Cat's-whisker detector

Galena cat's whisker detector
Precision cat's whisker detector with iron pyrite crystal, used in large wireless stations, early 1900s. The crystal is inside the metal capsule under the vertical needle "whisker" (right). The leaf springs and thumbscrew allowed fine adjustment of the pressure of the needle on the crystal.

A cat's-whisker detector (sometimes called a crystal detector) is an antique electronic component consisting of a thin wire that lightly touches a crystal of semiconducting mineral (usually galena) to make a crude point-contact rectifier. Developed around 1904 by early radio researchers Henry H. C. Dunwoody, G. W. Pickard and others, this device was used as the detector in early crystal radios, from the early twentieth century through World War II, and gave this type of radio receiver its name. Crystal radios were the most popular type of radio until the mid 1920s. The cat's whisker detector was the first type of semiconductor diode, and in fact, one of the first semiconductor electronic devices (after photoconductors). Cat's whisker detectors are obsolete and are now only used in antique or antique-reproduction radios, and for educational purposes.

Description

A small portable crystal radio with a cat's whisker detector visible at top

The tip of the wire contacting the surface of the crystal formed a crude unstable point-contact metal–semiconductor junction, forming a Schottky barrier diode. This junction conducts electric current in only one direction and resists current flowing in the other direction. In a crystal radio, its function was to rectify the radio signal, converting it from alternating current to a pulsing direct current, to extract the audio signal (modulation) from the radio frequency carrier wave. The metal whisker is the anode, and the crystal is the cathode; current flows from the whisker into the crystal but not in the other direction.

Only certain sites on the crystal surface functioned as rectifying junctions. The device was very sensitive to the exact geometry and pressure of contact between wire and crystal. It was therefore made adjustable, and a usable point of contact was found by trial and error before each use. The wire was suspended from a moveable arm and was dragged across the crystal face by the operator until the device began functioning. In a crystal radio, the operator would tune the radio to a strong local station if possible and then adjust the cat's whisker until the station or static was heard in the radio's earphones. This required some skill and a great deal of patience; even then, a good contact could easily be lost by the slightest vibration. An alternative method of adjustment was to use a battery-operated buzzer to generate a test signal. The spark produced by the buzzer's contacts functioned as a weak radio transmitter whose emissions could be detected when a diode in the crystal had been found and the buzz could be heard in the earphones, at which time the buzzer was turned off. The temperamental, unreliable action of the crystal detector was a barrier to its acceptance as a standard component in commercial radio equipment[1] and was one reason for its rapid replacement by vacuum tubes after 1920. Frederick Seitz, a later semiconductor researcher, wrote:

Pictorial diagram with parts labelled; a horizontal wire antenna at top is connected to the top end of a coil with a sliding contact for tuning. The top end of the coil is connected through a cat's-whisker detector to a set of headphones. The bottom end of the tuning coil is connected to ground, as is the second terminal of the headphones.
Diagram of a crystal radio from 1922 using a cat's-whisker detector
Modern galena cat's-whisker detector, showing parts. The galena crystal (upper left) is held in the metal capsule with a screw cap, leaving its face exposed.
Such variability, bordering on what seemed the mystical, plagued the early history of crystal detectors and caused many of the vacuum tube experts of a later generation to regard the art of crystal rectification as being close to disreputable.[2]

Crystal

A natural mineral crystal forms the semiconductor side of the junction. The most common crystal used was galena (PbS, lead sulfide), a naturally occurring ore of lead, although many other minerals were also used including silicon, iron pyrite, molybdenite and carborundum.[3] Galena is a semiconductor with a small bandgap of about 0.4 eV and is used without treatment directly as it is mined. However, not all galena crystals would function in a detector; galena with good detecting properties was rare and had no reliable visual characteristics distinguishing it from galena samples with poor detecting properties. A rough pebble of detecting mineral about the size of a pea was mounted in a metal cup, which formed one side of the circuit. The electrical contact between the cup and the crystal had to be good, because this contact must not act as a second rectifying junction, which would prevent the device from functioning. To make good contact with the crystal, it was either clamped with setscrews or mounted in solder. Because the relatively high melting temperature of tin-lead solder can damage many crystals, a low-melting-point (well under 200 °F (93 °C)) alloy such as Wood's metal was used. One surface was left exposed to allow contact with the cat's-whisker wire.

Whisker

The "cat's whisker", a springy piece of thin metal wire, formed the metal side of the junction. Phosphor bronze wire of about 30 gauge was commonly used because it had the optimal amount of springiness. It was mounted on an adjustable arm with an insulated handle so that the entire exposed surface of the crystal could be probed from many directions to find the most sensitive spot. Cat's whiskers in simple detectors were straight or curved, but most professional cat's whiskers had a coiled section in the middle that served as a spring.[4] The crystal required just the right gentle pressure by the wire; too much pressure caused the device to conduct in both directions. Precision detectors often used a metal needle instead of a cat's whisker, mounted on a thumbscrew-operated leaf spring to adjust the pressure applied.

Types

How a crystal detector works in a radio receiver.[5][6] (A) The amplitude modulated radio signal from the receiver's tuning section. The rapid oscillations are the radio frequency carrier wave. The audio signal (the sound) is contained in the slow variations (modulation) of the size of the waves. This signal cannot be converted to sound by the earphone, because the audio excursions are the same on both sides of the axis, averaging out to zero, resulting in no net motion of the earphone's diaphragm.(B) The crystal conducts current in only one direction, stripping off the oscillations on one side of the signal, leaving a pulsing direct current whose amplitude does not average zero but varies with the audio signal. (C) A bypass capacitor across the earphone smooths the waveform, removing the radio frequency carrier pulses, leaving the audio signal.

Historically, many other minerals and compounds besides galena were used for the crystal, the most important being iron pyrite ("fool's gold", iron disulfide, FeS2), silicon, molybdenite (MoS2), and silicon carbide (carborundum, SiC). Some were used with gold or graphite cat's whiskers. Another type had a crystal-to-crystal junction instead of a cat's whisker, with two crystals mounted facing each other. One crystal was moved forward on an adjustable mount until the crystal faces touched. The most common of these was a zincite-bornite (ZnO-Cu5FeS4) junction trade-named Perikon, but zincite-chalcopyrite, silicon-arsenic and silicon-antimony junctions were also used. The goal of researchers was to find junctions that were not as sensitive to vibration and unreliable as galena and pyrite. Some of these other junctions, particularly carborundum, were stable enough that they were equipped with a more permanent spring-loaded contact rather than a cat's whisker.[7] For this reason, carborundum detectors were preferred for use in large commercial wireless stations and military and shipboard stations that were subject to vibration from waves and gunnery exercises. Another quality desired was the ability to withstand high currents without damage, because in broadcast stations, the fragile detector junction could be "burned out" by atmospheric electric charge from the antenna or high radio frequency current leaking into the receiver from the powerful spark-gap transmitter during transmissions. Carborundum detectors, which used large-area contacts, were also particularly robust in this regard.

To increase sensitivity, some of these junctions such as silicon carbide were biased by connecting a battery and potentiometer across them to provide a small constant forward voltage across the junction.[8]

Foxhole radio from World War II

The oxide layers that form on many ordinary metal surfaces have semiconducting properties, and detectors for crystal radios have been improvised from a variety of everyday objects such as rusty needles and corroded pennies. The foxhole radio [6] was a crystal radio receiver improvised by soldiers during World War II without access to conventional sets. It used a razor blade and a safety pin or pencil lead to form a demodulating junction. Much patience was required to find an active detecting site on the blade. Unwanted rectifying junctions that form between metal parts of radio transmitter installations are still a source for interference, because they can produce harmonics of the transmitter frequency.

History

The modern circuit symbol for a diode originated as a schematic drawing of a cat's-whisker detector.

Unlike modern radio stations that transmit a waveform that represents sound, the radio transmitters during the first three decades of radio transmitted information by telegraphy; the operator turned the transmitter on and off with a switch called a telegraph key to spell out messages in Morse code, consisting of different length pulses of radio waves called "dots" and "dashes". Early radio receiving apparatus merely had to detect the presence or absence of the radio signal, not convert it into audio. The detection device that did this was called a detector. The crystal detector was the most successful of many detector devices that were used in the early days of radio. It replaced earlier electrolytic, magnetic, and particularly coherer detectors in radio receivers around 1906. Later, when AM radio transmission was developed to transmit sound, around World War I, crystal detectors proved able to receive this transmission as well.

The "unilateral conduction" of crystals, as it was then called, was discovered by Ferdinand Braun, a German physicist, in 1874 at the University of Würzburg, before radio had been invented.[9] Indian scientist Jagadish Chandra Bose was the first to use a crystal to detect radio waves, in his pioneering experiments with microwaves in 1894, applying for a patent on a galena detector in 1901.[10] The cat's-whisker detector was developed as a practical device mainly by G. W. Pickard. His first detector, which used a silicon crystal, was patented in 1906.[11] At nearly the same time, Henry Harrison Chase Dunwoody,[12] a retired general in the U.S. Army Signal Corps, patented the silicon carbide (carborundum) detector,[13] an artificial substance created accidentally during attempts by Edward Acheson to create diamonds.

Pickard tested more than 30,000 combinations of crystal and wire contacts and developed several types of detectors that saw wide use.[14] One variation consisted of a pair of different crystals with their faces touching, such as zincite touching bornite or chalcopyrite. Pickard named this the Perikon detector, from "PERfect pIcKard cONtact". Other detectors patented by Pickard employed the common crystal iron pyrite.

(top) Cartridge carborundum detector from 1925. Crystal detectors were also used to a limited extent in vacuum tube radios because they were more sensitive than vacuum tube detectors. The carborundum detector was used, since it did not require adjustment and so was made in the form of cartridges
(bottom) The carborundum detector required a DC bias of several volts, provided by a battery and potentiometer.
A crystal detector made in the 1960s for antique reproduction crystal sets.

From the earliest wireless telegraphy days of radio, well into the age of commercial AM broadcasting, unamplified radio receivers were powered only by the radio energy they picked up through their antennas. The crystal radio was the most widely used of these. Manufactured and homemade by the millions, it helped introduce radio to the public, contributing to the development of radio from an experimental hobby to an entertainment medium around 1920. After about 1920, receivers using crystal detectors were largely superseded by the first amplifying receivers, which used vacuum tubes. These did not require the fussy adjustments that crystals required, were more sensitive, and also were powerful enough to drive loudspeakers. Nevertheless, the expense of the early vacuum tubes and the batteries needed to run them meant that the crystal detector remained in commercial and military use for almost a decade more. However, by the late 1920s, radios using crystal detectors were relegated to use by hobbyists and youth groups and have been used by them as educational devices to the present day.

The point-contact semiconductor detector was subsequently resurrected around World War II because of the military requirement for microwave radar detectors. Vacuum-tube detectors do not work at microwave frequencies. The small area of the point contact minimized minority carrier storage and capacitance, making these diodes fast enough to function at radar frequencies. Silicon and germanium point-contact diodes were developed. Wartime research on p-n junctions in crystals paved the way for the invention of the point-contact transistor in 1947.

The germanium diodes that became widely available after the war proved to be as sensitive as galena and did not require any adjustment, so germanium diodes replaced cat's-whisker detectors in the few crystal radios still being made, largely putting an end to the manufacture of this antique radio component. Although cat's-whisker detectors are obsolete, modern point-contact silicon detectors are still commercially produced.[15] Thus, the point-contact method used to make these first semiconductor diodes 100 years ago is still being used today.

Copies of original cat's-whisker detectors are still manufactured and sold, for antique radio hobbyists.

The first crystal detector commercially produced, Pickard's silicon detector, from 1906.
A "Perikon" detector, 1914. Instead of a wire-to-crystal contact, this had a crystal-to-crystal contact. The bornite crystal (right) on the adjustable arm was moved forward until it touched one of the zincite crystals on the carousel (left). Multiple zincite crystals were provided because the zincite was vulnerable to damage from atmospheric electricity.
Precision detector using leaf spring and thumbscrew to control pressure
Pyrite detector
Carborundum (silicon carbide) detector. This used a metal clamp contact instead of a delicate cat's whisker, so carborundum detectors were used in military and shipboard stations where vibration could be expected.

See also

References

  1. ↑ Braun, Ernest; Stuart MacDonald (1982). Revolution in Miniature: The history and impact of semiconductor electronics, 2nd Ed. UK: Cambridge Univ. Press. pp. 11–12. ISBN 978-0-521-28903-0.
  2. ↑ Riordan, Michael; Lillian Hoddeson (1988). Crystal fire: the invention of the transistor and the birth of the information age. USA: W. W. Norton & Company. pp. 19–21. ISBN 0-393-31851-6.
  3. ↑ The Concise Household Encyclopedia (ca. 1935) The Amalgamated Press, London
  4. ↑ Sievers, Maurice L. (2008). Crystal Clear: Vintage American Crystal Sets, Crystal Detectors, and Crystals. Sonoran Publishing. p. 6. ISBN 1-886606-01-3.
  5. ↑ Marx & Van Muffling (1922) Radio Reception, p.43, fig.22
  6. 1 2 Campbell, John W. (October 1944). "Radio Detectors and How They Work". Popular Science (New York: Popular Science Publishing Co.) 145 (4): 206–209. Retrieved 2010-03-06.
  7. ↑ The Principles Underlying Radio Communication, 2nd Ed., Radio pamphlet no. 40. USA: Prepared by US National Bureau of Standards, United States Army Signal Corps. 1922. pp. 421–425.
  8. ↑ Pender, Harold; William Arthur del Mar (1922). Handbook for Electrical Engineers, 2nd Ed. New York: J. Wiley & Sons. p. 1268.
  9. ↑ Braun, F. (1874), "Ueber die Stromleitung durch Schwefelmetalle" [On current conduction through metal sulfides], Annalen der Physik und Chemie (in German) 153 (4): 556–563, doi:10.1002/andp.18752291207
  10. ↑ US 755840, Bose, Jagadis Chunder, "Detector for electrical disturbances", published September 30, 1901, issued March 29, 1904
  11. ↑ US 836531, Pickard, Greenleaf Whittier, "Means for receiving intelligence communicated by electric waves", published August 30, 1906, issued November 20, 1905
  12. ↑ Some biographical information on General Henry H.C. Dunwoody is available at: Arlington National Cemetery.
  13. ↑ US 837616, Dunwoody, Henry H. C., "Wireless-telegraph system", published March 23, 1906, issued December 4, 1906
  14. ↑ Lee, Thomas H. (2004). Planar Microwave Engineering: A practical guide to theory, measurements, and circuits. UK: Cambridge Univ. Press. pp. 297–300. ISBN 978-0-521-83526-8.
  15. ↑ For example, Advanced Semiconductor Inc. (North Hollywood, California, USA) is selling Si point-contact detectors which will cover from UHF (ultra high frequency) to 16 GHz.

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