Triphosphane

See also: triphos
Triphosphane
Names
Systematic IUPAC name
Triphosphane[1]
Other names
Triphosphine[2]
Identifiers
13597-70-1 YesY
ChEBI CHEBI:35893 N
ChemSpider 123032 N
Jmol interactive 3D Image
PubChem 139510
Properties
P
3
H
5
Molar mass 97.96099 g·mol−1
Appearance Colourless gas
Related compounds
Other anions
triazane
Related Binary phosphanes
phosphane
diphosphane
Related compounds
triazene
N verify (what is YesYN ?)
Infobox references

Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature:[3]

2 P2H4 → P3H5 + PH3

Samples to date have been contaminated with P2H4 and P4H6 (both branched and linear isomers).[4]

References

  1. "triphosphane (CHEBI:35893)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 7 June 2006. Main. Retrieved 27 September 2011.
  2. "Triphosphine". NIST Chemistry WebBook. USA: National Institute of Standards and Technology. Retrieved 27 September 2011.
  3. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
  4. Marianne Baudler, Klaus Glinka (1993). "Monocyclic and polycyclic phosphines". Chem. Rev. 93: 1623–1667. doi:10.1021/cr00020a010.

External links

This article is issued from Wikipedia - version of the Wednesday, June 24, 2015. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.