.
  7. ↑ https://books.google.co.uk/books?id=PmuqCHDC3pwC&pg=PA404&lpg=PA404&dq=Trinitrotoluene+History&source=bl&ots=ocKGcd_t0l&sig=-rG8tvuyhdfyYvt9q4kCjGdCXbE&hl=en&sa=X&ved=0ahUKEwj2iPfB7eHLAhWG0RQKHc50Dv44ChDoAQhSMBA#v=onepage&q=Trinitrotoluene%20History&f=false
  8. 1 2 Brown GI (1998). The Big Bang: a History of Explosives. Sutton Publishing. pp. 151–153. ISBN 0-7509-1878-0.
  9. ↑ Fairfield AP (1921). Naval Ordnance. Lord Baltimore Press. pp. 49–52.
  10. ↑ Urbanski T (1964). Chemistry and Technology of Explosives 1. Pergamon Press. pp. 389–91. ISBN 0-08-010238-7.
  11. ↑ Miller, J. S.; Johansen, R. T. (1976). "Fracturing Oil Shale with Explosives for In Situ Recovery." (PDF). Shale Oil, Tar Sand and Related Fuel Sources (American Chemical Society): 151. Retrieved 27 March 2015.
  12. ↑ Campbell J (1985). Naval weapons of World War Two. London: Conway Maritime Press. p. 100. ISBN 978-0-85177-329-2.
  13. ↑ U.S. Explosive Ordnance, Bureau of Ordnance. Washington, D.C.: U.S. Department of the Navy. 1947. p. 580.
  14. ↑ Explosives – Compounds
  15. ↑ Military Specification MIL-C-401
  16. ↑ Cooper PW (1996). Explosives Engineering. Wiley-VCH. ISBN 0-471-18636-8.
  17. ↑ DEPARTMENT OF THE TREASURY:Bureau of Alcohol, Tobacco and Firearms GlobalSecurity.org Retrieved 2011-12-02
  18. ↑ [secondary source] webpages:submarine torpedo explosive Retrieved 2011-12-02
  19. ↑ scribd.com website showing copy of a North American Intelligence document see:page 167 Retrieved 2011-12-02
  20. ↑ Furman et al. (2014), Decomposition of Condensed Phase Energetic Materials: Interplay between Uni- and Bimolecular Mechanisms, J. Am. Chem. Soc., 2014, 136 (11), pp 4192–4200. http://pubs.acs.org/doi/abs/10.1021/ja410020f
  21. ↑ Merck Index, 13th Edition, 9801
  22. ↑ NIST Guide for the Use of the International System of Units (SI): Appendix B8—Factors for Units Listed Alphabetically
  23. ↑ Babrauskas, Vytenis (2003). Ignition Handbook. Issaquah, WA: Fire Science Publishers/Society of Fire Protection Engineers. p. 453. ISBN 0-9728111-3-3.
  24. ↑ Grad, Paul (April 2013). "Quantum clusters serve as ultra-sensitive detectors". Chemical Engineering.
  25. ↑ Toxicological Profile for 2,4,6-Trinitrotoluene. atsdr.cdc.gov
  26. ↑ from U.S. Environmental Protection Agency's Integrated Risk Information System (IRIS) within the NLM Hazardous Substances Databank – Trinitrotoluene
  27. ↑ "2,4,6-Trinitrotoluene" (PDF). Agency for Toxic Substances and Disease Registry. Retrieved 2010-05-17.
  28. ↑ Akhavan J (2004). The Chemistry of Explosives. Royal Society of Chemistry. pp. 11–. ISBN 978-0-85404-640-9.
  29. ↑ "Explosive & Propellant Additives". islandgroup.com.
  30. 1 2 Esteve-Núñez A, Caballero A, Ramos JL (2001). "Biological degradation of 2,4,6-trinitrotoluene". Microbiol. Mol. Biol. Rev. 65 (3): 335–52, table of contents. doi:10.1128/MMBR.65.3.335-352.2001. PMC 99030. PMID 11527999.
  31. ↑ Ayoub K, van Hullebusch ED, Cassir M, Bermond A (2010). "Application of advanced oxidation processes for TNT removal: A review". J. Hazard. Mater. 178 (1-3): 10–28. doi:10.1016/j.jhazmat.2010.02.042. PMID 20347218.
  32. 1 2 3 4 5 Pichte J (2012). "Distribution and Fate of Military Explosives and Propellants in Soil: A Review". Applied and Environmental Soil Science 2012: 1–33. doi:10.1155/2012/617236.
  33. ↑ Brannon JM, Price CB, Yost SL, Hayes C, Porter B (2005). "Comparison of environmental fate and transport process descriptors of explosives in saline and freshwater systems". Mar. Pollut. Bull. 50 (3): 247–51. doi:10.1016/j.marpolbul.2004.10.008. PMID 15757688.
  34. ↑ Halasz A, Groom C, Zhou E, Paquet L, Beaulieu C, Deschamps S, Corriveau A, Thiboutot S, Ampleman G, Dubois C, Hawari J (2002). "Detection of explosives and their degradation products in soil environments". J Chromatogr A 963 (1-2): 411–8. PMID 12187997.
  35. ↑ Douglas TA, Johnson L, Walsh M, Collins C (2009). "A time series investigation of the stability of nitramine and nitroaromatic explosives in surface water samples at ambient temperature". Chemosphere 76 (1): 1–8. doi:10.1016/j.chemosphere.2009.02.050. PMID 19329139.
  36. ↑ Haderlein SB, Weissmahr KW, Schwarzenbach RP (January 1996). "Specific Adsorption of Nitroaromatic Explosives and Pesticides to Clay Minerals". Environmental Science & Technology 30 (2): 612–622. doi:10.1021/es9503701.
  37. 1 2 3 4 5 6 Pennington JC, Brannon JM (February 2002). "Environmental fate of explosives". Thermochimica Acta 384 (1-2): 163–172. doi:10.1016/S0040-6031(01)00801-2.
  38. ↑ Hawari J, Beaudet S, Halasz A, Thiboutot S, Ampleman G (2000). "Microbial degradation of explosives: biotransformation versus mineralization". Appl. Microbiol. Biotechnol. 54 (5): 605–18. doi:10.1007/s002530000445. PMID 11131384.
  39. ↑ Panz K, Miksch K (2012). "Phytoremediation of explosives (TNT, RDX, HMX) by wild-type and transgenic plants". J. Environ. Manage. 113: 85–92. doi:10.1016/j.jenvman.2012.08.016. PMID 22996005.

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