| Year | Name | Union |
| 1868 | Wood, William HenryWilliam Henry Wood | Manchester and Salford Trades Council |
| 1869 | Wilkinson, ThomasThomas Wilkinson | Flint Glass Makers Friendly Society |
| 1871 | Potter, GeorgeGeorge Potter | London Working Men's Association |
| 1872 | Leatherland, W. H.W. H. Leatherland | Organised Trade Association |
| 1873 | Lishman, WilliamWilliam Lishman | Leeds Trades Council |
| 1874 | Rolley, WilliamWilliam Rolley | Sheffield Federated Trades Council |
| 1875 | Fitzpatrick, JamesJames Fitzpatrick | Liverpool Trades Council |
| 1875 | Battersby, JohnJohn Battersby | Scottish Typographical Association |
| 1876 | Laird, James C.James C. Laird | Newcastle Trades Council |
| 1877 | Merrick, DanielDaniel Merrick | Leicester Boot and Shoe Finishers |
| 1878 | Jones, George FowlerGeorge Fowler Jones | Bristol Trades Council |
| 1879 | Gibson, DavidDavid Gibson | Edinburgh and District Trades Council |
| 1880 | Murphy, JohnJohn Murphy | Friendly Society of Ironfounders |
| 1881 | Coulson, EdwinEdwin Coulson | Operative Bricklayers' Society |
| 1882 | Austin, RobertRobert Austin | Amalgamated Society of Engineers |
| 1883 | Smith, ThomasThomas Smith | National Union of Boot and Shoe Riveters |
| 1884 | Thompson, JamesJames Thompson | Aberdeen Trades Council |
| 1885 | Threlfall, T. R.T. R. Threlfall | Typographical Association |
| 1886 | Maddison, FrederickFrederick Maddison | Typographical Association |
| 1887 | Bevan, W.W. Bevan | Amalgamated Society of Carpenters and Joiners |
| 1888 | Shaftoe, SamuelSamuel Shaftoe | Yorkshire United Skip, Basket and Hamper Makers Society |
| 1889 | Ritchie, RobertRobert Ritchie | Dundee Trades Council |
| 1890 | Matkin, WilliamWilliam Matkin | General Union of Carpenters and Joiners |
| 1891 | Burt, ThomasThomas Burt | Northumberland Miners' Association |
| 1892 | Hodge, JohnJohn Hodge | British Steel Smelters Association |
| 1893 | Munro, SamuelSamuel Munro | Typographical Association |
| 1894 | Delves, FrankFrank Delves | Amalgamated Society of Engineers |
| 1895 | Jenkins, JohnJohn Jenkins | Associated Shipwrights' Society |
| 1896 | Mallinson, JohnJohn Mallinson | Edinburgh Trades Council |
| 1897 | Stevens, John ValentineJohn Valentine Stevens | Tinplate Workers Union |
| 1898 | O'Grady, JamesJames O'Grady | Amalgamated Union of Cabinet Makers |
| 1899 | Vernon, W. J.W. J. Vernon | Typographical Association |
| 1900 | Pickles, WilliamWilliam Pickles | National Amalgamated Society of House and Ship Painters |
| 1901 | Bowerman, C. W.C. W. Bowerman | London Society of Compositors |
| 1902 | Steadman, W. C.W. C. Steadman | River Thames Barge Builders Trades Union |
| 1903 | Boyd Hornidge, W.W. Boyd Hornidge | National Union of Boot and Shoe Operatives |
| 1904 | Bell, RichardRichard Bell | Amalgamated Society of Railway Servants |
| 1905 | Sexton, JamesJames Sexton | National Union of Dock Labourers |
| 1906 | Cummings, D. C.D. C. Cummings | United Society of Boilermakers |
| 1907 | Gill, AlfredAlfred Gill | Bolton Cotton Spinners Association |
| 1908 | Shackleton, DavidDavid Shackleton | Northern Counties Amalgamated Association of Weavers |
| 1909 | Shackleton, DavidDavid Shackleton | Northern Counties Amalgamated Association of Weavers |
| 1910 | Haslam, JamesJames Haslam | Miners Federation of Great Britain |
| 1911 | Mullin, WilliamWilliam Mullin | Amalgamated Association of Card and Blowing Room Operatives |
| 1912 | Thorne, WillWill Thorne | National Union of Gas Workers and General Labourers |
| 1913 | Davis, William JohnWilliam John Davis | Amalgamated Society of Brassworkers |
| 1915 | Seddon, JamesJames Seddon | National Amalgamated Union of Shop Assistants, Warehousemen and Clerks |
| 1916 | Gosling, HarryHarry Gosling | National Transport Workers Federation |
| 1917 | Hill, JohnJohn Hill | United Society of Boilermakers |
| 1918 | Ogden, John WilliamJohn William Ogden | Northern Counties Amalgamated Association of Weavers |
| 1919 | Stuart-Bunning, G. H.G. H. Stuart-Bunning | Postmen's Federation |
| 1920 | Thomas, JimmyJimmy Thomas | National Union of Railwaymen |
| 1921 | Poulton, Edward L.Edward L. Poulton | National Union of Boot and Shoe Operatives |
| 1922 | Walker, Robert BarrieRobert Barrie Walker | National Union of Agricultural Workers |
| 1923 | Williams, JoeJoe Williams | Musicians Union |
| 1924 | Purcell, AlfAlf Purcell | National Amalgamated Furnishing Trades Association |
| 1925 | Swales, AlonzoAlonzo Swales | Amalgamated Engineering Union |
| 1926 | Pugh, ArthurArthur Pugh | Iron and Steel Trades Confederation |
| 1927 | Hicks, GeorgeGeorge Hicks | Amalgamated Union of Building Trade Workers |
| 1928 | Turner, BenBen Turner | General Union of Textile Workers |
| 1929 | Tillett, BenBen Tillett | Transport and General Workers Union |
| 1930 | Beard, JohnJohn Beard | Transport and General Workers Union |
| 1931 | Hayday, ArthurArthur Hayday | National Union of General and Municipal Workers |
| 1932 | Bromley, JohnJohn Bromley | Associated Society of Locomotive Engineers and Firemen |
| 1933 | Walkden, AlexanderAlexander Walkden | Railway Clerks' Association |
| 1934 | Conley, AndrewAndrew Conley | National Union of Tailors and Garment Workers |
| 1935 | Kean, WilliamWilliam Kean | National Union of Gold, Silver and Allied Trades |
| 1936 | Findlay, AllanAllan Findlay | United Patternmakers Association |
| 1937 | Bevin, ErnestErnest Bevin | Transport and General Workers Union |
| 1938 | Elvin, Herbert HenryHerbert Henry Elvin | National Union of Clerks and Administrative Workers |
| 1939 | Hallsworth, JosephJoseph Hallsworth | National Union of Distributive and Allied Workers |
| 1940 | Holmes, BillBill Holmes | National Union of Agricultural Workers |
| 1941 | Gibson, GeorgeGeorge Gibson | Mental Hospital and Institutional Workers Union |
| 1942 | Wolstencroft, FrankFrank Wolstencroft | Amalgamated Society of Woodworkers |
| 1943 | Loughlin, AnneAnne Loughlin | National Union of Tailors and Garment Workers |
| 1944 | Edwards, EbbyEbby Edwards | Miners Federation of Great Britain |
| 1945 | Edwards, EbbyEbby Edwards | National Union of Mineworkers |
| 1946 | Dukes, CharlesCharles Dukes | National Union of General and Municipal Workers |
| 1947 | Thomson, George WalkerGeorge Walker Thomson | Association of Engineering and Shipbuilding Draughtsmen |
| 1948 | Hancock, FlorenceFlorence Hancock | Transport and General Workers Union |
| 1949 | Lawther, WillWill Lawther | National Union of Mineworkers |
| 1950 | Bullock, HerbertHerbert Bullock | National Union of General and Municipal Workers |
| 1951 | Roberts, AlfredAlfred Roberts | National Association of Card, Blowing and Ring Room Operatives |
| 1952 | Deakin, ArthurArthur Deakin | Transport and General Workers Union |
| 1953 | O'Brien, TomTom O'Brien | National Association of Theatrical and Kine Employees |
| 1954 | Tanner, JackJack Tanner | Amalgamated Engineering Union |
| 1955 | Geddes, CharlesCharles Geddes | Union of Post Office Workers |
| 1956 | Beard, WilfredWilfred Beard | United Patternmakers Association |
| 1957 | Williamson, TomTom Williamson | National Union of General and Municipal Workers |
| 1958 | Yates, TomTom Yates | National Union of Seamen |
| 1959 | Willis, RobertRobert Willis | London Typographical Society |
| 1960 | Bartlett, ClaudeClaude Bartlett | Confederation Of Health Service Employees |
| 1961 | Hill, TedTed Hill | United Society of Boilermakers |
| 1962 | Godwin, AnneAnne Godwin | Clerical and Administrative Workers Union |
| 1963 | Hayday, FrederickFrederick Hayday | National Union of General and Municipal Workers |
| 1964 | Lowthian, George H.George H. Lowthian | Amalgamated Union of Building Trade Workers |
| 1965 | Collison, HaroldHarold Collison | National Union of Agricultural Workers |
| 1966 | O'Hagan, JosephJoseph O'Hagan | National Union of Blastfurnacemen, Ore Miners, Coke Workers and Kindred Trades |
| 1967 | Douglass, HarryHarry Douglass | Iron and Steel Trades Confederation |
| 1968 | Wright, LewisLewis Wright | Amalgamated Weavers' Association |
| 1969 | Newton, John E.John E. Newton | National Union of Tailors and Garment Workers |
| 1970 | Greene, SidneySidney Greene | National Union of Railwaymen |
| 1971 | Cooper, JackJack Cooper | National Union of General and Municipal Workers |
| 1972 | Smith, GeorgeGeorge Smith | Union of Construction, Allied Trades and Technicians |
| 1973 | Crawford, JosephJoseph Crawford | National Association of Colliery Overmen, Deputies and Shotfirers |
| 1974 | Allen, AlfredAlfred Allen | Union of Shop, Distributive and Allied Workers |
| 1975 | Patterson, MarieMarie Patterson | Transport and General Workers Union |
| 1976 | Plant, CyrilCyril Plant | Inland Revenue Staff Federation |
| 1977 | McGarvey, DannyDanny McGarvey[5] | Amalgamated Society of Boilermakers, Shipwrights, Blacksmiths and Structural Workers |
| 1977 | Patterson, MarieMarie Patterson | Transport and General Workers Union |
| 1978 | Basnett, DavidDavid Basnett | National Union of General and Municipal Workers |
| 1979 | Jackson, ThomasThomas Jackson | Union of Post Office Workers |
| 1980 | Parry, TerryTerry Parry | Fire Brigades Union |
| 1981 | Fisher, AlanAlan Fisher | National Union of Public Employees |
| 1982 | Sapper, AlanAlan Sapper | Association of Cinematograph Television and Allied Technicians |
| 1983 | Chapple, FrankFrank Chapple | Electrical, Electronic, Telecommunications and Plumbing Union |
| 1984 | Buckton, RayRay Buckton | Associated Society of Locomotive Engineers and Firemen |
| 1985 | Eccles, JackJack Eccles | General, Municipal, Boilermakers and Allied Trade Union |
| 1986 | Gill, KenKen Gill | Technical, Administrative and Supervisory Section |
| 1987 | Jarvis, FredFred Jarvis | National Union of Teachers |
| 1988 | Jenkins, CliveClive Jenkins | Manufacturing, Science and Finance |
| 1989 | Christopher, TonyTony Christopher | Inland Revenue Staff Federation |
| 1990 | Maddocks, AdaAda Maddocks | National and Local Government Officers Association |
| 1991 | Smith, AlecAlec Smith | GMB Union |
| 1992 | Bickerstaffe, RodneyRodney Bickerstaffe | National Union of Public Employees |
| 1993 | Tuffin, AlanAlan Tuffin | Union of Communication Workers |
| 1994 | Knapp, JimmyJimmy Knapp | National Union of Rail, Maritime and Transport Workers |
| 1995 | Mills, LeifLeif Mills | Banking, Insurance and Finance Union |
| 1996 | Prosser, MargaretMargaret Prosser | Transport and General Workers Union |
| 1997 | Dubbins, TonyTony Dubbins | Graphical, Paper and Media Union |
| 1998 | Edmonds, JohnJohn Edmonds | GMB Union |
| 1999 | Mackenzie, HectorHector Mackenzie | UNISON |
| 2000 | Donaghy, RitaRita Donaghy | UNISON |
| 2001 | Morris, BillBill Morris | Transport and General Workers Union |
| 2002 | Young, TonyTony Young | Communication Workers Union |
| 2003 | Gruchy, Nigel deNigel de Gruchy | National Association of Schoolmasters Union of Women Teachers |
| 2004 | Lyons, RogerRoger Lyons | Amicus |
| 2005 | Drake, JeannieJeannie Drake | Communication Workers Union |
| 2006 | Mills, GloriaGloria Mills | UNISON |
| 2007 | Shepherd, AlisonAlison Shepherd | UNISON |
| 2008 | Prentis, DaveDave Prentis | UNISON |
| 2009 | Bearcroft, SheilaSheila Bearcroft | GMB Union |
| 2010 | Rooney, DougieDougie Rooney | Unite |
| 2011 | Leahy, MichaelMichael Leahy | Community |
| 2012 | Kenny, PaulPaul Kenny | GMB Union |
| 2013 | Mercer, LesleyLesley Mercer | Chartered Society of Physiotherapy |
| 2014 | Taj, MohammadMohammad Taj | Unite |
| 2015 | Manasseh, LeslieLeslie Manasseh | Prospect |
| 2016 | Snape, LizLiz Snape | UNISON |