Isotopes of bohrium

Bohrium (Bh) is an artificial element (atomic number 107), and thus a standard atomic mass cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was ²⁶²Bh in 1981. There are 11 known isotopes ranging from ²⁶⁰Bh to ²⁷⁴Bh, and 1 isomer, ^262mBh. The longest-lived isotope is ²⁷⁰Bh with a half-life of 1 minute.

Table

nuclide symbol	Z(p)	N(n)	isotopic mass (u)	half-life	decay mode(s)[1][n 1]	daughter isotope(s)	nuclear spin
	excitation energy
^260Bh	107	153	260.12166(26)#	41(14) ms	α	^256Db
^261Bh	107	154	261.12146(22)#	12.8(3.2) ms	α (95%?)	^257Db	(5/2−)
					SF (5%?)	(various)
^262Bh	107	155	262.12297(33)#	84(11) ms	α (80%)	^258Db
					SF (20%)	(various)
^262mBh	220(50) keV			9.5(1.6) ms	α (70%)	^258Db
					SF (30%)	(various)
^264Bh[n 2]	107	157	264.12459(19)#	1.07(21) s	α (86%)	^260Db
					SF (14%)	(various)
^265Bh	107	158	265.12491(25)#	1.19(52) s	α	^261Db
^266Bh[n 3]	107	159	266.12679(18)#	2.5(1.6) s	α	^262Db
^267Bh	107	160	267.12750(28)#	22(10) s [17(+14−6) s]	α	^263Db
^270Bh[n 4]	107	163	270.13336(31)#	3.8(3.0) min	α	^266Db
^271Bh[n 5]	107	164	271.13526(48)#	1.5 s	α	^267Db
^272Bh[n 6]	107	165	272.13826(58)#	8.8(2.1) s	α	^268Db
^274Bh[n 7]	107	167	274.14355(65)#	0.9 min[2]	α	^270Db

1. Abbreviations:
   SF: Spontaneous fission
2. Not directly synthesized, occurs in decay chain of ²⁷²Rg
3. Not directly synthesized, occurs in decay chain of ²⁷⁸Uut
4. Not directly synthesized, occurs in decay chain of ²⁸²Uut
5. Not directly synthesized, occurs in decay chain of ²⁸⁷Uup
6. Not directly synthesized, occurs in decay chain of ²⁸⁸Uup
7. Not directly synthesized, occurs in decay chain of ²⁹⁴Uus

Notes

• Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
• Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.

Nucleosynthesis

Super-heavy elements such as bohrium are produced by bombarding lighter elements in particle accelerators that induce fusion reactions. Whereas most of the isotopes of bohrium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher atomic numbers.^[3]

Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets (actinides), giving rise to compound nuclei at high excitation energy (~40–50−MeV) that may either fission or evaporate several (3 to 5) neutrons.^[4] In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20 MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the ground state, they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products.^[3] The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see cold fusion).^[5]

Cold fusion

Before the first successful synthesis of hassium in 1981 by the GSI team, the synthesis of bohrium was first attempted in 1976 by scientists at the Joint Institute for Nuclear Research at Dubna using this cold fusion reaction. They detected two spontaneous fission activities, one with a half-life of 1–2 ms and one with a half-life of 5 s. Based on the results of other cold fusion reactions, they concluded that they were due to ²⁶¹Bh and ²⁵⁷Db respectively. However, later evidence gave a much lower SF branching for ²⁶¹Bh reducing confidence in this assignment. The assignment of the dubnium activity was later changed to ²⁵⁸Db, presuming that the decay of bohrium was missed. The 2 ms SF activity was assigned to ²⁵⁸Rf resulting from the 33% EC branch. The GSI team studied the reaction in 1981 in their discovery experiments. Five atoms of ²⁶²Bh were detected using the method of correlation of genetic parent-daughter decays.^[6] In 1987, an internal report from Dubna indicated that the team had been able to detect the spontaneous fission of ²⁶¹Bh directly. The GSI team further studied the reaction in 1989 and discovered the new isotope ²⁶¹Bh during the measurement of the 1n and 2n excitation functions but were unable to detect an SF branching for ²⁶¹Bh.^[7] They continued their study in 2003 using newly developed bismuth(III) fluoride (BiF₃) targets, used to provide further data on the decay data for ²⁶²Bh and the daughter ²⁵⁸Db. The 1n excitation function was remeasured in 2005 by the team at the Lawrence Berkeley National Laboratory (LBNL) after some doubt about the accuracy of previous data. They observed 18 atoms of ²⁶²Bh and 3 atoms of ²⁶¹Bh and confirmed the two isomers of ²⁶²Bh.^[8]

In 2007, the team at LBNL studied the analogous reaction with chromium-52 projectiles for the first time to search for the lightest bohrium isotope ²⁶⁰Bh:

209
83Bi + 52
24Cr → 260
107Bh + n

The team successfully detected 8 atoms of ²⁶⁰Bh decaying by alpha decay to ²⁵⁶Db, emitting alpha particles with energy 10.16 MeV. The alpha decay energy indicates the continued stabilizing effect of the N=152 closed shell.^[9]

The team at Dubna also studied the reaction between lead-208 targets and manganese-55 projectiles in 1976 as part of their newly established cold fusion approach to new elements:

208
82Pb + 55
25Mn → 262
107Bh + n

They observed the same spontaneous fission activities as those observed in the reaction between bismuth-209 and chromium-54 and again assigned them to ²⁶¹Bh and ²⁵⁷Db. Later evidence indicated that these should be reassigned to ²⁵⁸Db and ²⁵⁸Rf (see above). In 1983, they repeated the experiment using a new technique: measurement of alpha decay from a decay product that had been separated out chemically. The team were able to detect the alpha decay from a decay product of ²⁶²Bh, providing some evidence for the formation of bohrium nuclei. This reaction was later studied in detail using modern techniques by the team at LBNL. In 2005 they measured 33 decays of ²⁶²Bh and 2 atoms of ²⁶¹Bh, providing an excitation function for the reaction emitting one neutron and some spectroscopic data of both ²⁶²Bh isomers. The excitation function for the reaction emitting two neutrons was further studied in a 2006 repeat of the reaction. The team found that the reaction emitting one neutron had a higher cross section than the corresponding reaction with a ²⁰⁹Bi target, contrary to expectations. Further research is required to understand the reasons.^[10][11]

Hot fusion

The reaction between uranium-238 targets and phosphorus-31 projectiles was first studied in 2006 at the LBNL as part of their systematic study of fusion reactions using uranium-238 targets:

238
92U + 31
15P → 264
107Bh + 5 n

Results have not been published but preliminary results appear to indicate the observation of spontaneous fission, possibly from ²⁶⁴Bh.^[12]

Recently, the team at the Institute of Modern Physics (IMP), Lanzhou, have studied the nuclear reaction between americium-243 targets and accelerated nuclei of magnesium-26 in order to synthesise the new isotope ²⁶⁵Bh and gather more data on ²⁶⁶Bh:

243
95Am + 26
12Mg → 269−x
107Bh + x n (x = 3, 4, or 5)

In two series of experiments, the team measured partial excitation functions for the reactions emitting three, four, and five neutrons.^[13]

The reaction between targets of curium-248 and accelerated nuclei of sodium-23 was studied for the first time in 2008 by the team at RIKEN, Japan, in order to study the decay properties of ²⁶⁶Bh, which is a decay product in their claimed decay chains of ununtrium:^[14]

248
96Cm + 23
11Na → 271−x
107Bh + x n (x = 4 or 5)

The decay of ²⁶⁶Bh by the emission of alpha particles with energies of 9.05–9.23 MeV was further confirmed in 2010.^[15]

The first attempts to synthesize bohrium by hot fusion pathways were performed in 1979 by the team at Dubna, using the reaction between accelerated nuclei of neon-22 and targets of berkelium-249:

249
97Bk + 22
10Ne → 271−x
107Bh + x n (x = 4 or 5)

The reaction was repeated in 1983. In both cases, they were unable to detect any spontaneous fission from nuclei of bohrium. More recently, hot fusions pathways to bohrium have been re-investigated in order to allow for the synthesis of more long-lived, neutron rich isotopes to allow a first chemical study of bohrium. In 1999, the team at LBNL claimed the discovery of long-lived ²⁶⁷Bh (5 atoms) and ²⁶⁶Bh (1 atom).^[16] Later, both of these were confirmed.^[17] The team at the Paul Scherrer Institute (PSI) in Bern, Switzerland later synthesized 6 atoms of ²⁶⁷Bh in the first definitive study of the chemistry of bohrium.^[18]

As decay products

List of bohrium isotopes observed by decay

Evaporation residue	Observed bohrium isotope
^294Uus, ^290Uup, ^286Uut, ^282Rg, ^278Mt	^274Bh[19]
^288Uup, ^284Uut, ^280Rg, ^276Mt	^272Bh[20][21]
^287Uup, ^283Uut, ^279Rg, ^275Mt	^271Bh[20]
^282Uut, ^278Rg, ^274Mt	^270Bh[20]
^278Uut, ^274Rg, ^270Mt	^266Bh[21]
^272Rg, ^268Mt	^264Bh[22]
^266Mt	^262Bh[23]

Bohrium has been detected in the decay chains of elements with a higher atomic number, such as meitnerium. Meitnerium currently has seven known isotopes; all of them undergo alpha decays to become bohrium nuclei, with mass numbers between 262 and 274. Parent meitnerium nuclei can be themselves decay products of roentgenium, ununtrium, ununpentium, or ununseptium. To date, no other elements have been known to decay to bohrium.^[24] For example, in January 2010, the Dubna team (JINR) identified bohrium-274 as a product in the decay of ununseptium via an alpha decay sequence:^[19]

294
117Uus → 290
115Uup + 4
2He

290
115Uup → 286
113Uut + 4
2He

286
113Uut → 282
111Rg + 4
2He

282
111Rg → 278
109Mt + 4
2He

278
109Mt → 274
107Bh + 4
2He

Nuclear isomerism

²⁶²Bh

The only confirmed example of isomerism in bohrium is in the isotope ²⁶²Bh. Direct synthesis of ²⁶²Bh results in two states, a ground state and an isomeric state. The ground state is confirmed to decay by alpha decay, emitting alpha particles with energies of 10.08, 9.82, and 9.76 MeV, and has a revised half-life of 84 ms. The excited state also decays by alpha decay, emitting alpha particles with energies of 10.37 and 10.24 MeV, and has a revised half-life of 9.6 ms.^[6]

Chemical yields of isotopes

Cold fusion

The table below provides cross-sections and excitation energies for cold fusion reactions producing bohrium isotopes directly. Data in bold represents maxima derived from excitation function measurements. + represents an observed exit channel.

Projectile	Target	CN	1n	2n	3n
^55Mn	^208Pb	^263Bh	590 pb, 14.1 MeV	~35 pb
^54Cr	^209Bi	^263Bh	510 pb, 15.8 MeV	~50 pb
^52Cr	^209Bi	^261Bh	59 pb, 15.0 MeV

Hot fusion

The table below provides cross-sections and excitation energies for hot fusion reactions producing bohrium isotopes directly. Data in bold represents maxima derived from excitation function measurements. + represents an observed exit channel.

Projectile	Target	CN	3n	4n	5n
^26Mg	^243Am	^271Bh	+	+	+
^22Ne	^249Bk	^271Bh		~96 pb	+

References

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