Uranyl hydroxide

Uranyl hydroxide
Identifiers

CAS Number	211573-15-8^N
ChemSpider	4576989^N
Jmol interactive 3D	Image
PubChem	5465112
UN number	2909
InChI InChI=1S/2H2O.2O.U/h2*1H2;;;/q;;;;+2/p-2^N Key: VWIQIIGYDAPONF-UHFFFAOYSA-L^N
SMILES O[U](O)(=O)=O
Properties
Chemical formula	UH 2O 4
Molar mass	304.0424 g mol⁻¹
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is ^YN ?)
Infobox references

Uranyl hydroxide is a hydroxide of uranium with the chemical formula UO₂(OH)₂ in the monomeric form and (UO₂)₂(OH)₄ in the dimeric; both forms may exist in normal aqueous media. Uranyl hydroxide hydrate is precipitated as a colloidal yellowcake from oxidized uranium liquors near neutral pH.

Uranyl hydroxide was once used in glassmaking and ceramics in the colouring of the vitreous phases and the preparation of pigments for high temperature firing. The introduction of alkaline diuranates into glasses leads to yellow by transmission, green by reflection; moreover these glasses become dichroic and fluorescent under ultraviolet rays.

Uranyl hydroxide is teratogenic and radioactive.

References

The Structure of the a Form of Uranyl Hydroxide
Alexander, C.A. (2005) "Volatilization of urania under strongly oxidizing conditions," Journal of Nuclear Materials, 346, 312–318.

Uranium compounds

U(II)

U(III)

UCl₃
UI₃
UP
U(OH)₃
UH₃
UN

Organouranium(III) compounds	U(C₅H₅)₃

U(IV)

Organouranium(IV) compounds	U(C₈H₈)₂ U(C₅H₅)₄ U(C₅H₅)₃Cl

U(IV,V)

U₂N₃

U(V)

U(V,VI)

U₃O₈

U(VI)

U(XII)

UO₆ (hypothetical)

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