2D materials

2D Topological Materials, sometimes referred to as Single layer materials, are crystalline materials consisting of a single layer of atoms. Since the isolation of graphene, a single-layer of graphite, in 2004, a large amount of research has been directed at isolating other 2D materials due to their unusual characteristics and for use in applications such as photovoltaics, semiconductors, electrodes and water purification.

2D materials can generally be categorised as either 2D allotropes of various elements or compounds (usually consisting of two covalently bonding elements).[1] The elemental 2D materials generally carry the –ene suffix in their names while the compounds have –ane or -ide suffixes. Layered combinations of different 2D materials are generally called van der Waals heterostructures.

While the first 2D material to be discovered was graphene, in 2004, some 500 2D materials may remain to be found.[2] Research on these other materials has grown more rapidly than that on graphene since 2010.[3]

The global market for 2D materials is expected to reach $390 million USD within a decade, mostly for graphene in the semiconductor, electronics, battery energy and composites markets.[4][5]

2D Allotropes

Graphene

Main article: Graphene
Graphene is an atomic-scale honeycomb lattice of carbon atoms.

Graphene is a crystalline allotrope of carbon in the form of a nearly transparent (to visible light) one atom thick sheet. It is hundreds of times stronger than most steels by weight.[6] It has the highest thermal and electrical conductivity known to man, displaying current densities 1,000,000 times that of copper.[7] It was first produced in 2004.[8]

Andre Geim and Konstantin Novoselov won the 2010 Nobel Prize in Physics "for groundbreaking experiments regarding the two-dimensional material graphene". They first produced it by lifting graphene flakes from bulk graphite with adhesive tape and then transferred them onto a silicon wafer.[9]

Graphyne

Graphyne is another 2-dimensional carbon allotrope whose structure is similar to graphene's. It can be seen as a lattice of benzene rings connected by acetylene bonds. Depending on the content of the acetylene groups, graphyne can be considered a mixed hybridization, spn, where 1 < n < 2,[10][11] and versus graphene's (pure sp2) and diamond (pure sp3).

First-principle calculations using phonon dispersion curves and ab-initio finite temperature, quantum mechanical molecular dynamics simulations showed graphyne and its boron nitride analogues to be stable.[12]

The existence of graphyne was conjectured before 1960.[13] It has not yet been synthesized. However, graphdiyne (graphyne with diacetylene groups) was synthesized on copper substrates.[14] Recently it has been claimed to be a competitor for graphene, due to the potential of direction-dependent Dirac cones.[15][16]

Borophene

B
36° borophene, front and side view

Borophene is a proposed crystalline allotrope of boron. One unit consists of 36 atoms arranged in an 2-dimensional sheet with a hexagonal hole in the middle.[17][18] Borophene has also been synthesized, but with a different crystal structure.[19]

Germanene

Germanene is a two-dimensional allotrope of germanium, with a buckled honeycomb structure.[20] Experimentally synthesized germanene exhibits a honeycomb structure. This honeycomb structure consists of two hexagonal sub-lattices that are vertically displaced by 0.2 A from each other.[21]

Silicene

Structure of a typical silicene cluster showing ripples across the surface.

Silicene is a two-dimensional allotrope of silicon, with a hexagonal honeycomb structure similar to that of graphene.

Stanene

Main article: Stanene

Stanene is a predicted topological insulator that may display dissipationless currents at its edges near room temperature. It is composed of tin atoms arranged in a single layer, in a manner similar to graphene. Its buckled structure leads to high reactivity against common air pollutions such as NOx and COx and is able to trap and dissociate them at low temperature.[22]

Phosphorene

Phosphorene is a 2-dimensional, crystalline allotrope of phosphorus. Its mono-atomic hexagonal structure makes it conceptually similar to graphene. However, phosphorene has substantially different electronic properties; in particular it possesses a nonzero band gap while displaying high electron mobility.[3] This property potentially makes it a better semiconductor than graphene.[23]

Molybdenite

Main article: Molybdenite

Metals

Single atom layers of palladium,[24] and rhodium[25] have also been synthesized.

2D supracrystals

The supracrystals of 2D materials have been proposed and theoretically simulated.[26][27] These monolayer crystals are built of supra atomic periodic structures where atoms in the nodes of the lattice are replaced by symmetric complexes. For example in the hexagonal structure of graphene patterns of 4 or 6 carbon atoms would be arranged hexagonally instead of single atoms, as the repeating node in the unit cell.

3D-topological structures (foams, aerogel substances and materials)

Aerographite

Main article: Aerographite

Aerogel

Main article: Aerogel

Nanogel

Main article: Nanogel

Carbon nanofoam

Main article: Carbon nanofoam

Compounds

Graphane

Graphane

Graphane is a polymer of carbon and hydrogen with the formula unit (CH)
n where n is large. Graphane is a form of fully hydrogenated (on both sides) graphene.[28] Partial hydrogenation is then hydrogenated graphene.[29]

Graphane's carbon bonds are in sp3 configuration, as opposed to graphene's sp2 bond configuration. Thus graphane is a two-dimensional analog of cubic diamond.

The first theoretical description of graphane was reported in 2003[30] and its preparation was reported in 2009.

Graphane can be formed by electrolytic hydrogenation of graphene, few-layer graphene or high-oriented pyrolytic graphite. In the last case mechanical exfoliation of hydrogenated top layers can be used.[31]

p-doped graphane is postulated to be a high-temperature BCS theory superconductor with a Tc above 90 K.[32]

Hexagonal boron nitride

Two alternately stacked layers of hexagonal boron nitride

Boron nitride forms crystals of alternating atoms of boron and nitrogen, with a lattice spacing similar to that of carbon. It therefore also form similar allotropes like carbon, including a graphite-like hexagonal layered structure and graphene-like hexagonal monolayers. Unlike graphene, hexagonal boron nitride is electrically insulating, and can be combined with graphene and other 2D materials to make van der Waals heterostructure devices.

Germanane

Germanane is a single-layer crystal composed of germanium with one hydrogen bonded in the z-direction for each atom.[33] Germanane’s structure is similar to graphane,[34] Bulk germanium does not adopt this structure. Germanane is produced in a two-step route starting with calcium germanide. From this material, the calcium (Ca) is removed by de-intercalation with HCl to give a layered solid with the empirical formula GeH.[35] The Ca sites in Zintyl-phase CaGe
2 interchange with the hydrogen atoms in the HCl solution, producing GeH and CaCl2.

Transition metal Di-chalcogenides (TMDCs)

Molybdenum disulfide

Main article: Molybdenite
Layered structure of MoS
2, with Mo in blue and S in yellow

Molybdenum disulfide is the inorganic compound with the formula MoS
2. In its multilayer form it is a silvery black solid that occurs as the mineral molybdenite, the principal ore for molybdenum.[1] MoS
2 is relatively unreactive. It is unaffected by dilute acids and oxygen. In appearance and feel, molybdenum disulfide is similar to graphite. It is widely used as a solid lubricant because of its low friction properties and robustness. As a transition metal di-chalcogenide, MoS
2 possesses some of graphene's desirable qualities (such as mechanical strength and electrical conductivity), and can emit light, opening possible applications such as photodetectors.[36]

Tungsten diselenide

Tungsten diselenide is an inorganic compound with the formula WSe
2. The compound adopts a hexagonal crystalline structure similar to molybdenum disulfide. Every tungsten atom is covalently bonded to six selenium ligands in a trigonal prismatic coordination sphere, while each selenium is bonded to three tungsten atoms in a pyramidal geometry. The tungsten – selenium bond has a bond distance of 2.526 Å and the distance between selenium atoms is 3.34 Å.[37] Layers stack together via van der Waals interactions. WSe
2 is a stable semiconductor in the group-VI transition metal dichalcogenides.

MXenes

MXenes are layered transition metal carbides and carbonitrides with general formula of Mn+1XnTx, where M stands for early transition metal, X stands for carbon and/or nitrogen and Tx stands for surface terminations (mostly =O, -OH or -F). MXenes have high electric conductivity (1500 Scm−1) combined with hydrophilic surfaces. This materials show promise in energy storage applications and composites.

Organic

Ni3(HITP)2 is an organic, crystalline, structurally tunable electrical conductor with a high surface area. HITP is an organic chemical (2,3,6,7,10,11-hexaaminotriphenylene). It shares graphene’s hexagonal honeycomb structure. Multiple layers naturally form perfectly aligned stacks, with identical 2-nm openings at the centers of the hexagons. Room temperature electrical conductivity is ~40 S/cm (Siemens per centimeter), comparable to that of bulk graphite and among the highest for any conducting Metal-organic frameworks (MOFs). The temperature dependence of its conductivity is linear at temperatures between 100 K (Kelvin) and 500 K, suggesting an unusual charge transport mechanism that has not been previously observed in organic semiconductors.[38]

The material was claimed to be the first of a group formed by switching metals and/or organic compounds. The material can be isolated as a powder or a film. Conductivity values of 2 and 40 S·cm–1, respectively.[39]

Combinations

A 2015 study stacked two different TMD layers onto graphene. This composite displayed negative differential resistance – applying more voltage to the device reduced the current flowing through it.[3]

Applications

As of 2014, none of these materials has been used for large scale commercial applications (with the possible exception of graphene). Despite this, many are under close consideration for a number of industries, in areas including electronics and optoelectronics, sensors, biological engineering, filtration, lightweight/strong composite materials, photovoltaics, medicine, quantum dots, thermal management, ethanol distillation and energy storage,[40] and have enormous potential.

Graphene has been the most studied. In small quantities it is available as a powder and as a dispersion in a polymer matrix, or adhesive, elastomer, oil and aqueous and non-aqueous solutions. The dispersion is claimed to be suitable for advanced composites, paints and coatings, lubricants, oils and functional fluids, capacitors and batteries, thermal management applications, display materials and packaging, inks and 3D-printers’ materials, and barriers and films.[41]

Vantablack


References

  1. ↑ Garcia, J. C.; de Lima, D. B.; Assali, L. V. C.; Justo, J. F. (2011). "Group IV graphene- and graphane-like nanosheets". J. Phys. Chem. C 115: 13242. doi:10.1021/jp203657w.
  2. ↑ "The super materials that could trump graphene". Nature. 17 June 2015. Retrieved 19 June 2015.
  3. 1 2 3 Berger, Andy (July 17, 2015). "Beyond Graphene, a Zoo of New 2-D Materials". Discover Magazine. Retrieved 2015-09-19.
  4. ↑ "Graphene-Info Market Report". Graphene-info. June 2015. Retrieved June 2015.
  5. ↑ "Global Demand for Graphene after Commercial Production to be Enormous". AZONANO.com. 28 February 2014. Retrieved 24 July 2014.
  6. ↑ Andronico, Michael (14 April 2014). "5 Ways Graphene Will Change Gadgets Forever". Laptop.
  7. ↑ "Graphene properties". www.graphene-battery.net. 2014-05-29. Retrieved 2014-05-29.
  8. ↑ "This Month in Physics History: October 22, 2004: Discovery of Graphene". APS News. Series II 18 (9): 2. 2009.
  9. ↑ "The Nobel Prize in Physics 2010". The Nobel Foundation. Retrieved 2013-12-03.
  10. ↑ Heimann, R.B.; Evsvukov, S.E.; Koga, Y. (1997). "Carbon allotropes: a suggested classification scheme based on valence orbital hybridization". Carbon 35 (10–11): 1654–1658. doi:10.1016/S0008-6223(97)82794-7.
  11. ↑ Enyashin, Andrey N.; Ivanovskii, Alexander L. (2011). "Graphene Allotropes". Physica Status Solidi (b) 248 (8): 1879–1883. doi:10.1002/pssb.201046583.
  12. ↑ Özçelik, V. Ongun; S. Ciraci (January 10, 2013). "Size Dependence in the Stabilities and Electronic Properties of α-Graphyne and Its Boron Nitride Analogue". The Journal of Physical Chemistry C 117 (5): 2175–2182. doi:10.1021/jp3111869.
  13. ↑ Balaban, AT; Rentia, CC; Ciupitu, E. (1968). Rev. Roum. Chim. 13: 231.
  14. ↑ Guoxing Li; Yuliang Li; Huibiao Liu; Yanbing Guo; Yongjun Li; Daoben Zhu (2010). "Architecture of graphdiyne nanoscale films". Chemical Communications 46 (19): 3256–3258. doi:10.1039/B922733D.
  15. ↑ Malko, D.; Neiss, C.; Viñes, F.; Görling, A. (2012). "Competition for Graphene: Graphynes with Direction-Dependent Dirac Cones". Physical Review Letters 108 (8). Bibcode:2012PhRvL.108h6804M. doi:10.1103/PhysRevLett.108.086804.
  16. ↑ Schirber, Michael (24 February 2012). "Focus: Graphyne May Be Better than Graphene". Physics 5 (24). Bibcode:2012PhyOJ...5...24S. doi:10.1103/Physics.5.24.
  17. ↑ "Will ‘borophene’ replace graphene as a better conductor of electrons?". KurzweilAI. February 5, 2014. Retrieved February 5, 2014.
  18. ↑ Piazza, Z. A.; Hu, H. S.; Li, W. L.; Zhao, Y. F.; Li, J.; Wang, L. S. (2014). "Planar hexagonal B36 as a potential basis for extended single-atom layer boron sheets". Nature Communications 5: 3113. Bibcode:2014NatCo...5E3113P. doi:10.1038/ncomms4113. PMID 24445427.
  19. ↑ "Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs". Science 350: 1513–1516. December 18, 2015. Bibcode:2015Sci...350.1513M. doi:10.1126/science.aad1080. |first1= missing |last1= in Authors list (help)
  20. ↑ Bampoulis, P.; Zhang, L.; Safaei, A.; van Gastel, R.; Poelsema, B.; Zandvliet, H. J. W. (2014). "Germanene termination of Ge2Pt crystals on Ge(110)". Journal of Physics: Condensed Matter 26: 442001. Bibcode:2014JPCM...26R2001B. doi:10.1088/0953-8984/26/44/442001. PMID 25210978.
  21. ↑ Bampoulis, P.; Zhang, L.; Safaei, A.; Van Gastel, R.; Poelsema, B.; Zandvliet, H. J. W. (2014). "Germanene termination of Ge2Pt crystals on Ge(110)". Journal of Physics: Condensed Matter 26 (44): 442001. Bibcode:2014JPCM...26R2001B. doi:10.1088/0953-8984/26/44/442001. PMID 25210978.
  22. ↑ Takahashi, L.; Takahashi, K. (2015). "Low temperature pollutant trapping and dissociation over two-dimensional tin.". Physical Chemistry Chemical Physics C 17: 21394–21396. Bibcode:2015PCCP...1721394T. doi:10.1039/C5CP03382A.
  23. ↑ Li, L.; Yu, Y.; Ye, G. J.; Ge, Q.; Ou, X.; Wu, H.; Feng, D.; Chen, X. H.; Zhang, Y. (2014). "Black phosphorus field-effect transistors". Nature Nanotechnology 9 (5): 372–377. arXiv:1401.4117. Bibcode:2014NatNa...9..372L. doi:10.1038/nnano.2014.35.
  24. ↑ Yin, Xi; Liu, Xinhong; Pan, Yung-Tin; Walsh, Kathleen A.; Yang, Hong (November 4, 2014). "Hanoi Tower-like Multilayered Ultrathin Palladium Nanosheets". Nano Letters 14: 7188–7194. Bibcode:2014NanoL..14.7188Y. doi:10.1021/nl503879a.
  25. ↑ Duan, Haohong; Yan, Ning; Yu, Rong; Chang, Chun-Ran; Zhou, Gang; Hu, Han-Shi; Rong, Hongpan; Niu, Zhiqiang; Mao, Junjie (2014-01-01). "Ultrathin rhodium nanosheets". Nature Communications 5. Bibcode:2014NatCo...5E3093D. doi:10.1038/ncomms4093.
  26. ↑ Kochaev, A. I.; Karenin, A. A.; Meftakhutdinov, R. M.; Brazhe, R. A. (2012). "2D supracrystals as a promising materials for planar nanoacoustoelectronics". Journal of Physics: Conference Series 345: 012007. Bibcode:2012JPhCS.345a2007K. doi:10.1088/1742-6596/345/1/012007.
  27. ↑ Brazhe, R. A.; Kochaev, A. I. (2012). "Flexural waves in graphene and 2D supracrystals". Physics of the Solid State 54 (8): 1612–1614. Bibcode:2012PhSS...54.1612B. doi:10.1134/S1063783412080069.
  28. ↑ Sofo, Jorge O.; et al. (2007). "Graphane: A two-dimensional hydrocarbon". Physical Review B 75 (15): 153401–4. arXiv:cond-mat/0606704. Bibcode:2007PhRvB..75o3401S. doi:10.1103/PhysRevB.75.153401.
  29. ↑ D. C. Elias; et al. (2009). "Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane". Science 323 (5914): 610–3. arXiv:0810.4706. Bibcode:2009Sci...323..610E. doi:10.1126/science.1167130. PMID 19179524.
  30. ↑ Sluiter, Marcel; Kawazoe, Yoshiyuki (2003). "Cluster expansion method for adsorption: Application to hydrogen chemisorption on graphene". Physical Review B 68 (8): 085410. Bibcode:2003PhRvB..68h5410S. doi:10.1103/PhysRevB.68.085410.
  31. ↑ A. M. Ilyin; et al. (2011). "Computer simulation and experimental study of graphane-like structures formed by electrolytic hydrogenation". Physica E 43 (6): 1262–65. Bibcode:2011PhyE...43.1262I. doi:10.1016/j.physe.2011.02.012.
  32. ↑ G. Savini; et al. (2010). "Doped graphane: a prototype high-Tc electron-phonon superconductor". Phys Rev Lett 105. arXiv:1002.0653v1. doi:10.1103/physrevlett.105.059902.
  33. ↑ Bianco, E.; Butler, S.; Jiang, S.; Restrepo, O. D.; Windl, W.; Goldberger, J. E. (2013). "Stability and Exfoliation of Germanane: A Germanium Graphane Analogue". ACS Nano 7: 130326123449003. doi:10.1021/nn4009406.
  34. ↑ Garcia, J. C.; de Lima, D. B.; Assali, L. V. C.; Justo, J. F. (2011). "Group IV graphene- and graphane-like nanosheets". J. Phys. Chem. C 115: 13242–13246. doi:10.1021/jp203657w.
  35. ↑ "‘Germanane’ may replace silicon for lighter, faster electronics". KurzweilAI. Retrieved 2013-04-12.
  36. ↑ Coxworth, Ben (September 25, 2014). "Metal-based graphene alternative "shines" with promise". Gizmag. Retrieved September 30, 2014.
  37. ↑ Schutte, W.J.; De Boer, J.L.; Jellinek, F. (1986). "Crystal Structures of Tungsten Disulfide and Diselenide". Journal of Solid State Chemistry 70: 207–209. Bibcode:1987JSSCh..70..207S. doi:10.1016/0022-4596(87)90057-0.
  38. ↑ Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.; Er, Süleyman; Wade, Casey R.; Brozek, Carl K.; Aspuru-Guzik, Alán; Dincă, Mircea (2014-06-25). "High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue". Journal of the American Chemical Society 136 (25): 8859–8862. doi:10.1021/ja502765n. ISSN 0002-7863.
  39. ↑ "A new self-assembling graphene-like material for flat semiconductors". KurzweilAI. 2014-05-01. Retrieved 2014-08-24.
  40. ↑ "Graphene Uses & Applications". Graphenea. Retrieved 2014-04-13.
  41. ↑ "Applied Graphene Materials plc :: Graphene dispersions". appliedgraphenematerials.com.
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