Petalite

Petalite
Petalite from Minas Gerais State, Brazil (size: 3x4 cm)
General
Category	Phyllosilicate
Formula (repeating unit)	LiAlSi4O10
Strunz classification	09.EF.05
Crystal system	Monoclinic
Unit cell	a = 11.737 Å, b = 5.171 Å, c = 7.63 Å; β = 112.54°; Z = 2
Identification
Color	Colorless, grey, yellow, pink, to white
Crystal habit	Tabular prismatic crystals and columnar masses
Crystal symmetry	Monoclinic prismatic H-M symbol: (2/m) Space group: P 2/a
Twinning	Common on {001}, lamellar
Cleavage	Perfect on {001}, poor on {201} with 38.5° angle between the two
Fracture	Subconchoidal
Tenacity	Brittle
Mohs scale hardness	6 - 6.5
Luster	Vitreous, pearly on cleavages
Streak	Colorless
Diaphaneity	Transparent to translucent
Specific gravity	2.4
Optical properties	Biaxial (+)
Refractive index	nα=1.504, nβ=1.510, nγ=1.516
Birefringence	δ = 0.012
2V angle	82 – 84° measured
Melting point	1350 °C[1]
Fusibility	5
Solubility	Insoluble
References	[2][3][4][5]

Petalite, also known as castorite, is a lithium aluminium phyllosilicate mineral LiAlSi₄O₁₀, crystallizing in the monoclinic system. Petalite is a member of the feldspathoid group. It occurs as colorless, grey, yellow, yellow grey, to white tabular crystals and columnar masses. Occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component.^[6] The colorless varieties are often used as gemstones.

Faceted petalite, 12.66 ct, Brazil

Discovery and occurrence

Petalite from Paprok, Nuristan Province, Afghanistan (size: 7.3 x 2.9 x 2.4 cm)

Discovered in 1800, by Brazilian naturalist Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is derived from the Greek word petalon, which means leaf.^[4][7][8]

Economic deposits of petalite are found near Kalgoorlie, Western Australia; Aracuai, Minas Gerais, Brazil; Karibib, Namibia; Manitoba, Canada; and Bikita, Zimbabwe.

The first important economic application for petalite was as a raw material for the glass-ceramic cooking ware CorningWare. It has been used as a raw material for ceramic glazes.

References

1. "Petalite". Digital Fire. Retrieved 23 October 2011.
2. Handbook of Mineralogy
3. Webmineral
4. Mindat
5. • Hurlbut, Cornelius S. and Klein, Cornelis, 1985, Manual of Mineralogy, Wiley, 20th ed., pp. 459-460 ISBN 0-471-80580-7
6. Deer, W. A. (2004). Framework silicates: silica minerals, feldspathoids and the zeolites (2. ed.). London: Geological Soc. p. 296. ISBN 1-86239-144-0.
7. D'Andraba (1800). "Des caractères et des propriétés de plusieurs nouveaux minérauxde Suède et de Norwège , avec quelques observations chimiques faites sur ces substances". Journal de chimie et de physique 51: 239.
8. Sowerby, James (1811). Exotic mineralogy: Or, Coloured figures of foreign minerals: As a supplement to British mineralogy.