Miltiradiene synthase
Miltiradiene synthase (EC 4.2.3.131, SmMDS, SmiKSL) is an enzyme with systematic name (+)-copaly-diphosphate diphosphate-lyase (cyclizing, miltiradiene-forming).[1][2] This enzyme catalyses the following chemical reaction
- (+)-copalyl diphosphate miltiradiene + diphosphate
This enzyme is isolated from the plant Selaginella moellendorffii.
References
- ↑ Gao, W., Hillwig, M.L., Huang, L., Cui, G., Wang, X., Kong, J., Yang, B. and Peters, R.J. (2009). "A functional genomics approach to tanshinone biosynthesis provides stereochemical insights". Org. Lett. 11: 5170–5173. doi:10.1021/ol902051v. PMID 19905026.
- ↑ Sugai, Y., Ueno, Y., Hayashi, K., Oogami, S., Toyomasu, T., Matsumoto, S., Natsume, M., Nozaki, H. and Kawaide, H. (2011). "Enzymatic 13C labeling and multidimensional NMR analysis of miltiradiene synthesized by bifunctional diterpene cyclase in Selaginella moellendorffii". J. Biol. Chem. 286: 42840–42847. doi:10.1074/jbc.m111.302703. PMID 22027823.
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