Dodecanol
Names | |
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IUPAC name
Dodecan-1-ol | |
Other names
Dodecanol 1-Dodecanol Dodecyl alcohol Lauryl alcohol | |
Identifiers | |
112-53-8 | |
ChEBI | CHEBI:28878 |
ChEMBL | ChEMBL24722 |
ChemSpider | 7901 |
DrugBank | DB06894 |
Jmol interactive 3D | Image |
KEGG | C02277 |
PubChem | 8193 |
UNII | 178A96NLP2 |
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Properties | |
C12H26O | |
Molar mass | 186.34 |
Appearance | Colorless solid |
Density | 0.8309 |
Melting point | 24 °C (75 °F; 297 K) |
Boiling point | 259 °C (498 °F; 532 K) |
0.004 g/L[2] | |
Solubility in ethanol and diethyl ether | Soluble |
Hazards | |
R/S statement | R36 |
Flash point | 127 °C (261 °F; 400 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
Dodecanol /ˈdoʊˈdɛkɑːnɒl/ (systematically named dodecan-1-ol) is an organic compound with the chemical formula CH3(CH2)10CH2OH (also written as C
12H
26O). It is tasteless, colourless solid with a floral smell. It is classified as a fatty alcohol.
Production and use
In 1993, the European demand of dodecanol was around 60 thousand tons per year (Tt/a). It can be obtained from palm kernel or coconut oil fatty acids and methyl esters by hydrogenation.[3] It may also be produced synthetically via the Ziegler process.
Dodecanol is used to make surfactants, lubricating oils, pharmaceuticals, in the formation of monolithic polymers and as a flavor enhancing food additive. In cosmetics, dodecanol is used as an emollient. It is also the precursor to dodecanal, an important fragrance.
Toxicity
Dodecanol can irritate the skin. It has about half the toxicity of ethanol, but it is very harmful to marine organisms.[4]
Mutual solubility with water
The mutual solubility of 1-dodecanol and water has been quantified as follows.[5]
Temperature, °C | Solubility of Dodecanol in Water | Solubility of Water in Dodecanol |
---|---|---|
29.5 | 0.04 | 2.87 |
40.0 | 0.05 | 2.85 |
50.2 | 0.09 | 2.69 |
60.5 | 0.15 | 2.96 |
70.5 | 0.09 | 2.70 |
80.3 | 0.14 | 2.89 |
90.8 | 0.18 | 2.96 |
standard deviation | 0.02 | 0.01 |
References
- ↑ Merck Index, 12th Edition, 3464.
- ↑ Record in the GESTIS Substance Database of the IFA
- ↑ Klaus Noweck, Wolfgang Grafahrend, "Fatty Alcohols" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. doi:10.1002/14356007.a10_277.pub2
- ↑ MSDS Safety Sheet
- ↑ Richard Stephenson and James Stuart, "Mutual Binary Solubilities: Water-Alcohols and Water-Esters", J. Chem. Eng. Data, 1986, 31, 56-70.
External links
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